scholarly journals Cation ratio of soil structural stability (CROSS)

Soil Research ◽  
2011 ◽  
Vol 49 (3) ◽  
pp. 280 ◽  
Author(s):  
Pichu Rengasamy ◽  
Alla Marchuk
Keyword(s):  
Hydraulic Conductivity ◽  
Structural Stability ◽  
Control Treatment ◽  
Recycled Water ◽  
Clay Dispersion ◽  
Soil Structural Stability ◽  
Salt Affected Soils ◽  
Highly Correlated ◽  
Irrigation Waters ◽  
Cation Ratio

Sodium salts tend to dominate salt-affected soils and groundwater in Australia; therefore, sodium adsorption ratio (SAR) is used to parameterise soil sodicity and the effects of sodium on soil structure. However, some natural soils in Australia, and others irrigated with recycled water, have elevated concentrations of potassium and/or magnesium. Therefore, there is a need to derive and define a new ratio including these cations in place of SAR, which will indicate the dispersive effects of Na and K on clay dispersion, and Ca and Mg on flocculation. Based on the differential dispersive effects Na and K and the differential flocculation powers of Ca and Mg, we propose the concept of ‘cation ratio of soil structural stability’ (CROSS), analogous to SAR. This paper also gives the results of a preliminary experiment conducted on three soils varying in soil texture on hydraulic conductivity using percolating waters containing different proportions of the cations Ca, Mg, K, and Na. The relative changes in hydraulic conductivity of these soils, compared with the control treatment using CaCl2 solution, was highly correlated with CROSS. Clay dispersion in 29 soils treated with irrigation waters of varying cationic composition was highly correlated with CROSS rather than SAR. It was also found that CROSS measured in 1 : 5 soil/water extracts was strongly related to the ratio of exchangeable cations. These results encourage further study to investigate the use of CROSS as an index of soil structural stability in soils with different electrolytes, organic matter, mineralogy, and pH.

Nature of the clay - cation bond affects soil structure as verified by X-ray computed tomography

Soil Research ◽  
2012 ◽  
Vol 50 (8) ◽  
pp. 638 ◽  
Author(s):  
Alla Marchuk ◽  
Pichu Rengasamy ◽  
Ann McNeill ◽  
Anupama Kumar
Keyword(s):  
Computed Tomography ◽  
Hydraulic Conductivity ◽  
Zeta Potential ◽  
Structural Stability ◽  
Structural Parameters ◽  
Pore Connectivity ◽  
X Ray ◽  
Clay Dispersion ◽  
X Ray Computed ◽  
Cation Ratio

Non-destructive X-ray computed tomography (µCT) scanning was used to characterise changes in pore architecture as influenced by the proportion of cations (Na, K, Mg, or Ca) bonded to soil particles. These observed changes were correlated with measured saturated hydraulic conductivity, clay dispersion, and zeta potential, as well as cation ratio of structural stability (CROSS) and exchangeable cation ratio. Pore architectural parameters such as total porosity, closed porosity, and pore connectivity, as characterised from µCT scans, were influenced by the valence of the cation and the extent it dominated in the soil. Soils with a dominance of Ca or Mg exhibited a well-developed pore structure and pore interconnectedness, whereas in soil dominated by Na or K there were a large number of isolated pore clusters surrounded by solid matrix where the pores were filled with dispersed clay particles. Saturated hydraulic conductivities of cationic soils dominated by a single cation were dependent on the observed pore structural parameters, and were significantly correlated with active porosity (R2 = 0.76) and pore connectivity (R2 = 0.97). Hydraulic conductivity of cation-treated soils decreased in the order Ca > Mg > K > Na, while clay dispersion, as measured by turbidity and the negative charge of the dispersed clays from these soils, measured as zeta potential, decreased in the order Na > K > Mg > Ca. The results of the study confirm that structural changes during soil–water interaction depend on the ionicity of clay–cation bonding. All of the structural parameters studied were highly correlated with the ionicity indices of dominant cations. The degree of ionicity of an individual cation also explains the different effects caused by cations within a monovalent or divalent category. While sodium adsorption ratio as a measure of soil structural stability is only applicable to sodium-dominant soils, CROSS derived from the ionicity of clay–cation bonds is better suited to soils containing multiple cations in various proportions.

