scholarly journals Interpretation of Young’s equation for a liquid droplet on a flat and smooth solid surface: Mechanical and thermodynamic routes with a simple Lennard-Jones liquid

2019 ◽  
Vol 150 (4) ◽  
pp. 044701 ◽  
Author(s):  
Yasutaka Yamaguchi ◽  
Hiroki Kusudo ◽  
Donatas Surblys ◽  
Takeshi Omori ◽  
Gota Kikugawa
2018 ◽  
Vol 5 (12) ◽  
pp. 181101 ◽  
Author(s):  
Y. Tatekura ◽  
M. Watanabe ◽  
K. Kobayashi ◽  
T. Sanada

The prime objective of this study is to answer the question: How large is the pressure developed at the instant of a spherical liquid droplet impact on a solid surface? Engel first proposed that the maximum pressure rise generated by a spherical liquid droplet impact on a solid surface is different from the one-dimensional water-hammer pressure by a spherical shape factor (Engel 1955 J. Res. Natl Bur. Stand. 55 (5), 281–298). Many researchers have since proposed various factors to accurately predict the maximum pressure rise. We numerically found that the maximum pressure rise can be predicted by the combination of water-hammer theory and the shock relation; then, we analytically extended Engel’s elastic impact model, by realizing that the progression speed of the contact between the gas–liquid interface and the solid surface is much faster than the compression wavefront propagation speed at the instant of the impact. We successfully correct Engel’s theory so that it can accurately provide the maximum pressure rise at the instant of impact between a spherical liquid droplet and solid surface, that is, no shape factor appears in the theory.


1995 ◽  
Vol 117 (3) ◽  
pp. 394-401 ◽  
Author(s):  
Natsuo Hatta ◽  
Hitoshi Fujimoto ◽  
Hirohiko Takuda

This paper is concerned with numerical simulations of the deformation behavior of a liquid droplet impinging on a flat solid surface, as well as the flow field inside the droplet. In the present situation, the case where a droplet impinges on the surface at room temperature with a speed in the order of a few [m/s], is treated. These simulations were performed using the MAC-type solution method to solve a finite-differencing approximation of the Navier-Stokes equations governing an axisymmetric and incompressible fluid flow. For the first case where the liquid is water, the liquid film formed by the droplet impinging on the solid surface flows radially along it and expands in a fairly thin discoid-like shape. Thereafter, the liquid flow shows a tendency to stagnate at the periphery of the circular film, with the result that water is concentrated there is a doughnut-like shape. Subsequently, the water begins to flow backwards toward the center where it accumulates in the central region. For the second case where a n-heptane droplet impinges the surface, the film continues to spread monotonically up to a maximum diameter and there is no recoiling process to cause a backwards flow towards the central region. In this study the whole deformation process was investigated from numerical as well as experimental points of view. We find that the results obtained by the present mathematical model give fairly good agreement with the experimental observations. The effects of the viscous stresses and the surface tension on the deformation process of the droplets are estimated and discussed from a practical standpoint.


Author(s):  
Kamaljit Singh ◽  
Saurabh Baghmar ◽  
Jagdish Sharma ◽  
M. V. Khemchandani ◽  
Q. J. Wang

The interaction between lubricant molecules and the solid surface to be lubricated depends upon the surface forces which can be attractive, and repulsive. It thus forms an interactive zone above the solid surface having a band width and height of surface potential and is considered as ‘Zone of Influence’-(ZOI). Its value will vary with the nature of surface finish, distribution of alloying constituents on surface matrix and its size which play very important role in prediction of stability and failure of boundary lubrication friction including absorption and desorption of lubricant molecules. A theoretical model for the formation of boundary lubrication is proposed by combining Lennard Jones (6–12) potential to incorporate for estimating the critical temperature of boundary lubricant, friction coefficient and variation of ZOI for a given condition. Experimental values using EN 31 Ball sliding against the aluminum surface with 0.4% stearic acid as lubricant data agrees well with theoretical values.


2015 ◽  
Vol 5 (2) ◽  
pp. 17
Author(s):  
Xiao-Song Wang

<p class="1Body">The surface tension depends on the radius of curvature of the liquid-vapor interface. For nano-scale wetting phenomena of cylindrical droplets, we should consider the curvature effects of the surface tension and the line tension. However, previous works have not analyzed the influence of the curvature effects of the surface tension. In this paper, we discuss the influence of the curvature effects of the surface tension on the contact angles based the Kim-Lee-Han-Park equation. The hydrophilic wetting of cylindrical droplets on rough and chemically homogeneous non-deformable substrates were studied by methods of thermodynamics. A generalized Young’s equation for wetting of cylindrical droplets on chemically homogeneous and rough non-deformable substrates was derived based on the thermodynamic equilibrium conditions. This equation reduces to the Wenzel equation if we ignore the influence of line tension. For contact angles of cylindrical droplets with sufficiently large radii, a generalized Young’s equations were derived considering the curvature effects of the surface tension.</p>


1995 ◽  
Vol 294 ◽  
pp. 209-230 ◽  
Author(s):  
Marc K. Smith

A two-dimensional liquid droplet placed on a non-uniformly heated solid surface will move towards the region of colder temperatures if the temperature gradient in the solid surface is large enough. Such behaviour is analysed for a thin viscous droplet using lubrication theory to develop an evolution equation for the shape of the droplet. For the small mobility capillary numbers examined in this work, the contact-line motion is controlled by a dynamic relationship posed between the contact-line speed and the apparent contact angle. Results are obtained numerically and also approximately using a perturbation technique for small heating. The initial spreading or shrinking of the droplet when placed on the heated solid is biased toward the direction of decreasing temperature on the solid. Possible steady-state responses are either a motionless droplet or one moving at a constant velocity down the temperature gradient without change in shape. These behaviours are the result of a thermocapillary recirculation cell inside the droplet that distorts the free surface and alters the apparent contact angles. This change in the apparent contact angles then modifies the contact-line speed.


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