Hierarchically multifunctional integrated catalyst with intimate and synergistic active sites for one-pot tandem catalysis

Author(s):  
Yao Yao ◽  
Kexin Huang ◽  
Yi Liu ◽  
Tingting Luo ◽  
Ge Tian ◽  
...  

As a typical process intensified strategy, tandem reaction driven by multifunctional catalyst is a paragon of the green catalytic process. Two or more active sites are usually required and their...

2015 ◽  
Vol 51 (40) ◽  
pp. 8504-8507 ◽  
Author(s):  
Fan Jia ◽  
Xiaoyu Chen ◽  
Yan Zheng ◽  
Yusheng Qin ◽  
Youhua Tao ◽  
...  

One-pot synthesis of well-defined bio-renewable polyesters and cyclic carbonates in high yields was successfully realized for the first time by way of a tandem reaction using metal salen complexes as catalysts.


2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Jian Wei ◽  
Qingjie Ge ◽  
Ruwei Yao ◽  
Zhiyong Wen ◽  
Chuanyan Fang ◽  
...  

Abstract The direct production of liquid fuels from CO2 hydrogenation has attracted enormous interest for its significant roles in mitigating CO2 emissions and reducing dependence on petrochemicals. Here we report a highly efficient, stable and multifunctional Na–Fe3O4/HZSM-5 catalyst, which can directly convert CO2 to gasoline-range (C5–C11) hydrocarbons with selectivity up to 78% of all hydrocarbons while only 4% methane at a CO2 conversion of 22% under industrial relevant conditions. It is achieved by a multifunctional catalyst providing three types of active sites (Fe3O4, Fe5C2 and acid sites), which cooperatively catalyse a tandem reaction. More significantly, the appropriate proximity of three types of active sites plays a crucial role in the successive and synergetic catalytic conversion of CO2 to gasoline. The multifunctional catalyst, exhibiting a remarkable stability for 1,000 h on stream, definitely has the potential to be a promising industrial catalyst for CO2 utilization to liquid fuels.


Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 3918
Author(s):  
Anna Dymerska ◽  
Wojciech Kukułka ◽  
Marcin Biegun ◽  
Ewa Mijowska

The renewable energy technologies require electrocatalysts for reactions, such as the oxygen and/or hydrogen evolution reaction (OER/HER). They are complex electrochemical reactions that take place through the direct transfer of electrons. However, mostly they have high over-potentials and slow kinetics, that is why they require electrocatalysts to lower the over-potential of the reactions and enhance the reaction rate. The commercially used catalysts (e.g., ruthenium nanoparticles—Ru, iridium nanoparticles—Ir, and their oxides: RuO2, IrO2, platinum—Pt) contain metals that have poor stability, and are not economically worthwhile for widespread application. Here, we propose the spinel structure of nickel-cobalt oxide (NiCo2O4) fabricated to serve as electrocatalyst for OER. These structures were obtained by a facile two-step method: (1) One-pot solvothermal reaction and subsequently (2) pyrolysis or carbonization, respectively. This material exhibits novel rod-like morphology formed by tiny spheres. The presence of transition metal particles such as Co and Ni due to their conductivity and electron configurations provides a great number of active sites, which brings superior electrochemical performance in oxygen evolution and good stability in long-term tests. Therefore, it is believed that we propose interesting low-cost material that can act as a super stable catalyst in OER.


Author(s):  
Elizabeth A. K. Wilson ◽  
Shawn C. Eady ◽  
Trent Silbaugh ◽  
Levi T. Thompson ◽  
Mark A. Barteau

ChemInform ◽  
2013 ◽  
Vol 44 (28) ◽  
pp. no-no
Author(s):  
Yuqin Wang ◽  
Yanhong Chen ◽  
Qian He ◽  
Yuyuan Xie ◽  
Chunhao Yang
Keyword(s):  

Fuel ◽  
2021 ◽  
pp. 121060
Author(s):  
Chuhua Jia ◽  
Cheng Zhang ◽  
Shaoqu Xie ◽  
Wanli Zhang ◽  
Ziling Wang ◽  
...  

2015 ◽  
Vol 51 (52) ◽  
pp. 10419-10422 ◽  
Author(s):  
Qihao Yang ◽  
Yu-Zhen Chen ◽  
Zhiyong U. Wang ◽  
Qiang Xu ◽  
Hai-Long Jiang

The hydrogenation efficiency of nitro compounds is greatly boosted by coupling with ammonia borane dehydrogenation over rationally synthesized Pd@MIL-101 with Pd NPs in ∼3 nm.


Nanoscale ◽  
2021 ◽  
Author(s):  
Zejun Sun ◽  
Yujiao Sun ◽  
Meng Yang ◽  
Hui Jin ◽  
Rijun Gui

A facile one-pot precipitation was employed to prepare a petal-shaped hybrid in mild conditions. The hybrid is composed of urate oxidase (UOx) encapsulated into zeolite-like metal-organic frameworks (MOF) with doping...


ChemInform ◽  
2016 ◽  
Vol 47 (18) ◽  
Author(s):  
Tuanjie Meng ◽  
Lantao Liu ◽  
Huiyi Jia ◽  
Lifeng Ren ◽  
Cuilan Feng ◽  
...  

ChemInform ◽  
2011 ◽  
Vol 42 (7) ◽  
pp. no-no
Author(s):  
Li Zhang ◽  
Zhenggen Zha ◽  
Zhenlei Zhang ◽  
Yunfeng Li ◽  
Zhiyong Wang

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