During the last decades, especially the Eleventh Five-Year Plan period, China vocational education on environmental protection has made remarkable progresses. The vocational education on environmental protection has developed fast and spread widely, and formed an integrity system with various kinds of types. On the basis of analyzing the development status of vocational education in the field of China environmental protection and the cooperative mechanism and operative mode of production, teaching, research and application of partial higher vocational environmental education and environmental majors at home, this paper describes the history and development of vocational education on environmental protection in China and conducted a case study of vocational education on Changsha Environmental Protection Vocational College (CEPVC). The purpose is to identify lessons from past experience in vocational education to inform future development. The retrospective nature of this paper focuses attention on what has been done in the past, and to a lesser extent on the nature of current state. There are significant issues in vocational education, for example, the contribution of training to informal sector employment, that fall largely outside of vocational education experience, this is important for the future.