Influence of organic matter, clay mineralogy, and pH on the effects of CROSS on soil structure is related to the zeta potential of the dispersed clay

Soil Research ◽  
2013 ◽  
Vol 51 (1) ◽  
pp. 34 ◽  
Author(s):  
Alla Marchuk ◽  
Pichu Rengasamy ◽  
Ann McNeill
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Zeta Potential ◽  
Structural Stability ◽  
Soil Structure ◽  
Clay Mineralogy ◽  
Net Charge ◽  
Clay Dispersion ◽  
Soil Structural Stability ◽  
Negative Zeta Potential

The high proportion of adsorbed monovalent cations in soils in relation to divalent cations affects soil structural stability in salt-affected soils. Cationic effects on soil structure depend on the ionic strength of the soil solution. The relationships between CROSS (cation ratio of soil structural stability) and the threshold electrolyte concentration (TEC) required for the prevention of soil structural problems vary widely for individual soils even within a soil class, usually attributed to variations in clay mineralogy, organic matter, and pH. The objective of the present study was to test the hypothesis that clay dispersion influenced by CROSS values depends on the unique association of soil components, including clay and organic matter, in each soil affecting the net charge available for clay–water interactions. Experiments using four soils differing in clay mineralogy and organic carbon showed that clay dispersion at comparable CROSS values depended on the net charge (measured as negative zeta potential) of dispersed clays rather than the charge attributed to the clay mineralogy and/or organic matter. The effect of pH on clay dispersion was also dependent on its influence on the net charge. Treating the soils with NaOH dissolved the organic carbon and increased the pH, thereby increasing the negative zeta potential and, hence, clay dispersion. Treatment with calgon (sodium hexametaphosphate) did not dissolve organic carbon significantly or increase the pH. However, the attachment of hexametaphosphate with six charges on each molecule greatly increased the negative zeta potential and clay dispersion. A high correlation (R2 = 0.72) was obtained between the relative clay content and relative zeta potential of all soils with different treatments, confirming the hypothesis that clay dispersion due to adsorbed cations depends on the net charge available for clay–water interactions. The distinctive way in which clay minerals and organic matter are associated and the changes in soil chemistry affecting the net charge cause the CROSS–TEC relationship to be unique for each soil.

scholarly journals Assessment of Soil Structural Properties in Relation to Land Use Change in South-East Asia

Proceedings ◽  
2020 ◽  
Vol 36 (1) ◽  
pp. 182
Author(s):  
Rachel de Lastic ◽  
Thảo Hoàng ◽  
Phuong Nguyen ◽  
Sovanda Son ◽  
Vuthy Suos ◽  
...  
Keyword(s):  
Land Use ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Hydraulic Conductivity ◽  
Land Use Change ◽  
Structural Stability ◽  
Fruit Tree ◽  
Total Carbon ◽  
Tree Plantations ◽  
Soil Structural Stability

For many emerging economies, rapid land use change from forest to farmland is resulting in high levels of land degradation. Farming systems such as maize cultivation under conventional tillage after slash and burn degrade the soil resource through declining soil structural stability. Cultivation enhances mineralisation and hence loss of soil organic matter, which in turn reduces soil structures stability and promotes further carbon losses through soil erosion. Alternative land uses such as fruit tree plantations, or practise change to reduced tillage or conservation agriculture have the potential to counter this spiral of accelerated soil degradation through improving soil structural stability and build-up of soil organic matter. This project assessed how land use influences soil structural stability in Cambodia near Battambang and the North-Western Mountain regions of Vietnam where maize based system are most common. Soil properties measured were: (1) total carbon and nitrogen content analysis, (2) particle and aggregate size distribution using laser refraction, (3) hydraulic conductivity, (4) bulk density and (5) microbial CO2 respiration. Information on land use history was also collected through farmer surveys. Land use significantly influenced aggregate stability and hydraulic conductivity. This was largely associated with differences in soil organic carbon content. Forest system had the highest, and conventional maize systems had the lowest amount of large aggregates. Fruit tree plantations are relatively new to these regions but they already showed improved soil aggregate sizes though the level of improvement varied and depended on remnant soil.

scholarly journals Impact of monovalent cations on soil structure. Part II. Results of two Swiss soils

2018 ◽  
Vol 32 (1) ◽  
pp. 69-80 ◽  
Author(s):  
Elham Farahani ◽  
Hojat Emami ◽  
Thomas Keller
Keyword(s):  
Structural Stability ◽  
Water Retention ◽  
Agricultural Soils ◽  
Clay Content ◽  
Air Permeability ◽  
Soil Samples ◽  
Soil Structural Stability ◽  
The Impact ◽  
Dispersible Clay ◽  
Cation Ratio

