Phyto-Functionalized Silver Nanoparticles Derived from Conifer Bark Extracts and Evaluation of Their Antimicrobial and Cytogenotoxic Effects

Silver nanoparticles synthesized using plant extracts as reducing and capping agents showed various biological activities. In the present study, colloidal silver nanoparticle solutions were produced from the aqueous extracts of Picea abies and Pinus nigra bark. The phenolic profile of bark extracts was analyzed by liquid chromatography coupled to mass spectrometry. The synthesis of silver nanoparticles was monitored using UV-Vis spectroscopy by measuring the Surface Plasmon Resonance band. Silver nanoparticles were characterized by attenuated total reflection Fourier transform infrared spectroscopy, Raman spectroscopy, dynamic light scattering, scanning electron microscopy, energy dispersive X-ray and transmission electron microscopy analyses. The antimicrobial and cytogenotoxic effects of silver nanoparticles were evaluated by disk diffusion and Allium cepa assays, respectively. Picea abies and Pinus nigra bark extract derived silver nanoparticles were spherical (mean hydrodynamic diameters of 78.48 and 77.66 nm, respectively) and well dispersed, having a narrow particle size distribution (polydispersity index values of 0.334 and 0.224, respectively) and good stability (zeta potential values of −10.8 and −14.6 mV, respectively). Silver nanoparticles showed stronger antibacterial, antifungal, and antimitotic effects than the bark extracts used for their synthesis. Silver nanoparticles obtained in the present study are promising candidates for the development of novel formulations with various therapeutic applications.

A Novel High-Throughput Chaotic Advection Microreactor for the Preparation of Uniform BaSO4 Nanoparticles

Owing to high mixing efficiency, microreactors are used to synthesize uniform BaSO4 nanoparticles, but application in industrial scale is limited due to poor throughput. In this work, a high-throughput passive four-stage asymmetric oscillating feedback microreactor using chaotic mixing mechanism was developed to prepare BaSO4 nanoparticles of high size uniformity. Three-dimensional unsteady simulations showed that chaotic mixing could be induced by three unique secondary flows (i.e., vortex, recirculation, and oscillation), and the fluid oscillation mechanism was examined in detail. Simulations and Villermaux-Dushman experiments indicate that almost complete mixing in molecular level could be achieved when total volumetric flow rate Qtotal was larger than 10 mL/min, and the prepared BaSO4 nanoparticles were with narrow particle size distribution (PSD). Through the adjustment of Qtotal and reactant concentrations, it is easy to control the average size. An average size of 26 nm with narrow PSD could be achieved at Qtotal = 160 mL/min.

Ultrasonic Synthesis of Nanochitosan and Its Size Effects on Turbidity Removal and Dealkalization in Wastewater Treatment

A detailed study on the synthesis of chitosan nanoparticles under ultrasonication is reported in this paper. By using this simple technique, chitosan particles in nanometer range can be easily prepared without using any harmful and expensive chemicals. The results show that increasing the ultrasonic irradiation time and ultrasonic wave amplitude are the key factors for producing discrete chitosan nanoparticles with narrow particle size distribution. The resulting nanoparticles show superior turbidity removal efficiency (75.4%) and dealkalization (58.3%) in wastewater treatment than the bulk chitosan solid (35.4% and 11.1%, respectively), thus offering an eco-friendly and promising approach for treating wastewater via the coagulation/flocculation process.

Continuous Crystallization Using Ultrasound Assisted Nucleation, Cubic Cooling Profiles and Oscillatory Flow

Continuous tubular crystallizers have the potential to reduce manufacturing costs and increase product quality. However, designing tubular crystallizers is a complex and challenging task as crystallization is a complex, multiphase process with a propensity for fouling and clogging. While several designs have been proposed to overcome these issues, these designs are either unproven or poorly scalable and complex. In this work a continuous crystallizer is designed and evaluated to mitigate these issues. The tubular crystallizer combines a novel method to obtain a cubic cooling profile to control the supersaturation, ultrasound to induce nucleation and oscillatory flow to improve mixing and minimize fouling and sedimentation. The results show that the crystallizer was able to operate for more than 4 h without clogging, with high yields and a narrow particle size distribution. The design proposed here is therefore considered a viable approach for continuous crystallizers.

A Nano Method for a Big Challenge: Nanosilica-Based Sealing System for Water Shutoff

