scholarly journals Crystal Engineering Approach for Fabrication of Inverted Perovskite Solar Cell in Ambient Conditions

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1751
Author(s):  
Inga Ermanova ◽  
Narges Yaghoobi Nia ◽  
Enrico Lamanna ◽  
Elisabetta Di Bartolomeo ◽  
Evgeny Kolesnikov ◽  
...  

In this paper, we demonstrate the high potentialities of pristine single-cation and mixed cation/anion perovskite solar cells (PSC) fabricated by sequential method deposition in p-i-n planar architecture (ITO/NiOX/Perovskite/PCBM/BCP/Ag) in ambient conditions. We applied the crystal engineering approach for perovskite deposition to control the quality and crystallinity of the light-harvesting film. The formation of a full converted and uniform perovskite absorber layer from poriferous pre-film on a planar hole transporting layer (HTL) is one of the crucial factors for the fabrication of high-performance PSCs. We show that the in-air sequential deposited MAPbI3-based PSCs on planar nickel oxide (NiOX) permitted to obtain a Power Conversion Efficiency (PCE) exceeding 14% while the (FA,MA,Cs)Pb(I,Br)3-based PSC achieved 15.6%. In this paper we also compared the influence of transporting layers on the cell performance by testing material depositions quantity and thickness (for hole transporting layer), and conditions of deposition processes (for electron transporting layer). Moreover, we optimized second step of perovskite deposition by varying the dipping time of substrates into the MA(I,Br) solution. We have shown that the layer by layer deposition of the NiOx is the key point to improve the efficiency for inverted perovskite solar cell out of glove-box using sequential deposition method, increasing the relative efficiency of +26% with respect to reference cells.

2016 ◽  
Vol 9 (5) ◽  
pp. 1681-1686 ◽  
Author(s):  
Tadas Malinauskas ◽  
Michael Saliba ◽  
Taisuke Matsui ◽  
Maryte Daskeviciene ◽  
Simona Urnikaite ◽  
...  

Small-molecule fluorene HTMs were synthesized and tested in perovskite solar cell, PCE of up to 19.96% was reached.


Author(s):  
Fei Wu ◽  
Kangrong Yan ◽  
Haotian Wu ◽  
Benfang Niu ◽  
Zhixin Liu ◽  
...  

PEDOT:PSS is one of the most frequently used hole transporting layer (HTL) for solution-processed optoelectronic devices, but seems unsuccessful in high-performance lead based perovskite solar cells (PVSCs) due to the...


RSC Advances ◽  
2020 ◽  
Vol 10 (59) ◽  
pp. 35831-35839 ◽  
Author(s):  
Mustafa K. A. Mohammed

Carbon-based perovskite solar cells (C-PSCs) are the most promising photovoltaic (PV) due to their low material and manufacturing cost and superior long-term stability.


2018 ◽  
Vol 6 (28) ◽  
pp. 13751-13760 ◽  
Author(s):  
Chien-Hung Chiang ◽  
Cheng-Chiang Chen ◽  
Mohammad Khaja Nazeeruddin ◽  
Chun-Guey Wu

A new inorganic hole transporting layer, a sputtering made LiCoO2 film, was developed and used in an inverted perovskite solar cell (PSC) and sub-module (PSM).


2015 ◽  
Vol 17 (7) ◽  
pp. 4937-4944 ◽  
Author(s):  
Huiyun Wei ◽  
Jiangjian Shi ◽  
Xin Xu ◽  
Junyan Xiao ◽  
Jianheng Luo ◽  
...  

A MIS back contact was constructed by introducing an ultrathin AlOxlayer to improve the performance of HTM-free perovskite solar cells.


2018 ◽  
Vol 6 (25) ◽  
pp. 6816-6822 ◽  
Author(s):  
Hongyuan Liu ◽  
Xiaorui Liu

A strategy to modulate the π-bridged units in bis(4-methoxyphenyl)amine-based molecules for improving the performance of perovskite solar cells was provided.


2018 ◽  
Vol 67 ◽  
pp. 01022 ◽  
Author(s):  
Michael Hariadi ◽  
Istighfari Dzikri ◽  
Retno Wigajatri Purnamaningsih ◽  
Nji Raden Poespawati

Indonesia is an archipelagic nation that has many small islands where the average load is low and currently supplied by diesel power generators. The drawbacks from these generators are cost constraints from its operation. Solar cells are the solution of this problem with the support of daily average radiation in Indonesia of 4.8 kWh/m2/day. There has been a lot of technology for the construction of solar cells such as silicon based, copper indium gallium selenide (CIGS), which was already successfully commercialized. However, these technologies have been obsolete and started to reach its maximum potential. Perovskite solar cells have a very high future potential, due to the increase on the efficiency of this technology in a relatively short amount of time. The current challenge for the fabrication of perovskite solar cell is the material cost and fabrication cost. This paper discussed the low-cost fabrication of perovskite solar cell using only spin coating deposition method and relatively also low-cost materials for the structure of the perovskite solar cell itself. As a result, we achieve perovskite solar cell with VOC of 0.6 V, ISC of 13 mA, FF of 0.28, and 1.2% efficiency.


2017 ◽  
Vol 1 (7) ◽  
pp. 1533-1540 ◽  
Author(s):  
Ahmed Esmail Shalan ◽  
Sudhakar Narra ◽  
Tomoya Oshikiri ◽  
Kosei Ueno ◽  
Xu Shi ◽  
...  

Configuration of the perovskite solar cell and diagram of the mechanism of preparation of TiO2 using atomic-layer deposition.


Author(s):  
Xinmiao Chen ◽  
Lei Lu ◽  
Dawei Gu ◽  
Xiaoyan Zhang ◽  
Yu He ◽  
...  

The printable HTM-free (HTM=hole transport materials) mesoporous carbon-based perovskite solar cell (C-PSC) is one of the most promising technologies, because of its simple production process, lost-cost and excellent stability. In...


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