scholarly journals Direct detection of rare earth ion distributions in gallium nitride and its influence on growth morphology

2020 ◽  
Vol 127 (1) ◽  
pp. 013102 ◽  
Author(s):  
B. Mitchell ◽  
D. Timmerman ◽  
W. Zhu ◽  
J. Y. Lin ◽  
H. X. Jiang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Gallium Nitride ◽  
Direct Detection ◽  
Growth Morphology ◽  
Rare Earth Ion ◽  
Ion Distributions

Nanocrystalline Rare Earth-doped Gallium Nitride Phosphor Powders

2005 ◽  
Vol 866 ◽  
Author(s):  
G.A. Hirata ◽  
J. Tao ◽  
P. Chen ◽  
K.C. Mishra ◽  
J. McKittrick
Keyword(s):  
Rare Earth ◽  
Gallium Nitride ◽  
High Purity ◽  
Photoelectron Spectroscopy ◽  
Single Phase ◽  
Luminescent Properties ◽  
Nanocrystalline Powder ◽  
Rare Earth Ion ◽  
Chemical Route ◽  
Rare Earth Doped

AbstractWe report on the fabrication and luminescent properties of rare earth-doped gallium nitride (GaN) phosphor powders. Single phase GaN and GaN:RE3+ powders were prepared by using a novel chemical route.In this work a new method for the synthesis of high purity, single phase doped GaN powders is reported. (Ga1-xREx)N powders are obtained by dissolving metal nitrates (Ga(NO3)3, (RE(NO3)3) in deionized water and an organic fuel (hydrazine) in order to form a gallium/RE amorphous/nanocrystalline powder. The RE-oxide powders are then reacted with heated ammonia at different temperatures and processing times producing GaN:RE phosphors. X-ray diffraction analysis showed that single phase GaN powders are formed. Preliminary results show (Ga0.95Eu0.05)N powders are luminescent, with the main emission occurring at 611 nm which is due to the 5Do→7F2 transitions in Eu3+. High-purity GaN powders are obtained according to Xray photoelectron spectroscopy (XPS) chemical analysis. Low-temperature cathodoluminescence and photoluminescence measurements indicate that the emission at λ=611 nm is originated from energy transfer from the host to the rare earth ion and to a direct excitation to the Eu3+ electronic levels.This method can be used to obtain red-luminescence GaN:Eu3+ and other rare earth (e.g. Er, Tb, Tm)-doped GaN powders to produce green and blue luminescence as well.

scholarly journals Structure, Luminescence, and Magnetic Properties of Crystalline Manganese Tungstate Doped with Rare Earth Ion

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3717
Author(s):  
Jae-Young Jung ◽  
Soung-Soo Yi ◽  
Dong-Hyun Hwang ◽  
Chang-Sik Son
Keyword(s):  
Magnetic Field ◽  
Rare Earth ◽  
Sintering Temperature ◽  
Luminescent Properties ◽  
Concentration Quenching ◽  
Rare Earth Ions ◽  
Precipitation Method ◽  
Rare Earth Ion ◽  
Co Precipitation ◽  
Quenching Phenomenon

The precursor prepared by co-precipitation method was sintered at various temperatures to synthesize crystalline manganese tungstate (MnWO4). Sintered MnWO4 showed the best crystallinity at a sintering temperature of 800 °C. Rare earth ion (Dysprosium; Dy3+) was added when preparing the precursor to enhance the magnetic and luminescent properties of crystalline MnWO4 based on these sintering temperature conditions. As the amount of rare earth ions was changed, the magnetic and luminescent characteristics were enhanced; however, after 0.1 mol.%, the luminescent characteristics decreased due to the concentration quenching phenomenon. In addition, a composite was prepared by mixing MnWO4 powder, with enhanced magnetism and luminescence properties due to the addition of dysprosium, with epoxy. To one of the two prepared composites a magnetic field was applied to induce alignment of the MnWO4 particles. Aligned particles showed stronger luminescence than the composite sample prepared with unsorted particles. As a result of this, it was suggested that it can be used as phosphor and a photosensitizer by utilizing the magnetic and luminescent properties of the synthesized MnWO4 powder with the addition of rare earth ions.

scholarly journals Conduction-band states and the 5d-4f laser transition of rare-earth ion dopants

1997 ◽  
Author(s):  
Stephen A. Payne ◽  
Christopher D. Marshall ◽  
Andy J. Bayramian ◽  
Janice K. Lawson
Keyword(s):  
Rare Earth ◽  
Conduction Band ◽  
Rare Earth Ion ◽  
Laser Transition

Photon echoes in an amplifying rare-earth ion-doped crystal

2006 ◽  
Author(s):  
V. Crozatier ◽  
G. Gorju ◽  
F. Bretenaker ◽  
J.-L. Le Gouet ◽  
I. Lorgere ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Ion ◽  
Photon Echoes

Rare-earth-ion-size control on magnetic irreversibility field in CuBa2RECu2O7−δ

2001 ◽  
Vol 357-360 ◽  
pp. 230-233 ◽  
Author(s):  
Yukiko Yasukawa ◽  
Takayuki Nakane ◽  
Maarit Karppinen ◽  
Hisao Yamauchi
Keyword(s):  
Rare Earth ◽  
Size Control ◽  
Irreversibility Field ◽  
Rare Earth Ion ◽  
Magnetic Irreversibility ◽  
Ion Size

Internal Friction Study of the Rare Earth Ion Substituted Fast Oxide-Ion Conductors (La1-ΧreΧ)2Mo2O9 (Re=Nd, Gd)

2012 ◽  
Vol 184 ◽  
pp. 110-115
Author(s):  
X.P. Wang ◽  
J. Hu ◽  
Zhong Zhuang ◽  
Tao Zhang ◽  
Qian Feng Fang
Keyword(s):  
Phase Transition ◽  
Rare Earth ◽  
Internal Friction ◽  
Diffusion Processes ◽  
Rare Earth Ion ◽  
Disorder Transition ◽  
Oxide Ion Conductors ◽  
Oxide Ion ◽  
The Rare Earth ◽  
Ion Conductors

The relaxation and phase transition behaviors of rare-earth ion substituted fast oxide-ion conductors (La1-xRex)2Mo2O9 (Re=Nd, Gd) were investigated by internal friction (IF) measurement in the temperature range 300 K - 950 K. Three different IF peaks (labeled as PL, PH, and PG, respectively) were observed in the rare-earth ion doped La2Mo2O9 samples. Peak PL corresponds to short diffusion processes of oxygen ions among different oxygen vacancy sites. Peak PH is associated with the static/dynamic disorder transition in oxygen ion distribution. Peak PG is a newly discovered peak embodying phase transition-like characteristics and is suggested to be related to order-disorder transition associated with the rearrangement of La/ Re sub-lattice.

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