The blending effect of Sumatran crude oil on wax deposition through flow assurance simulation

2021 ◽  
Author(s):  
Ferdio Giffary ◽  
Achmad Anggawirya Alimin ◽  
Bambang Heru Susanto
Author(s):  
Gaurav Himanta Khaklari ◽  
Prasenjit Talukdar

Crude oil needs to be transported from oil wells to refinery and storage facilities in one form or another to ultimately become end use products. After the successful extraction of oil from the ground it is mostly transported through pipelines where the crude oil experiences various changes in its physical and chemical properties. These rheological changes may cause numerous flow assurance problems such as wax and paraffin deposition which ultimately restricts the flow of oil. Chemical additives such as Pour Point depressants (PPDs) are used in this case for the efficient transportation of crude oil by lowering the Wax Deposition Temperature (WAT). Hence, in order to enhance the knowledge about PPDs, the mechanism of various types of Pour Point Depressant for aiding the flow of crude oil while transportation were discussed in this paper.


Energies ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 4325
Author(s):  
Zhihua Wang ◽  
Yunfei Xu ◽  
Yi Zhao ◽  
Zhimin Li ◽  
Yang Liu ◽  
...  

Wax deposition during crude oil transmission can cause a series of negative effects and lead to problems associated with pipeline safety. A considerable number of previous works have investigated the wax deposition mechanism, inhibition technology, and remediation methods. However, studies on the shearing mechanism of wax deposition have focused largely on the characterization of this phenomena. The role of the shearing mechanism on wax deposition has not been completely clarified. This mechanism can be divided into the shearing dispersion effect caused by radial migration of wax particles and the shearing stripping effect caused by hydrodynamic scouring. From the perspective of energy analysis, a novel wax deposition model was proposed that considered the flow parameters of waxy crude oil in pipelines instead of its rheological parameters. Considering the two effects of shearing dispersion and shearing stripping coexist, with either one of them being the dominant mechanism, a shearing dispersion flux model and a shearing stripping model were established. Furthermore, a quantitative method to distinguish between the roles of shearing dispersion and shearing stripping in wax deposition was developed. The results indicated that the shearing mechanism can contribute an average of approximately 10% and a maximum of nearly 30% to the wax deposition process. With an increase in the oil flow rate, the effect of the shearing mechanism on wax deposition is enhanced, and its contribution was demonstrated to be negative; shear stripping was observed to be the dominant mechanism. A critical flow rate was observed when the dominant effect changes. When the oil flow rate is lower than the critical flow rate, the shearing dispersion effect is the dominant effect; its contribution rate increases with an increase in the oil flow temperature. When the oil flow rate is higher than the critical flow rate, the shearing stripping effect is the dominant effect; its contribution rate increases with an increase in the oil flow temperature. This understanding can be used to design operational parameters of the actual crude oil pipelines and address the potential flow assurance problems. The results of this study are of great significance for understanding the wax deposition theory of crude oil and accelerating the development of petroleum industry pipelines.


SPE Journal ◽  
2021 ◽  
pp. 1-13
Author(s):  
Biswadeep Pal ◽  
Tarun Kumar Naiya

Summary Pour-point depressants (PPDs) were synthesized from natural sources and used in waxy crude oil transportation to reduce the pour point and improve flow. A biodegradable PPD (BPPD) was synthesized and tested to mitigate crude oil flow assurance problems in the present work. The transesterification process was used to synthesize coconut oil ethyl ester (COEE, termed as BPPD). Fourier transform electron spectroscopy (FTIR), proton nuclear magnetic resonance (H-NMR), and microscopic analysis were performed for better understanding of mechanisms for both BPPD and a commercially available PPD named PPD-A. The pour point of crude oil was reduced by 12 and 9°C after the addition of 800 ppm BPPD and PPD-A, respectively. The microscopic analysis confirms that the crystals of wax converted to very fine and dispersed particles during mixing of additives, which in turn increase flowability. BPPD performs better to reduce interfacial tension than PPD-A. The maximum reduction of 19% in interfacial tension was observed after the addition of 800 ppm BPPD. BPPD alters the wettability of the pipeline surface from intermediate wet to water-wet within 60 seconds, which results in reduced slip velocity and consequently lessens the deposition of wax. As a result, crude oils will not stick to the wall of the pipe surface and will experience less resistance to flow through pipelines. FTIR analysis indicated that long-chain alkane and aromatic groups are responsible for a higher pour point, and their concentration level was reduced after the addition of BPPD. The viscosity of crude oil was reduced by almost 94% after the addition of 800 ppm BPPD with crude oil, which in turn minimizes pumping costs for crude oil. As a result, the total project cost was reduced substantially. Biodegradability tests confirm that the BPPD is biodegradable and nontoxic. Due to its biodegradability and nontoxic nature, BPPD has a promising capacity to be used in the petroleum industry for easier pipeline transportation of waxy crude.


2018 ◽  
Vol 32 (10) ◽  
pp. 10605-10615 ◽  
Author(s):  
Haoran Zhu ◽  
Chuanxian Li ◽  
Fei Yang ◽  
Hongye Liu ◽  
Dinghong Liu ◽  
...  

Processes ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 1572
Author(s):  
Bin Yao ◽  
Deyin Zhao ◽  
Zhi Zhang ◽  
Cheng Huang

The Shunbei crude oil pipeline is prepared to use the unheated transportation process to transport waxy crudes. However, the wax formation in the pipeline is unknown. In order to predict the wax deposition of the pipeline, the physical property experiment of Shunbei crude oil was carried out through field sampling. The density, freezing point, hydrocarbon composition, and viscosity–temperature characteristics of crude oil are obtained. The cloud point and wax precipitation characteristics of the crude oil were obtained using the differential scanning calorimetry (DSC) thermal analysis method. Then, the wax deposition rate of the pipeline was predicted by two methods: OLGA software and wax deposition kinetic model. Finally, the optimal pigging cycle of the pipeline was calculated on this basis. The results show that: Shunbei crude oil is a light crude oil with low wax content, a low freezing point, and a high cloud point. Comparing the OLGA simulation results with the calculation results of the Huang Qiyu model, the development trend of wax deposition along the pipeline was the same under different working conditions. The relative error of the maximum wax layer thickness was 6%, proving that it is feasible for OLGA to simulate wax deposition in long-distance crude oil pipelines. Affected by the wax precipitation characteristics of Shunbei crude oil, there was a peak of wax precipitation between the pipeline section where crude oil temperature was 9.31–13.31 °C and the recommended pigging cycle at the lowest throughput was 34 days in winter and 51 days in spring and autumn.


2017 ◽  
Vol 35 (18) ◽  
pp. 1831-1838 ◽  
Author(s):  
Ashish Dewangan ◽  
Ashok Kumar Yadav

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