Plasmon-driven photocatalytic molecular transformations on metallic nanostructure surfaces: mechanistic insights gained from plasmon-enhanced Raman spectroscopy

2021 ◽  
Vol 6 (4) ◽  
pp. 250-280
Author(s):  
Kexun Chen ◽  
Hui Wang
Keyword(s):  
Raman Spectroscopy ◽  
Metal Surfaces ◽  
Review Article ◽  
Metallic Nanostructure ◽  
Complex Mechanisms ◽  
Shed Light ◽  
Nanostructured Metal

This Review Article elaborates on the insights gained from in situ plasmon-enhanced Raman spectroscopy, which shed light on the complex mechanisms underpinning plasmon-driven photocatalytic molecular transformations on nanostructured metal surfaces.

Preparation of phthalocyanine and octacyanophthalocyanine films by CVD on metal surfaces, and in SITU observation of the molecular processes by Raman spectroscopy

1988 ◽  
Vol 33-34 ◽  
pp. 1324-1331 ◽  
Author(s):  
Kikujiro Ishii ◽  
Satoshi Mitsumura ◽  
Yukinobu Hibino ◽  
Ryoji Hagiwara ◽  
Hideyuki Nakayama
Keyword(s):  
Raman Spectroscopy ◽  
Metal Surfaces ◽  
In Situ Observation ◽  
Molecular Processes

In Situ Raman Spectroscopy Studies on La2CaB10O19 Crystal Growth

2020 ◽  
Vol 20 (10) ◽  
pp. 6604-6609
Author(s):  
Shanshan Liu ◽  
Guochun Zhang ◽  
Kai Feng ◽  
Yanyang Han ◽  
Tao He ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Crystal Growth ◽  
In Situ Raman Spectroscopy ◽  
In Situ Raman ◽  
Spectroscopy Studies

scholarly journals Retraction of “High-Capacitance Mechanism for Ti3C2Tx MXene by in Situ Electrochemical Raman Spectroscopy Investigation″

ACS Nano ◽  
2021 ◽  
Author(s):  
Minmin Hu ◽  
Zhaojin Li ◽  
Tao Hu ◽  
Shihao Zhu ◽  
Chao Zhang ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
High Capacitance

The use of in-situ Raman spectroscopy in investigating carbon materials as the anodes of alkali metal-ion batteries

Carbon ◽  
2021 ◽  
Vol 177 ◽  
pp. 428
Author(s):  
Xiaoqin Cheng ◽  
Huijun Li ◽  
Zhenxin Zhao ◽  
Yong-zhen Wang ◽  
Xiaomin Wang
Keyword(s):  
Raman Spectroscopy ◽  
Alkali Metal ◽  
Metal Ion ◽  
Carbon Materials ◽  
In Situ Raman Spectroscopy ◽  
Alkali Metal Ion ◽  
In Situ Raman

scholarly journals A thin, deformable, high-performance supercapacitor implant that can be biodegraded and bioabsorbed within an animal body

2021 ◽  
Vol 7 (2) ◽  
pp. eabe3097
Author(s):  
Hongwei Sheng ◽  
Jingjing Zhou ◽  
Bo Li ◽  
Yuhang He ◽  
Xuetao Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Electronic Devices ◽  
Form Factors ◽  
Time Frame ◽  
Water Soluble ◽  
Two Dimensional ◽  
Medical Electronics ◽  
Thin Structure ◽  
Shed Light

It has been an outstanding challenge to achieve implantable energy modules that are mechanically soft (compatible with soft organs and tissues), have compact form factors, and are biodegradable (present for a desired time frame to power biodegradable, implantable medical electronics). Here, we present a fully biodegradable and bioabsorbable high-performance supercapacitor implant, which is lightweight and has a thin structure, mechanical flexibility, tunable degradation duration, and biocompatibility. The supercapacitor with a high areal capacitance (112.5 mF cm−2 at 1 mA cm−2) and energy density (15.64 μWh cm−2) uses two-dimensional, amorphous molybdenum oxide (MoOx) flakes as electrodes, which are grown in situ on water-soluble Mo foil using a green electrochemical strategy. Biodegradation behaviors and biocompatibility of the associated materials and the supercapacitor implant are systematically studied. Demonstrations of a supercapacitor implant that powers several electronic devices and that is completely degraded after implantation and absorbed in rat body shed light on its potential uses.

scholarly journals Structural and Technological Approach to Reveal the Role of the Lipid Phase in the Formation of Soy Emulsion Gels with Chia Oil

Gels ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 48
Author(s):  
Ana M. Herrero ◽  
Claudia Ruiz-Capillas
Keyword(s):  
Raman Spectroscopy ◽  
Structural Properties ◽  
Structural Changes ◽  
Protein Secondary Structure ◽  
Lipid Phase ◽  
Α Helix ◽  
Β Sheet ◽  
Shed Light ◽  
Chia Oil

Considerable attention has been paid to emulsion gels (EGs) in recent years due to their interesting applications in food. The aim of this work is to shed light on the role played by chia oil in the technological and structural properties of EGs made from soy protein isolates (SPI) and alginate. Two systems were studied: oil-free SPI gels (SPI/G) and the corresponding SPI EGs (SPI/EG) that contain chia oil. The proximate composition, technological properties (syneresis, pH, color and texture) and structural properties using Raman spectroscopy were determined for SPI/G and SPI/EG. No noticeable (p > 0.05) syneresis was observed in either sample. The pH values were similar (p > 0.05) for SPI/G and SPI/EG, but their texture and color differed significantly depending on the presence of chia oil. SPI/EG featured significantly lower redness and more lightness and yellowness and exhibited greater puncture and gel strengths than SPI/G. Raman spectroscopy revealed significant changes in the protein secondary structure, i.e., higher (p < 0.05) α-helix and lower (p < 0.05) β-sheet, turn and unordered structures, after the incorporation of chia oil to form the corresponding SPI/EG. Apparently, there is a correlation between these structural changes and the textural modifications observed.

Calibration Methods to Circumvent Unknown Component Spectra for Quantitative in situ Raman Monitoring of Co-Polymerisation Reaction

2021 ◽  
Author(s):  
Wendy Rusli ◽  
Pavan Kumar Naraharisetti ◽  
Wee Chew
Keyword(s):  
Raman Spectroscopy ◽  
Reaction Monitoring ◽  
The Past ◽  
In Situ Raman ◽  
Calibration Methods ◽  
Unknown Component

The use of Raman spectroscopy for reaction monitoring has been successfully applied over the past few decades. One complication in such usage is the applicability for quantitative reaction studies. This...

An apparatus for in situ Raman spectroscopy of ion‐irradiated frozen targets

1991 ◽  
Vol 62 (7) ◽  
pp. 1743-1745 ◽  
Author(s):  
F. Spinella ◽  
G. A. Baratta ◽  
G. Strazzulla
Keyword(s):  
Raman Spectroscopy ◽  
In Situ Raman Spectroscopy ◽  
In Situ Raman
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