AbstractIn this study, we investigated the impact of adding solutions with different potassium and sodium concentrations on dispersible clay, water retention characteristics, air permeability, and soil shrinkage behaviour using two agricultural soils from Switzerland with different clay content but similar organic carbon to clay ratio. Three different solutions (including only Na, only K, and the combination of both) were added to soil samples at three different cation ratio of soil structural stability levels, and the soil samples were incubated for one month. Our findings showed that the amount of readily dispersible clay increased with increasing Na concentrations and with increasing cation ratio of soil structural stability. The treatment with the maximum Na concentration resulted in the highest water retention and in the lowest shrinkage capacity. This was was associated with high amounts of readily dispersible clay. Air permeability generally increased during incubation due to moderate wetting and drying cycles, but the increase was negatively correlated with readily dispersible clay. Readily dispersible clay decreased with increasing K, while readily dispersible clay increased with increasing K in Iranian soil (Part I of our study). This can be attributed to the different clay mineralogy of the studied soils (muscovite in Part I and illite in Part II).

scholarly journals Organic matter and soil aggregation in agricultural systems with different adoption times

2019 ◽  
Vol 40 (6Supl3) ◽  
pp. 3443 ◽  
Author(s):  
Jean Sérgio Rosset ◽  
Maria do Carmo Lana ◽  
Marcos Gervasio Pereira ◽  
Jolimar Antonio Schiavo ◽  
Leandro Rampim ◽  
...  
Keyword(s):  
Organic Matter ◽  
Structural Stability ◽  
Soil Aggregation ◽  
Total Carbon ◽  
Management Systems ◽  
Physical Fractionation ◽  
Positive Effects ◽  
Brachiaria Ruziziensis ◽  
No Till ◽  
Soil Structural Stability

In conservation management systems, such as no-till (NT), it is important to analyze the pattern of changes in soil quality as a function of the time since adoption of the system. This study evaluated the physical fractions of organic matter and soil aggregation in management systems in areas cultivated with different times since implementation of NT: 6, 14, and 22 successive years of soybean and maize/wheat crops (NT6, NT14, and NT22, respectively); 12 years of no-till with successive years of soybean and maize/wheat crops, and the last 4 years with integration of maize and ruzi grass (Brachiaria ruziziensis) - (NT+B); pasture; and forest. Physical fractionation of organic matter determined the total carbon (TC), particulate organic matter (POM), and mineral organic matter (MOM) by calculating the carbon management index (CMI) and variables related to soil structural stability. Forest and pasture areas showed the highest contents of TC, POM, and MOM, as well as higher stocks of POM and MOM. Among the cultivated areas, higher TC and particulate fractions of organic matter and the best CMI values were observed in the area of NT22. There were changes in aggregation indices, depending on the time since implementation of NT. Areas of NT22, pasture, and forest showed the greatest evolution in C-CO2, indicating increased biological activity, with positive effects on soil structural stability.

scholarly journals Modification of sandy soil hydrophysical environment through bagasse additive under laboratory experiment

2015 ◽  
Vol 29 (1) ◽  
pp. 101-106 ◽  
Author(s):  
A.A. Abd El-Halim ◽  
Arunsiri Kumlung
Keyword(s):  
Hydraulic Conductivity ◽  
Laboratory Experiment ◽  
Bulk Density ◽  
Sandy Soil ◽  
Sandy Soils ◽  
Total Porosity ◽  
Dry Weight ◽  
Weight Basis ◽  
Control Treatment ◽  
Study Results

Abstract Until now sandy soils can be considered as one roup having common hydrophysical problems. Therefore, a laboratory experiment was conducted to evaluate the influence of bagasse as an amendment to improve hydrophysical properties of sandy soil, through the determination of bulk density, aggregatesize distribution, total porosity, hydraulic conductivity, pore-space structure and water retention. To fulfil this objective, sandy soils were amended with bagasse at the rate of 0, 0.5, 1, 2, 3 and 4% on the dry weight basis. The study results demonstrated that the addition of bagasse to sandy soils in between 3 to 4% on the dry weight basis led to a significant decrease in bulk density, hydraulic conductivity, and rapid-drainable pores, and increase in the total porosity, water-holding pores, fine capillary pores, water retained at field capacity, wilting point, and soil available water as compared with the control treatment

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