scholarly journals The Room Temperature Elastic Behaviour of CsH2PO4

1985 ◽  
Vol 38 (1) ◽  
pp. 63 ◽  
Author(s):  
S Prawer ◽  
TF Smith ◽  
TR Finlayson

The components of the elastic constant matrix of monoclinic caesium dihydrogen phosphate (CDP) have been determined using ultrasonic velocity measurements to be Cl1 = 28� 83 � 0 '43, C22 = 26�67 � O� 37, C33 = 65 �45 � 0'48, C44 = 8 .1O� 0,15, Css = 5 �20� 0,24, C66 = 9�17 � 0,22, C12 = 1l'4�3'6, C13 = 42�87�1�58, CIS = 5'13�0'67, C23 = 14�5�4�4, C 2S = 8'4�4'3, C3S = 7�50�0�81 and C46 = -2�25�0�31 GPa. Calculations of the velocity surfaces, ray directions, Young's modulus surfaces and linear compressibility show marked elastic anisotropy, which has been correlated with the chain and layer-like structure of CDP.

2020 ◽  
Vol 21 (3) ◽  
pp. 781
Author(s):  
Isabel Iglesias ◽  
José A. Huidobro ◽  
Belén F. Alfonso ◽  
Camino Trobajo ◽  
Aránzazu Espina ◽  
...  

The hydrothermal synthesis and both the chemical and structural characterization of a diamin iron phosphate are reported. A new synthetic route, by using n-butylammonium dihydrogen phosphate as a precursor, leads to the largest crystals described thus far for this compound. Its crystal structure is determined from single-crystal X-ray diffraction data. It crystallizes in the orthorhombic system (Pnma space group, a = 10.1116(2) Å, b = 6.3652(1) Å, c = 7.5691(1) Å, Z = 4) at room temperature and, below 220 K, changes towards the monoclinic system P21/n, space group. The in situ powder X-ray thermo-diffraction monitoring for the compound, between room temperature and 1100 K, is also included. Thermal analysis shows that the solid is stable up to ca. 440 K. The kinetic analysis of thermal decomposition (hydrogenated and deuterated forms) is performed by using the isoconversional methods of Vyazovkin and a modified version of Friedman. Similar values for the kinetic parameters are achieved by both methods and they are checked by comparing experimental and calculated conversion curves.


2014 ◽  
Vol 2014 ◽  
pp. 1-6
Author(s):  
S. V. San’kova ◽  
N. M. Shkatulyak ◽  
V. V. Usov ◽  
N. A. Volchok

The measuring of the constants of single-crystals requires the availability of crystals of relatively big size. In this paper the elastic constants of the single crystals of magnesium alloy with zinc, zirconium, and rare earth metals (REM) were determined by means of the experimental anisotropy of Young’s modulus and integral characteristics of texture (ICT), which were found from pole figures. Using these constants the anisotropy of Young’s modulus of alloy sheet ZE10 was calculated. Deviation of calculated values from experimental values did not exceed 2%.


1986 ◽  
Vol 108 (2) ◽  
pp. 141-148 ◽  
Author(s):  
H. C. Park ◽  
Y. K. Liu ◽  
R. S. Lakes

The elastic Young’s modulus and shear modulus of bone-particle impregnated polymethylmethacrylate (PMMA) has been measured experimentally at room temperature as a function of bone particle concentration. It was found that the moduli increased with increasing bone particle content. This increase was less than the stiffness increase predicted by higher-order composite theory [1, 2] under the assumption of perfect bonding between particles and matrix. It was concluded that a bond existed but that it was not a perfect bond.


2009 ◽  
Author(s):  
G. V. S. Murthy ◽  
Kumar Anish ◽  
G. Sridhar ◽  
T. Jayakumar ◽  
R. N. Ghosh ◽  
...  

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