Extraordinary energy storage performance and thermal stability in sodium niobate-based ceramics modified by the ion disorder and stabilized antiferroelectric orthorhombic R phase

Author(s):  
Ruirui Kang ◽  
Zepeng Wang ◽  
Weijie Yang ◽  
Xiaopei Zhu ◽  
Peng Shi ◽  
...  

Developing high-performance dielectric capacitors is essential to meet the growing demands of hybrid electric vehicles and high-power applications. The energy storage efficiency and the temperature-variant energy storage properties should be...

2021 ◽  
Author(s):  
Liwei Zhu ◽  
Ning Liu ◽  
Xincheng Lv ◽  
Ziqiu Zhang ◽  
Liangmin Yu ◽  
...  

A novel carbon nanomaterial with unique morphology was prepared and proven to be an effective material for EMWA and electrochemical energy storage.


2020 ◽  
Vol 10 (04) ◽  
pp. 2050011
Author(s):  
Nguyen Truong-Tho ◽  
Le Dai Vuong

Sintered lead-free [Formula: see text]([Formula: see text][Formula: see text]([Formula: see text][Formula: see text]O3 ceramics (BNKTS) have been fabricated via a solid-state reaction. The effect of sintering temperature on the structural, morphological, dielectric, ferroelectric and energy storage properties of BNKTS ceramics was investigated, and it was found that the electrical properties of the synthesized ceramics increased with the increase in the sintering temperature, and the highest values were achieved at [Formula: see text]C. The ceramics sintered at the optimized temperature of [Formula: see text]C exhibited the best physical, dielectric, ferroelectric and energy storage properties, namely, high density (the relative density, [Formula: see text][Formula: see text]g.cm[Formula: see text], approximate to 96.7% of the theoretical value), high densification factor ([Formula: see text]), high dielectric constant ([Formula: see text]), low dielectric loss (tan[Formula: see text]), highest dielectric constant ([Formula: see text]), high remanent polarization ([Formula: see text]C.cm[Formula: see text], high coercive field ([Formula: see text][Formula: see text]kV/cm), high energy storage density (0.12[Formula: see text]J/cm[Formula: see text], and high energy storage efficiency (41.7% at 46.3[Formula: see text]kV/cm).


2020 ◽  
pp. 1-10
Author(s):  
Jinbo Wang ◽  
Huiqing Fan

The validity of Mn element on enhanced energy storage performance and fatigue resistance of Mn-doped 0.7Na0.5Bi0.5TiO3–0.3Sr0.7Bi0.2TiO3 lead-free ferroelectric ceramics (BNT–BST–xMn) is certified by doping. The effects of Mn modification on the dielectric behavior, ferroelectric, energy storage properties, and AC impedance are comprehensively investigated. It is found that the average grain size of the ceramics modified by Mn additions is reduced slightly. Moreover, the relaxor properties are evidently enhanced with the increased Mn content. The AC impedance spectra can even better clarify the dielectric response and relaxor behavior. The results suggest that both of the dielectric response and relaxor behavior are determined by defects especially concentration of the oxygen vacancy. The superior energy storage properties are realized at x = 0.05 with an energy storage density (Wrec) of 1.33 J/cm3 as well as energy storage efficiency (η) of 86.2% at 100 kV/cm, accompanied with a superior thermal stability. BNT–BST–5Mn ceramics can maintain a stable energy storage performance within 106 fatigue cycles, indicating an excellent fatigue resistance.


2019 ◽  
Vol 7 (8) ◽  
pp. 3815-3827 ◽  
Author(s):  
Xueying Cao ◽  
Liang Cui ◽  
Bingping Liu ◽  
Ying Liu ◽  
Dedong Jia ◽  
...  

A vertically oriented star anise-like MOF-based material is prepared by a novel strategy using Cu(OH)2 as the template and precursor, which shows promising electrochemical energy storage properties.


2019 ◽  
Vol 12 (03) ◽  
pp. 1950034 ◽  
Author(s):  
Long He ◽  
Jing Wang ◽  
Zhong Yang ◽  
Kongjun Zhu ◽  
Chaoyong Deng

Flexible Nd-doped BaTiO3@Al2O3/polyvinylidene fluoride (PVDF) composites have been successfully developed. With the reaction temperature of 70∘C, Nd-doped BaTiO3@Al2O3 particles display uniform core–shell structures and disperse well in the PVDF matrix. Due to the benign dielectric properties of Nd-doped BaTiO3 and great suppression of the Al2O3 coating on the leakage current and dielectric loss, the Nd-doped BaTiO3@Al2O3/PVDF composites with different Nd-doped BaTiO3@Al2O3 filling ratios (0–4[Formula: see text]vol.%) exhibit relatively good dielectric and energy storage performance. Among them, the maximum discharged energy density of 8.6[Formula: see text]J/cm3 was achieved in the composite with 1[Formula: see text]vol.% Nd-doped BaTiO3@Al2O3 loading.


2018 ◽  
Vol 6 (26) ◽  
pp. 12291-12297 ◽  
Author(s):  
Zhongshuai Liang ◽  
Ming Liu ◽  
Chunrui Ma ◽  
Lvkang Shen ◽  
Lu Lu ◽  
...  

High performance Pb-free Ba(Zr0.35Ti0.65)O3 film capacitors exhibit outstanding energy storage properties over a wide temperature range from −100 °C to 200 °C, demonstrating a great foreground for utilization in equipment working in harsh environments.


2020 ◽  
Vol 8 (17) ◽  
pp. 5681-5691 ◽  
Author(s):  
Pengyuan Fan ◽  
Shan-Tao Zhang ◽  
Jiwen Xu ◽  
Jiadong Zang ◽  
Chanatip Samart ◽  
...  

Compared with the relaxor with pinched P–E loops, the relaxor/antiferroelectric (RE/AFE) composites have narrower and oblique curves, proving the design of RE/AFE is an effective method to improve the energy storage properties of dielectric ceramics.


2019 ◽  
Vol 7 (14) ◽  
pp. 8573-8580 ◽  
Author(s):  
Letao Yang ◽  
Xi Kong ◽  
Zhenxiang Cheng ◽  
Shujun Zhang

A strategy of mitigating polarization saturation is applied to enhance the energy storage properties of Sn-modified NBT–ST relaxor ceramics.


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