Minimizing unwanted water production from oil wells is highly required in the petroleum industry. This would lead to improved economic life of mature wells that involve new and innovative technologies. Nanosilica-based sealing fluid has been developed to address problems associated with unwanted water production. The objective of this work is to evaluate a newly developed novel water shutoff system based on nanosilica over a wide range of parameters. This modified nanosilica has a smooth, spherical shape, and are present in a narrow particle size distribution. Therefore, it can be used for water management in different water production mechanisms including high permeability streak, wormhole, and fractured reservoirs. A systematic evaluation of novel nanosilica/activator for water shutoff purposes requires the examination of the chemical properties before, during, and after gelation at given reservoir conditions. These properties are solution initial viscosity, gelation time, injectivity, and strength of the formed gel against applied external forces in different flooding systems. This paper details a promising method to control undesired water production using eco-friendly, cost-effective nanosilica. Experimental results revealed that nanosilica initially exhibited a low viscosity and hence providing a significant advantage in terms of mixing and pumping requirements. Nanosilica gelation time, which is a critical factor in placement of injected-chemical treatment, can be tailored by adjusting the activator concentration to match field requirements at the desired temperature. In addition, core flood tests were conducted in carbonate core plugs, Berea sandstone rock, and artificially fractured (metal tube) to investigate the performance of the chemical treatment. Flow tests clearly indicated that the water production significantly dropped in all tested types of rocks. The environmental scanning electron microscope (SEM) results showed the presence of SiO-rich compounds suggesting that the tested nanosilica product filled the porous media; therefore, it blocked the whole core plug. A novel cost-effective sealant that uses nanotechnology to block the near wellbore region has been developed. The performance and methods controlling its propagation rate into a porous medium will be presented. Based on the outcomes, it must be emphasized that these trivial particles have a promising application in the oil reservoir for water shutoff purposes.

Laser synthesis of a weakly agglomerated aluminium oxide nanopowder doped with terbium and ytterbium

This paper describes a method of femtosecond laser synthesis of nanoparticles of powdered aluminum oxide doped with terbium and ytterbium was developed. The formation of a plasma torch of nanoparticles of a powdery material is carried out as a result of ablation under the influence of a sharply focused beam of femtosecond laser radiation with an intensity of 108- 1010W/m2. The radiation source is the TETA-10 laser system. SEM images of the obtained nanopowders are presented. Spherical nanoparticles of narrow particle size distribution in the range from 5 to 15 nm was synthesized with the ability to control the size of nanoparticles by purposefully changing the parameters and characteristics of pulsed radiation in the treatment area. The design of a specialized high-voltage electrostatic precipitator up to 25 kV for capturing ablated nanoparticles in an electron cloud of increased concentration was developed.

Structural and Optical Properties of Silicon Carbide Powders Synthesized from Organosilane Using High-Temperature High-Pressure Method

The development of new strategies for the mass synthesis of SiC nanocrystals with high structure perfection and narrow particle size distribution remains in demand for high-tech applications. In this work, the size-controllable synthesis of the SiC 3C polytype, free of sp2 carbon, with high structure quality nanocrystals, was realized for the first time by the pyrolysis of organosilane C12H36Si6 at 8 GPa and temperatures up to 2000 °C. It is shown that the average particle size can be monotonically changed from ~2 nm to ~500 nm by increasing the synthesis temperature from 800 °C to 1400 °C. At higher temperatures, further enlargement of the crystals is impeded, which is consistent with the recrystallization mechanism driven by a decrease in the surface energy of the particles. The optical properties investigated by IR transmission spectroscopy, Raman scattering, and low-temperature photoluminescence provided information about the concentration and distribution of carriers in nanoparticles, as well as the dominant type of internal point defects. It is shown that changing the growth modes in combination with heat treatment enables control over not only the average crystal size, but also the LO phonon—plasmon coupled modes in the crystals, which is of interest for applications related to IR photonics.

Synergistic Photocatalytic-Adsorption Removal of Basic Magenta Effect of AgZnO/Polyoxometalates Nanocomposites

The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L)2(H2O)]H2[Cu(L)2(P2Mo5O23)]⋅4H2O (HL = C6H6N2O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet–visible spectra (UV–Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane.

Effect of Liquid Feeding Rate on Carbonation of Precipitated Calcium Carbonate via Continuous Method

Precipitated calcium carbonate (PCC) is an innovative product generated from lime that significantly offers various functional characteristics in fulfilling numerous market demand. PCC is produced by hydrating high-calcium quicklime resulting slurry so-called milk-of-lime and reacting the slurry with carbon dioxide (CO2) via carbonation process. The resulting PCC product is extremely white and typically has a uniform narrow particle size distribution. PCC is available in various crystal morphologies and sizes, which can be tailored to optimize performance in a specific application. The final properties of the PCC can be diversified by controlling processing parameters. In this current work, effect of liquid air pressure corresponding to feeding rate on a formation of PCC was investigated. In enhancing the product yield, the quicklime was initially converted into a solution containing calcium ion (Ca2+) using natural promoter agent. Subsequently, CO2 gas was continuously supplied into the Ca-rich ionic solution, thus inducing carbonation reaction to form PCC. This present work showed the carbonation time of producing PCC was effectively reduced as a function of feeding rate from 15 minutes at 10 psi to only 7 minutes at 50 psi. The PCC yield slightly increased from 19 g to 23 g with increasing the feeding rate from 10 psi to 50 psi, respectively. Morphologically, the PCC particles were dominated by rhombohedral structures at various feeding rates with an indication of intergrowth mechanism. This current finding signified the increasing feeding rate offered a significant reduction of PCC production time that might be efficiently applied by the industrial manufacturers.