Comparison of the particulate organic carbon and permanganate oxidation methods for estimating labile soil organic carbon

Soil Research ◽  
2006 ◽  
Vol 44 (3) ◽  
pp. 255 ◽  
Author(s):  
J. O. Skjemstad ◽  
R. S. Swift ◽  
J. A. McGowan

Forty-four soils from under native vegetation and a range of management practices following clearing were analysed for ‘labile’ organic carbon (OC) using both the particulate organic carbon (POC) and the 333 mm KmnO4 (MnoxC) methods. Although there was some correlation between the 2 methods, the POC method was more sensitive by about a factor of 2 to rapid loss in OC as a result of management or land-use change. Unlike the POC method, the MnoxC method was insensitive to rapid gains in TOC following establishment of pasture on degraded soil. The MnoxC method was shown to be particularly sensitive to the presence of lignin or lignin-like compounds and therefore is likely to be very sensitive to the nature of the vegetation present at or near the time of sampling and explains the insensitivity of this method to OC gain under pasture. The presence of charcoal is an issue with both techniques, but whereas the charcoal contribution to the POC fraction can be assessed, the MnoxC method cannot distinguish between charcoal and most biomolecules found in soil. Because of these limitations, the MnoxC method should not be applied indiscriminately across different soil types and management practices.

Author(s):  
Magdalena Banach-Szott ◽  
Bozena Debska ◽  
Erika Tobiasova

AbstractMany studies report organic carbon stabilization by clay minerals, but the effects of land use and soil type on the properties of humic acids (HAs) are missing. The aim of the paper is to determine the effects of land use and soil types on the characteristics of HAs, which have a considerable influence on organic matter quality. It was hypothesised that the effect of the land use on HAs properties depends on the particular size distribution. The research was performed in three ecosystems: agricultural, forest, and meadow, located in Slovakia. From each of them, the samples of 4 soil types were taken: Chernozem, Luvisol, Planosol, and Cambisol. The soil samples were assayed for the content of total organic carbon (TOC) and the particle size distribution. HAs were extracted with the Schnitzer method and analysed for the elemental composition, spectrometric parameters in the UV-VIS range, and hydrophilic and hydrophobic properties, and the infrared spectra were produced. The research results have shown that the properties of HAs can be modified by the land use and the scope and that the direction of changes depends on the soil type. The HAs of Chernozem and Luvisol in the agri-ecosystem were identified with a higher “degree of maturity”, as reflected by atomic ratios (H/C, O/C, O/H), absorbance coefficients, and the FT-IR spectra, as compared with the HAs of the meadow and forest ecosystem. However, as for the HAs of Cambisol, a higher “degree of maturity” was demonstrated for the meadow ecosystem, as compared with the HAs of the agri- and forest ecosystem. The present research has clearly identified that the content of clay is the factor determining the HAs properties. Soils with a higher content of the clay fraction contain HAs with a higher “degree of maturity”.


2019 ◽  
Vol 35 (3) ◽  
pp. 433-442 ◽  
Author(s):  
Stoécio Malta Ferreira Maia ◽  
Giordano Bruno Medeiros Gonzaga ◽  
Leilane Kristine dos Santos Silva ◽  
Guilherme Bastos Lyra ◽  
Tâmara Cláudia de Araújo Gomes

2019 ◽  
pp. 1-107 ◽  
Author(s):  
Thangavel Ramesh ◽  
Nanthi S. Bolan ◽  
Mary Beth Kirkham ◽  
Hasintha Wijesekara ◽  
Manjaiah Kanchikerimath ◽  
...  

2014 ◽  
Vol 6 (1) ◽  
pp. 35-70 ◽  
Author(s):  
L. Parras-Alcántara ◽  
B. Lozano-García

Abstract. Soil organic carbon (SOC) concentration is a soil variable subject to changes. In agricultural soils, the management system is a key factor that influence to these changes. For determine the management system effects on SOC stocks (SOC-S) in olive groves, 114 soil profiles were studied in the Los Pedroches Valley (Mediterranean rangelands – southern Spain) for long-term (20 yr). The management practices were conventional tillage (CT) and organic farming (OF) in four soil types: Cambisols (CM), Regosols (RG), Luvisols (LV) and Leptosols (LP). Soil properties were statistically analyzed by management techniques, soil types and horizons. The principal components analyses identified four factors that explained 65% of the variance. Also, significant differences (p < 0.05) were found between soil types and management techniques. Equally was observed that the management system affected to SOC-S. In addition, the total SOC-S for 20 yr increased in OF with respect to CT by 72% and 66% in CM and LV respectively. The SOC showed significant differences for horizons (p < 0.05) in relation to the management types. The stratification ratio index of SOC was >2 in all studied soils. These results indicate high soils quality, and that management practices affect to SOC store in the Los Pedroches Valley.


