Correlation of polymer concentration with the membrane performance of polyethersulfone membrane for humic acid removal

2021 ◽  
Author(s):  
N. N. Tan ◽  
Q. H. Ng ◽  
S. K. Enche AB Rahim ◽  
C. W. Heah ◽  
S. H. Shuit ◽  
...  
2020 ◽  
Vol 2020 ◽  
pp. 1-7
Author(s):  
Huda AlFannakh ◽  
Heba Abdallah ◽  
S. S. Ibrahim ◽  
Basma Souayeh

Three ultrafiltration membranes were prepared using phase separation techniques. The membranes were characterized by scan electron microscope, porosity, pore size distribution measurement, and mechanical properties. The membrane performance was carried out using synthetic solutions from humic acid and tap water to express the contaminated drinking water. The polyvinylidene difluoride (M2) has the highest tensile strength 33.2 MPa with elongation of 52.3%, while polyacrylonitrile (M3) has the lowest mechanical properties, tensile strength 16.4 MPa with elongation of 42.7%. Polyethersulfone membrane (M1) provides the highest removal of humic acid, which was 99.5, 98.8, and 98.2% using feed concentrations 0.1, 0.3, and 0.5 g/l, respectively, while M3 provides the highest permeate flux which was 250, 234.4, and 201.4 l/m2 h using feed concentrations 0.1, 0.3, and 0.5 g/l, respectively. Analysis of water samples indicates that the prepared membranes can be used to treat the contaminated drinking water which produced the high quality of drinking water after treatment.


2013 ◽  
Vol 372 ◽  
pp. 3-7 ◽  
Author(s):  
Muhamad Fikri Shohur ◽  
Zawati Harun ◽  
Muhamad Zaini Yunos ◽  
Sulaiman Hassan ◽  
Mohd Riduan Jamalludin

This study investigates the effect of Sodium Chloride (NaCl) coagulant medium with different concentration to produce Polysulfone (PSf) ultrafiltration (UF) asymmetric membrane. The polymer membrane prepared by a phase inversion method using Polysulfone (PSf) as a base polymer, Polyethylene glycol (PEG) 400MW as copolymer additive, N-methyl-2-pyrrolidone (NMP) as solvent and NaCl coagulant medium with different concentration as nonsolvent. In this work, the concentration of immersion medium for membrane phase immersion process prepared based on different coagulation concentration medium NaCl was modified repeatedly in the range of 1-5%. These membrane performance were analyzed via pure water permeation and solute rejection of humic acid. Based on these results, the membrane immersed in 4% concentration of NaCl coagulant medium showed the highest pure water permeation (235.69 l.m-2. h-1) and solute rejection of humic acid which is up to 98%.


Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1446 ◽  
Author(s):  
Nyiko M. Chauke ◽  
Richard M. Moutloali ◽  
James Ramontja

ZSM-22/polyethersulfone membranes were prepared for salt rejection using modelled brackish water. The membranes were fabricated via direct ZSM-22 incorporation into a polymer matrix, thereby inducing the water permeability, hydrophilicity and fouling resistance of the pristine polyethersulfone (PES) membrane. A ZSM-22 zeolite material with a 60 Si/Al ratio, high crystallinity and needle-like morphologies was produced and effectively used as a nanoadditive in the development of ZSM-22/PES membranes with nominal loadings of 0–0.75 wt.%. The characterisation and membrane performance evaluation of the resulting materials with XRD, BET, FTIR, TEM, SEM and contact angle as well as dead-end cell, respectively, showed improved water permeability in comparison with the pristine PES membrane. These ZSM-22/PES membranes were found to be more effective and superior in the processing of modelled brackish water. The salt rejection of the prepared membranes for NaCl and MgCl2 was effective, while they exhibited quite improved water flux and flux recovery ratios in the membrane permeability and anti-fouling test. This indicates that different amounts of ZSM-22 nanoadditives produce widely divergent influences on the performance of the pristine PES membrane. As such, over 55% of salt rejection is observed, which means that the obtained membranes are effective in salt removal from water.


Membranes ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 239
Author(s):  
Mariane Carolina Proner ◽  
Ingrid Ramalho Marques ◽  
Alan Ambrosi ◽  
Katia Rezzadori ◽  
Cristiane da Costa ◽  
...  

