Molecular interactions and functionalities of organic additive in a perovskite semiconducting device: a case study towards high performance solar cells

2022 ◽  
Author(s):  
Hongkang Gong ◽  
Qi Song ◽  
Chao Ji ◽  
Huimin Zhang ◽  
Chunjun Liang ◽  
...  
Keyword(s):  
Solar Cell ◽  
Amino Acid ◽  
Molecular Interactions ◽  
High Performance ◽  
Perovskite Solar Cell ◽  
Organic Additive ◽  
Acid Hydrochloride ◽  
Halide Perovskite ◽  
Phenylbutyric Acid

A chiral aromatic amino acid, (S)-3-Amino-4-phenylbutyric acid hydrochloride (s-APACl), was employed as an additive to the active layer in a p-i-n organic-inorganic halide perovskite solar cell. This additive led to...

scholarly journals Performance and Stability Comparison of Low-Cost Mixed Halide Perovskite Solar Cells: CH3NH3PbI3- x Cl x and CH3NH3PbI3- x SCN x

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Nji Raden Poespawati ◽  
Junivan Sulistianto ◽  
Tomy Abuzairi ◽  
Retno Wigajatri Purnamaningsih
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Spin Coating ◽  
High Performance ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Cell Stability ◽  
Stability Measurement ◽  
Halide Perovskite

Perovskite solar cell is categorized as a third-generation solar cell which is used for its high-performance and low-cost production. However, device stability is a major problem in the development of perovskite solar cells. Mixed halide perovskite is one of the subjects that have been proposed to improve perovskite solar cell stability. Research about solar cells using mixed halide perovskite is widely reported. However, complex configurations and fabrication using sophisticated equipment were usually used in those reported studies. In this work, the fabrication of solar cells using mixed halide perovskite CH3NH3PbI3- x Cl x and CH3NH3PbI3- x SCN x was conducted using a simple and low-cost structure. Solution-processed deposition fabrication method using spin coating was used to fabricate the devices. Optimization of the spin coating rate for each layer in the perovskite solar cells was performed to ensure that the devices exhibited decent performance. Stability measurement and analysis of the perovskite solar cells were conducted. Summarily, solar cells with mixed halide perovskite CH3NH3PbI3- x Cl x exhibit the highest performance with an efficiency of 2.92%. On the other hand, solar cell with mixed halide perovskite CH3NH3PbI3- x SCN x has the best stability which only drops its efficiency by 39% from its initial value after 13 days.

scholarly journals A 0D/3D Heterostructured All‐Inorganic Halide Perovskite Solar Cell with High Performance and Enhanced Phase Stability

2019 ◽  
Vol 31 (48) ◽  
pp. 1904735 ◽  
Author(s):  
Fujin Bai ◽  
Jie Zhang ◽  
Yufei Yuan ◽  
Hongbin Liu ◽  
Xiaosong Li ◽  
...  
Keyword(s):  
Solar Cell ◽  
Phase Stability ◽  
High Performance ◽  
Perovskite Solar Cell ◽  
Halide Perovskite

scholarly journals Crystal Engineering Approach for Fabrication of Inverted Perovskite Solar Cell in Ambient Conditions

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1751
Author(s):  
Inga Ermanova ◽  
Narges Yaghoobi Nia ◽  
Enrico Lamanna ◽  
Elisabetta Di Bartolomeo ◽  
Evgeny Kolesnikov ◽  
...  
Keyword(s):  
Solar Cell ◽  
Crystal Engineering ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Layer By Layer ◽  
Ambient Conditions ◽  
Sequential Method ◽  
Engineering Approach ◽  
Hole Transporting

In this paper, we demonstrate the high potentialities of pristine single-cation and mixed cation/anion perovskite solar cells (PSC) fabricated by sequential method deposition in p-i-n planar architecture (ITO/NiOX/Perovskite/PCBM/BCP/Ag) in ambient conditions. We applied the crystal engineering approach for perovskite deposition to control the quality and crystallinity of the light-harvesting film. The formation of a full converted and uniform perovskite absorber layer from poriferous pre-film on a planar hole transporting layer (HTL) is one of the crucial factors for the fabrication of high-performance PSCs. We show that the in-air sequential deposited MAPbI3-based PSCs on planar nickel oxide (NiOX) permitted to obtain a Power Conversion Efficiency (PCE) exceeding 14% while the (FA,MA,Cs)Pb(I,Br)3-based PSC achieved 15.6%. In this paper we also compared the influence of transporting layers on the cell performance by testing material depositions quantity and thickness (for hole transporting layer), and conditions of deposition processes (for electron transporting layer). Moreover, we optimized second step of perovskite deposition by varying the dipping time of substrates into the MA(I,Br) solution. We have shown that the layer by layer deposition of the NiOx is the key point to improve the efficiency for inverted perovskite solar cell out of glove-box using sequential deposition method, increasing the relative efficiency of +26% with respect to reference cells.

scholarly journals High-performance hole conductor-free perovskite solar cell using a carbon nanotube counter electrode

RSC Advances ◽  
2020 ◽  
Vol 10 (59) ◽  
pp. 35831-35839 ◽  
Author(s):  
Mustafa K. A. Mohammed
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Carbon Nanotube ◽  
High Performance ◽  
Counter Electrode ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Manufacturing Cost ◽  
Long Term Stability

Carbon-based perovskite solar cells (C-PSCs) are the most promising photovoltaic (PV) due to their low material and manufacturing cost and superior long-term stability.

scholarly journals Progress and Challenges on Scaling up of Perovskite Solar Cell Technology

2021 ◽  
Author(s):  
Jin Yan ◽  
Tom J Savenije ◽  
Luana Mazzarella ◽  
Olindo Isabella
Keyword(s):  
Solar Cell ◽  
Scaling Up ◽  
Perovskite Solar Cell ◽  
Metal Halide ◽  
Cell Technology ◽  
Metal Halide Perovskite ◽  
Halide Perovskite ◽  
Solar Cell Technology

Since the first application of a metal halide perovskite (PVK) absorber in a solar cell, these materials have drawn a great deal of attention in the photovoltaic (PV) community, showing...

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