2020 ◽  
Author(s):  
Klaus Jarosch ◽  
Luis Carlos Colocho Hurtarte ◽  
Konstantin Gavazov ◽  
Aleksander Westphal Muniz ◽  
Christoph Müller ◽  
...  

&lt;p&gt;The conversion of tropical forest for cassava cultivation is widely known to decrease the soil organic matter (OM) and nutrient contents of highly weathered soils in the tropics. Amazonian Dark Earth (ADE) might be affected less due to their historical anthropogenic amelioration with e.g. charcoal, ceramics and bones, leading to higher soil OM and nutrient concentrations. In this study, we analysed the effect of land use change on the OM dynamics and its composition under tropical conditions, using ADE and an adjacent Acrisol (ACR) as model systems. Soil samples were obtained south of Manaus (Brazil), from a secondary forest and an adjacently located 40-year-old cassava plantation. The land use change induced a severe decrease of organic carbon (OC) concentrations in ADE (from 35 to 15&amp;#160;g&amp;#160;OC&amp;#160;kg&lt;sup&gt;&amp;#8209;1&lt;/sup&gt;) while OC in the adjacent ACR was less affected (18 to 16&amp;#160;g&amp;#160;OC&amp;#160;kg&lt;sup&gt;&amp;#8209;1&lt;/sup&gt;). Soils were analysed by &lt;sup&gt;13&lt;/sup&gt;C NMR spectroscopy to obtain information on how the conversion of secondary forest to cassava affected the chemical composition of OM. Our results show that land use change induces differences in the OM composition: The OM in ADE changes to a more decomposed state (increase of alkyl:O/N-alkyl ratio) whereas the OM in ACR changes to a less decomposed state (decrease of alkyl:O/N-alkyl ratio). According to a molecular mixing model, land use change influenced mostly the proportion of lipids, which might be related with a change of the plant input. The incubation of the soils with &lt;sup&gt;13&lt;/sup&gt;C glucose enabled resolving how soil microorganisms were affected by land use change. In both soil types ADE and ACR, land use change caused a reduction of the total &lt;sup&gt;13&lt;/sup&gt;C glucose respiration by approximately one third in a 7-days incubation, implying lower microbial activity. Microorganisms in both soil types appear to be more readily active in soils under forest, since we observed a distinct lag time between &lt;sup&gt;13&lt;/sup&gt;C glucose addition and respiration under cassava planation. This indicated differences in microbial community structure, which we will assess further by determining the &lt;sup&gt;13&lt;/sup&gt;C label uptake by the microbial biomass and the microbial community structure using &lt;sup&gt;13&lt;/sup&gt;C PLFA analysis. Preliminary results from synchrotron-based STXM demonstrate a distinct arrangement of OM at fine-sized charcoal-particle interfaces. Samples of soils receiving &lt;sup&gt;13&lt;/sup&gt;C label will be further analysed by NanoSIMS with the hypothesis that charcoal interfaces foster nutrient dynamics at the microscale. Despite the high loss of OC in the ameliorated ADE through land use change, the remaining OM might improve the nutrient availability thanks to charcoal interactions compared to the ACR. Our results contribute to a better understanding of the sensitivity of OM upon land use change and how the microbial community is responding to land use change in highly weathered tropical soils.&lt;/p&gt;


2012 ◽  
Vol 9 (8) ◽  
pp. 3151-3171 ◽  
Author(s):  
P. Gottschalk ◽  
J.U. Smith ◽  
M. Wattenbach ◽  
J. Bellarby ◽  
E. Stehfest ◽  
...  

Abstract. We use a soil carbon (C) model (RothC), driven by a range of climate models for a range of climate scenarios to examine the impacts of future climate on global soil organic carbon (SOC) stocks. The results suggest an overall global increase in SOC stocks by 2100 under all scenarios, but with a different extent of increase among the climate model and emissions scenarios. The impacts of projected land use changes are also simulated, but have relatively minor impacts at the global scale. Whether soils gain or lose SOC depends upon the balance between C inputs and decomposition. Changes in net primary production (NPP) change C inputs to the soil, whilst decomposition usually increases under warmer temperatures, but can also be slowed by decreased soil moisture. Underlying the global trend of increasing SOC under future climate is a complex pattern of regional SOC change. SOC losses are projected to occur in northern latitudes where higher SOC decomposition rates due to higher temperatures are not balanced by increased NPP, whereas in tropical regions, NPP increases override losses due to higher SOC decomposition. The spatial heterogeneity in the response of SOC to changing climate shows how delicately balanced the competing gain and loss processes are, with subtle changes in temperature, moisture, soil type and land use, interacting to determine whether SOC increases or decreases in the future. Our results suggest that we should stop looking for a single answer regarding whether SOC stocks will increase or decrease under future climate, since there is no single answer. Instead, we should focus on improving our prediction of the factors that determine the size and direction of change, and the land management practices that can be implemented to protect and enhance SOC stocks.


Sign in / Sign up

Export Citation Format

Share Document