The mussel-inspired method has been investigated to modify commercial ultrafiltration membranes to induce antifouling characteristics. Such features are essential to improve the feasibility of using membrane processes in protein recovery from waste streams, wastewater treatment, and reuse. However, some issues still need to be clarified, such as the influence of membrane pore size and the polymer concentration used in modifying the solution. The aim of the present work is to study a one-step deposition of dopamine (DA) and polyethyleneimine (PEI) on ultrafiltration membrane surfaces. The effects of different membrane molecular weight cut-offs (MWCO, 20, 30, and 50 kDa) and DA/PEI concentrations on membrane performance were assessed by surface characterization (FTIR, AFM, zeta potential, contact angle, protein adsorption) and permeation of protein solution. Results indicate that larger MWCO membranes (50 kDa) are most benefited by modification using DA and PEI. Moreover, PEI is primarily responsible for improving membrane performance in protein solution filtration. The membrane modified with 0.5:4.0 mg mL−1 (DA: PEI) presented a better performance in protein solution filtration, with only 15% of permeate flux drop after 2 h of filtration. The modified membrane can thus be potentially applied to the recovery of proteins from waste streams.


2013 ◽  
Vol 65 (4) ◽  
Author(s):  
Mohd Riduan Jamalludin ◽  
Zawati Harun ◽  
Hatijah Basri ◽  
Muhamad Zaini Yunos ◽  
Muhamad Fikri Shohur ◽  
...  

In the present work, the effect of rice husk silica (RHS) on the performance of polysulfone (PSf) blended with polyethylene glycol (PEG) membranes were investigated. The hybrid ultrafiltration membranes were prepared by phase inversion technique. The membrane performance was analyzed by using pure water flux, humic acid for the rejection test and followed by the membrane characterization. Results showed that PEG increased membrane pure water flux to 621.212 LMH and rejection humic acid at and 98%. The analysis of SEM revealed that PEG obviously changed the microstructure of the membrane especially at the top and sub layer.


2018 ◽  
Vol 2017 (2) ◽  
pp. 329-339 ◽  
Author(s):  
Sevgi Güneş-Durak ◽  
Türkan Ormancı-Acar ◽  
Neşe Tüfekci

Abstract In this study, four different membranes were fabricated by using polyetherimide and polyacrylonitrile polymers, N-methyl-2-pyrrolidone and polyvinylpyrrolidone (PVP) via phase inversion method to improve the membrane performance in fruit juice wastewater (FJWW) treatment. The addition of PVP to the casting solution increased membrane hydrophilicity, water content, contact angle, porosity, Fourier transform infrared spectroscopy peaks, membrane thickness, average roughness and viscosity of cast solutions compared to the bare membrane. It can be said that the addition of a lower polymer concentration and PVP intensively increases the pure water flux of the membrane. However, as the flux increased, a small decrease in FJWW rejection was observed.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Azam Marjani ◽  
Ali Taghvaie Nakhjiri ◽  
Maryam Adimi ◽  
Hassan Fathinejad Jirandehi ◽  
Saeed Shirazian

2018 ◽  
Vol 55 (1) ◽  
pp. 95-98 ◽  
Author(s):  
Laurentia Geanina Tiron ◽  
Stefan Catalin Pintilie ◽  
Andreea Liliana Lazar ◽  
Maria Vlad ◽  
Stefan Balta ◽  
...  

Water is an important element of life, while every industry in its processes uses an important amount of water. Following processes, the water is contaminated and requires water treatment technologies. Unconventional methods to wastewater treatment, in the last years, use membrane technology as one of the most reliable processes for contaminants removal. In this article, the influence of the different concentrations of polysulfone (PSf) on the polymeric membranes properties was studied. These membranes were obtained through phase inversion method and with different polymer concentrations: 23, 25, 27 and 30 wt.%. The performance of the membranes was studied by pure water flux, permeability and retention. It has been observed that by increasing the polymer concentration, the pure water flux and the permeability will decrease. Retention was determined using methylene blue, which is one of the most utilized dye from industry and it could be observed that by increasing the polymer concentration the retention degree of the pollutant also increases. In order to explain the evolution of membrane permeability at different polymer concentrations, surface hydrophilicity by contact angle method and cross-section SEM imaging were used.


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