scholarly journals Nitrosamines: A review of formation pathways, precursors, control, and occurrence in drinking water

2019 ◽  
Vol 280 ◽  
pp. 05003
Author(s):  
Maxwell Meadows ◽  
Soni M. Pradhanang ◽  
Thomas B. Boving ◽  
Hichem Hadjeres

Nitrogenous disinfection by-products (N-DBPs) are emerging by-products that may be present in drinking water as by-products of water treatment plant (WTP) operations. Nitrosamines are N-DBPs that form by reaction of chloramine with certain organic nitrogen-containing compounds; however, the exact processes and environments in which nitrosamines form are still not well understood. Organic nitrogen precursors react within the WTP and distribution system, forming the toxic by-products during chloramination, or while in distribution. To best control the formation potential of nitrosamines, precursors must be removed from source water prior to chloramine disinfection. These nitrosamine forming precursors are abundant in source waters worldwide, presenting a need for further study of the mechanisms that reduce the formation potential of nitrosamines in chloramination WTPs.

2019 ◽  
Vol 19 (6) ◽  
pp. 1579-1586 ◽  
Author(s):  
Xiang-Ren Zhou ◽  
Yi-Li Lin ◽  
Tian-Yang Zhang ◽  
Bin Xu ◽  
Wen-Hai Chu ◽  
...  

Abstract The objective of this research was to study the occurrence and seasonal variations of disinfection by-products (DBPs), including traditional carbonaceous and emerging nitrogenous DBPs, in a full-scale drinking water treatment plant (DWTP) for nearly 2 years. The removal efficiencies of each DBP through the treatment processes were also investigated. This DWTP takes raw water from the Yangtze River in East China. The quality of the raw water used in this DWTP varied with different seasons. The results suggested that DBP concentrations of the finished water were higher in spring (82.33 ± 15.12 μg/L) and summer (117.29 ± 9.94 μg/L) with higher dissolved organic carbon (DOC) levels, but lower in autumn (41.10 ± 5.82 μg/L) and winter (78.47 ± 2.74 μg/L) with lower DOC levels. Due to the increase of bromide concentration in spring and winter, more toxic brominated DBPs increased obviously and took up a greater proportion. In this DWTP, DBP concentrations increased dramatically after pre-chlorination, especially in summer. It is noteworthy that the removal of DBPs during the subsequent treatment was more obvious in spring than in the other three seasons because the pH value is more beneficial to coagulation in spring.


2004 ◽  
Vol 4 (5-6) ◽  
pp. 343-353 ◽  
Author(s):  
M.J. Rosa ◽  
T. Cecílio ◽  
M. Ribau Teixeira ◽  
M. Viriato ◽  
R. Coelho ◽  
...  

A monitoring programme of hazardous substances was implemented in Alcantarilha's water treatment plant (Algarve, Portugal) since 2002, in addition to the legally established monitoring of standard physical, chemical and microbiological parameters. The objective of this programme was to ensure the drinking water quality regarding the waterborne disease organisms Cryptosporidium, Giardia, Salmonella, Pseudomonas aeruginosa, enterovirus and cyanobacteria, and the potentially harmful chemicals aluminium, cyanotoxins, and disinfection by-products (THM) and their precursors (TOC, DOC, UV254 nm, SUVA). Most of these parameters are new and still not regulated by the Portuguese and the European legislation. Data presented in this study refer to the period of August 2002 to October 2003. Results show that, despite the seasonal variations of the raw water quality, concentrations of the hazardous substances in the supplied drinking water were far below the legal standards and the WHO's and EPA guideline values, demonstrating the high removal efficiencies of this treatment plant.


2017 ◽  
Vol 5 (2) ◽  
pp. 168-179
Author(s):  
M. Farhaoui

Water management is a key pillar of sustainable development. Indeed, the rational use of water has become a condition for new investments in the water sector as many sectors. Optimizing the production of drinking water is one aspect. This optimization involves not only the choice of water resource use but also the management of by-products of the water treatment process to manage sustainably the exploited water resources. The city of Meknes is watered from two sources and a set of holes (14), the turbidity of water sources can vary depending on rainfall recorded in the region. A water treatment plant (600 l/s) was performed for the purification of water sources. Through this study, we focus on modeling of sludge volume produced by this plant.  The objective is to design a model for calculating the sludge volume from the actual data recorded in the plant. The model ca be used by the operator to predict the sludge volume and can be used also by the designers. The results of this study demonstrated that the volumes calculated from the model constructed considering the data recorded at the station perfectly match the volumes produced with a determination coefficient of 100%. The application of this model can not only provide the operator with an effective tool for managing of the station by-products but also to provide designers with a formula to prevent over/under design of structures. Therefore, these measures help to optimize the cost of production of drinking water and will play an important role in the sustainable development of water resources.


2020 ◽  
Vol 704 ◽  
pp. 135280 ◽  
Author(s):  
Henry MacKeown ◽  
Junias Adusei Gyamfi ◽  
Klaas Vital Kaat Marnix Schoutteten ◽  
David Dumoulin ◽  
Liesbeth Verdickt ◽  
...  

2015 ◽  
Vol 802 ◽  
pp. 513-518
Author(s):  
Nurazim Ibrahim ◽  
Hamidi Abdul Aziz ◽  
Mohd Suffian Yusoff

Natural organic matter (NOM) in water reacts with chlorine or other disinfectants and form hazardous disinfectant by-products (DBPs). This study aimed to detect the presence of NOM in a conventional water distribution system using UV absorbance at 254 nm as a surrogate. Two water treatment plants were selected, namely, Jalan Baharu Water Treatment Plant (JBWTP) and Lubok Buntar Water Treatment Plant (LBWTP). Aside from determining the amount of NOM, the reduction of UV254after completing the series of treatments (coagulation, flocculation, sedimentation, filtration, and disinfection) was also observed. The presence of UV254in both raw water and treated water samples confirmed the presence of NOM. The concentration of UV254recorded at JBWTP and LBWTP were 0.14 and 0.13 cm−1, respectively. After the treatment processes, the concentration was reduced to 0.04 cm−1for JBWTP and 0.03 cm−1for LBWTP. These results indicated that the water supply in both plants contains DBP precursors and implied the possibility of DBP formation in the system. Moreover, the percentage reduction of UV254recorded were 69% and 75% for JBWTP and LBWTP, respectively.


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