Effects of alkali metal on solution loss and coke degradation

2019 ◽  
Vol 116 (6) ◽  
pp. 609 ◽  
Author(s):  
Dongsheng Yu ◽  
Rui Guo ◽  
Yinghua Liang ◽  
Lianji Liu ◽  
Peng Chen

To research the effect of alkali metals on the solution-loss rate and coke strength after reaction, potassium and sodium vapors were prepared by a high-temperature thermal-reduction method, and the thermal properties of four industrial cokes that absorbed potassium and sodium vapor were studied. The thermal properties include the traditional thermal-property indices, coke reactive index and coke strength after reaction, and the coke strength after a 25% mass loss, which is obtained by a continuous thermogravimetric test. Results show that because of the different adsorption mode, the catalytic effect of potassium and sodium is different. During the early stages of the solution-loss reaction, the reaction rate of the potassium-rich coke is higher than that of the sodium-rich coke, but the reaction rate decreases rapidly. The reaction rate of the sodium-rich coke in the later stage of the reaction is higher than that of the potassium-rich coke. The coke strength after reaction of the alkali-rich coke is low, mainly because of the high carbon-solution loss. The coke strength after the 25% mass loss of potassium-rich coke was higher than that of the original coke because the solution reaction was closer to the surface reaction.

1990 ◽  
Vol 162 (1) ◽  
pp. K21-K24
Author(s):  
T. Soma ◽  
M. Hasebe ◽  
H.-Matsuo Kagaya

2018 ◽  
Vol 58 (7) ◽  
pp. 1218-1223 ◽  
Author(s):  
Tengfei Song ◽  
Jianliang Zhang ◽  
Guangwei Wang ◽  
Haiyang Wang ◽  
Runsheng Xu

2017 ◽  
Vol 8 (4) ◽  
pp. 392-401 ◽  
Author(s):  
Hassan A.M. Mhamoud ◽  
Jia Yanmin

Purpose This study aims to focus on the resistance to elevated temperatures of up to 700ºC of high-performance concrete (HPC) compared to ordinary Portland concrete (OPC) with regards to mass loss and residual compressive and flexural strength. Design/methodology/approach Two mixtures were developed to test. The first mixture, OPC, was used as the control, and the second mixture was HPC. After 28 days under water (per Chinese standard), the samples were tested for compressive strength and residual strength. Findings The test results showed that at elevated temperatures of up to 500ºC, each mixture experienced mass loss. Below this temperature, the strength and the mass loss did not differ greatly. Originality/value When adding a 10 per cent silica fume, 25 per cent fly, 25 per cent slag to HPC, the compressive strength increased by 17 per cent and enhanced the residual compressive strength. A sharp decrease was observed in the residual flexural strength of HPC when compared to OPC after exposure to temperatures of 700ºC.


Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1493 ◽  
Author(s):  
In-Hwan Yang ◽  
Jihun Park

The thermal conductivity of concrete is a key factor for efficient energy consumption in concrete buildings because thermal conductivity plays a significant role in heat transfer through concrete walls. This study investigated the effects of replacing fine aggregates with coal bottom ash (CBA) and the influence of curing age on the thermal properties of high-strength concrete with a compressive strength exceeding 60 MPa. The different CBA aggregate contents included 25%, 50%, 75%, and 100%, and different curing ages included 28 and 56 days. For concrete containing CBA fine aggregate, the thermal and mechanical properties, including the unit weight, thermal conductivity, compressive strength, and ultrasonic velocity, were measured. The experimental results reveal that the unit weight and thermal conductivity of the CBA concrete were highly dependent on the CBA content. The unit weight, thermal conductivity, and compressive strength of the concrete decreased as the CBA content increased. Relationships between the thermal conductivity and the unit weight, thermal conductivity and compressive strength of the CBA concrete were proposed in the form of exponential functions. The equations proposed in this study provided predictions that were in good agreement with the test results. In addition, the test results show that there was an approximately linear relationship between the thermal conductivity and ultrasonic velocity of the CBA concrete.


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