scholarly journals Nanoparticles Size Distribution Assessment During Early Synthesis Stages

2021 ◽  
Vol 343 ◽  
pp. 01005
Author(s):  
Dan Chicea ◽  
Mirela Maria Codescu ◽  
Alexandra Nicolae ◽  
Oleksandr Doroshkevych ◽  
Akhmed Islamov ◽  
...  

Nanotechnology, an innovative field of material science, designs and produces nanostructures materials with unique properties that make them suited for various bioengineering applications. The shape and the dimension are the main variables depending on the method of synthesis or chemical precursors. Silver nanoparticles obtained through chemical synthesis exhibit as strong antibacterial effect if their size lays in a well-defined range. However, a small size of such particles, in the range of nanometers to several tens of nanometers, requires specific techniques as Dynamic Light Scattering or Transmission Electron Microscopy, both being affected by certain assumptions or by the high cost and long time required for a measurement. A nonconventional method based on Direct Particle Tracking can be used to produce the particle size distribution in the early nanoparticle synthesis stages. The work presents a realistic computer simulation of nanoparticle diffusion performed with the CHODIN code and a size distribution assessment using a code for Direct Particle Tracking written for this purpose. The results are consistent with the particle size used for simulation and states as a proof of concept for using the Direct Particle Tracking method for particle size distribution in the early stages of nanoparticle synthesis.

Author(s):  
K.H. Ang ◽  
I. Alexandrou ◽  
N.D. Mathur ◽  
R. Lacerda ◽  
I.Y.Y. Bu ◽  
...  

An electric arc discharge in de-ionised water between a solid graphite cathode and an anode made by compressing Ni and C containing powders in a mass ratio of Ni:C = 7:3 was used here to prepare carbon encapsulated Ni nanoparticles in the form of powder suspended in water. The morphology of the produced material was analysed using high resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). The magnetic properties of the samples were determined using a Princeton vibrating sample magnetometer (VSM). Collection of the powder produced from different depths in the water container has proved to be an effective method for obtaining samples with narrow particle size distribution. Further material purification by dry NH4 plasma etching was used to remove the amorphous carbon content of the samples. XRD and HRTEM analysis showed that the material synthesized is fcc Ni particles with mean particle size ranging from 14 to 30 nm encapsulated in 2 to 5 graphitic cages. The data suggests that the process reported has the ability to mass-produce carbon encapsulated ferromagnetic nanoparticles with desired particle size distribution, and hence with controlled size-dependent magnetic properties.


2001 ◽  
Vol 701 ◽  
Author(s):  
Vladimir Privman

ABSTRACTWe outline a theoretical framework for estimating the evolution of the particle size distribution in colloid and nanoparticle synthesis, when the primary growth mode is by externally controlled addition of singlet building blocks. The master equations, analyzed in the leading “non-diffusive” expansion approximation, are reduced to a set of easily numerically programmable relations that yield information on the time evolution of the particle size distribution.


2004 ◽  
Vol 21 (5) ◽  
pp. 372-378 ◽  
Author(s):  
Christiane Finder ◽  
Michael Wohlgemuth ◽  
Christian Mayer

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