Room temperature deintercalation of alkali metal atoms from epitaxial graphene by formation of charge-transfer complexes

2016 ◽  
Vol 109 (8) ◽  
pp. 081603 ◽  
Author(s):  
H.-C. Shin ◽  
S. J. Ahn ◽  
H. W. Kim ◽  
Y. Moon ◽  
K. B. Rai ◽  
...  
2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Hulya Demirhan ◽  
Mustafa Arslan ◽  
Mustafa Zengin ◽  
Mustafa Kucukislamoglu

Charge transfer complexes (CTC) of mirtazapine with tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), and tetracyanoquinodimethane (TCNQ) have been studied spectrophotometrically in dichloromethane at room temperature. The stoichiometries of the complexes were found to be 1 : 1 ratio by the Job Method between mirtazapine and the acceptors. The equilibrium constants and thermodynamic parameters of the complexes were determined by the Benesi-Hildebrand and Van't Hoff equations. Mirtazapine in pure and dosage form was applied in this study. The results indicate that the formation constants for the complexes depend on the nature of electron acceptors and donor. And also the spectral studies of the complexes were determined by FT-IR and NMR spectroscopy.


Author(s):  
С.Ю. Давыдов ◽  
А.В. Зубов

Abstract A model of a heterostructure consisting of a silicon-carbide single layer formed on a massive silicon substrate is proposed. The problem of the adsorption of alkali metal atoms and halogen atoms on the carbon and silicon surface atoms of a 2D SiC/Si heterostructure is considered. Analytical estimates for charge transfer and the adsorption energy are reported.


Langmuir ◽  
2014 ◽  
Vol 31 (4) ◽  
pp. 1581-1587 ◽  
Author(s):  
Rajesh Ramanathan ◽  
Sumeet Walia ◽  
Ahmad Esmaielzadeh Kandjani ◽  
Sivacarendran Balendran ◽  
Mahsa Mohammadtaheri ◽  
...  

1967 ◽  
Vol 46 (3) ◽  
pp. 837-842 ◽  
Author(s):  
Hiroo Inokuchi ◽  
Nobuyuki Wakayama ◽  
Tamotsu Kondow ◽  
Yoshihiro Mori

2021 ◽  
Author(s):  
Jacques Lalevée ◽  
Qiang Ma ◽  
Shaohui Liu ◽  
Marie Le Dot ◽  
haifaa Mokbel ◽  
...  

By virtue of remarkable spatial resolution, a metal-free visible LEDs photopolymerization process, initiated by imidazole based charge transfer complexes at mild condition (room temperature, without inert atmosphere, monomer purification or...


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