Room temperature tin-119 Mössbauer spectra of unassociated tin compounds

Author(s):  
G. Michael Bancroft ◽  
K. David Butler ◽  
T. K. Sham
2021 ◽  
Author(s):  
Natalia Kazak ◽  
Yurii V. Knyazev ◽  
Vyacheslav Zhandun ◽  
Juan Bartolomé ◽  
Ana Arauzo ◽  
...  

The ludwigite Co2FeBO5 has been studied experimentally using 57Fe Mössbauer spectroscopy and theoretically by means of the DFT+GGA calculations. The room-temperature Mössbauer spectra are composed of four quadrupole doublets corresponding...


1993 ◽  
Vol 46 (5) ◽  
pp. 679 ◽  
Author(s):  
JM Cadogan ◽  
SJ Campbell ◽  
XL Zhao ◽  
E Wu

Mossbauer spectra of YC012B6 and NdCo12B6 doped with enriched 57Fe have been obtained at various temperatures between 4�2 K and room temperature. The spectrum of YC012B6 at 4�2 K indicates that the Co sublattice orders in the crystallographic basal plane. NdCo12B6 orders along or close to the crystallographic c-axis at 4�2 K and undergoes a spin-reorientation with increasing temperature until at ~55 K the magnetisation lies in or near the basal plane.


1991 ◽  
Vol 181 (1-3) ◽  
pp. 1-10 ◽  
Author(s):  
C. Meyer ◽  
F. Hartmann-Boutron ◽  
Y. Gros ◽  
P. Strobel

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Yun He ◽  
Xingxing Yang ◽  
Jinpei Lin ◽  
Qing Lin ◽  
Jianghui Dong

Zinc substituted magnesium ferrite nanomaterialsMg1-xZnxFe2O4(x= 0, 0.1, 0.3, 0.5, 0.7) powders have been prepared by a sol-gel autocombustion method. The lattice parameter increases with increase in Zn concentration, but average crystallite size tends to decrease by increasing the zinc content. SEM results indicate the distribution of grains and morphology of the samples. Some particles are agglomerated due to the presence of magnetic interactions among particles. Room temperature Mössbauer spectra ofMg1-xZnxFe2O4shows that the A Mössbauer absorption area decreases and the B Mössbauer absorption area increases with zinc concentration increasing. The change of the saturation magnetization can be explained with Néel’s theory. It was confirmed that the transition from ferrimagnetic to superparamagnetic behaviour depends on increase in zinc concentration by Mössbauer spectra at room temperature. Saturation magnetization increases and coercivity decreases with Zn content increasing.


Clay Minerals ◽  
1979 ◽  
Vol 14 (4) ◽  
pp. 273-283 ◽  
Author(s):  
E. Murad

Abstractβ-FeOOH (akaganéite) was prepared by slow hydrolysis of an FeCl3 solution. X-ray diffraction measurements gave refined unit-cell parameters of a=10·535 Å, c=3·030 Å.Two doublets with δ(Fe)=0·39, ΔEQ=0·95, and δ=0·38, ΔEQ=0·55 mm s−1, respectively, can be fitted to the Mössbauer spectrum taken at room temperature.Magnetically split Mössbauer spectra were registered at 135 and 4°K. These can be resolved into at least three superimposed sextets, corresponding to different Fe3+ sites in the β-FeOOH structure. At 4°K a three sextet model gives parameters of δ=0·36, ΔEQ=0·90, Hi=473; δ=0·35, ΔEQ=0·30, Hi=479; and δ=0·37, ΔEQ=−0·05 mm s−1, Hi=486kOe, respectively.The complexity of the Mössbauer spectra of β-FeOOH limits the usefulness of this method as a tool for the identification of akaganéite in composite natural samples.


1980 ◽  
Vol 35 (10) ◽  
pp. 1257-1260 ◽  
Author(s):  
Erwin Riedel ◽  
Till Dützmann ◽  
Norbert Pfeil

Abstract The spinel system Zn[FexV2-x]O4 has been prepared by heating mixtures of ZnV2O4 and ZnFe2O4 at 1000 °C. The lattice constants increase linearly with x by 3.6 pm, the oxygen parameters are constant with a mean value u = 0.384s. The parameters of room temperature Mössbauer spectra show that in the whole series V(III) and Fe(III) are present.


1994 ◽  
Vol 360 ◽  
Author(s):  
V. Marquina ◽  
M. JimÉnez ◽  
M.L. Marquina ◽  
R. Ridaura ◽  
S. Aburto ◽  
...  

AbstractMagnetic susceptibility measurements and Mössbauer spectra (MS) were performed on a series of NixFeyAlzB shape memory ribbons obtained by a melt spinning technique. The MS at room temperature show quadrupole splittings of two iron sites. At low temperatures (T<120 K) relaxed magnetic spectra begin to develop and, in one of the samples, a complete resolved magnetic spectrum at 13 K was observed. The overall magnetic susceptibility curves show non Curie-Weiss type behavior with peaks at around 60 K and 35 K. These curves also show magnetic hysteresis in the up-down temperature cycle used during the measurements. We relate our observations with a structural change occurring at temperatures between room temperature and 260 K, a second one around 200 K, and with the developing of spin-glass behavior at low temperatures, when the magnetic influences of Fe and Ni atoms almost compensate each other.


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