scholarly journals Long term trends in fertility of soils under continuous cultivation and cereal cropping in southern Queensland .V. Rate of loss of total nitrogen from the soil profile and changes in carbon : nitrogen ratios

Soil Research ◽  
1986 ◽  
Vol 24 (4) ◽  
pp. 493 ◽  
Author(s):  
RC Dalal ◽  
RJ Mayer
Keyword(s):  
Root Zone ◽  
Continuous Cultivation ◽  
N Loss ◽  
Total N ◽  
Cultivation Period ◽  
N Removal ◽  
Long Term Trends ◽  
Red Earth ◽  
Kinetics Of

The kinetics of total N loss from the top (0-0.1 m) and the subsoil (up to 1.2 m depth) of six southern Queensland soils after different periods (0-70 years) of cultivation and cereal cropping, were studied. The equation: Nt = Ne + (No - N,)exp(- kt), where No, Ne and N, are total N concentrations initially, at equilibrium and at time t, respectively, and k is the rate of loss of total N from soil, described total N loss from only three soils. For the 0-0.1 m depth, the kw values (based on weight of total Nholume of soil) were 0.061, 0.115 and 0.275 year-1, respectively for Waco (black earth; initially grassland), Langlands-Logie (grey, brown and red clays; brigalow) and Cecilvale soil (grey, brown and red clays; poplar box). The kw values decreased to less than half at 0-0.6 m depths of those at 0-0.1 m depth. In the other three soils, Billa Billa (grey, brown and red clays; belah), Thallon (grey, brown and red clays; coolibah) and Riverview (red earth; silver-leaved ironbark), total N declined linearly over the 20-25 years of cultivation period studied. Average annual rates of N loss from the profiles of the six soils, respectively, were 31.3, 67.1, 34.5, 50.8, 35.8 and 32.0 kg N ha-1 year-1 , from Waco, Langlands-Logie, Cecilvale, Billa Billa, Thallon and Riverview soils. Except for Langlands-Logie, these losses could be accounted for by crop N removal. In the Langlands-Logie soil, besides N removal by crop (51 kg N ha-1 year-1, 1982-1984 period), leaching of N below the root-zone appeared to be the likely factor for N loss. C:N ratios generally increased with depth in the five clay soils but decreased with depth in the red earth (Riverview). Cultivation had no significant effect on the C:N ratios of Cecilvale, Thallon and Riverview soils, but it caused a decrease in Langlands-Logie soil (up to 0.6 m depth) and an increase in Waco soil (up to 1.2 m depth). It was inferred, therefore, that in the latter, remaining soil N was likely to mineralise more slowly with increasing period of cultivation, resulting in a fertility loss which may be greater than that shown by the decrease in total N.

Agricultural practices and diffuse nitrogen pollution in Denmark: empirical leaching and catchment models

1999 ◽  
Vol 39 (12) ◽  
pp. 257-264 ◽  
Author(s):  
Hans E. Andersen ◽  
Brian Kronvang ◽  
Søren E. Larsen
Keyword(s):  
Agricultural Land ◽  
Root Zone ◽  
Agricultural Practices ◽  
Animal Manure ◽  
Annual Runoff ◽  
N Leaching ◽  
N Loss ◽  
Total N ◽  
Model Calculations ◽  
N Removal

An empirical leaching model was applied to data on agricultural practices at the field level within 6 small Danish agricultural catchments in order to document any changes in nitrogen (N) leaching from the root zone during the period 1989-96. The model calculations performed at normal climate revealed an average reduction in N-leaching that amounted to 30% in the loamy catchments and 9% in the sandy catchments. The reductions in N leaching could be ascribed to several improvements in agricultural practices during the study period: (i) regulations on livestock density; (ii) regulations on the utilisation of animal manure; (iii) regulations concerning application practices for manure. The average annual total N-loss from agricultural areas to surface water constituted only 54% of the annual average N leached from the root zone in the three loamy catchments and 17% in the three sandy catchments. Thus, subsurface N-removal processes are capable of removing large amounts of N leached from agricultural land. An empirical model for the annual diffuse N-loss to streams from small catchments is presented. The model predicts annual N-loss as a function of the average annual use of mineral fertiliser and manure in the catchment and the total annual runoff from the unsaturated zone.

scholarly journals Long term trends in fertility of soils under continuous cultivation and cereal cropping in southern Queensland. II. Total organic carbon and its rate of loss from the soil profile

Soil Research ◽  
1986 ◽  
Vol 24 (2) ◽  
pp. 281 ◽  
Author(s):  
RC Dalal ◽  
RJ Mayer
Keyword(s):  
Activity Ratio ◽  
Clay Content ◽  
Continuous Cultivation ◽  
Stepwise Multiple Regression ◽  
Annual Rainfall ◽  
Aggregation Index ◽  
Organic C ◽  
Long Term Trends ◽  
Kinetics Of

The kinetics of organic C loss were studied in six southern Queensland soils subjected to different periods (0-70 years) of cultivation and cereal cropping. The equation: Ct = Ce + (C0 - Ce)exp(- kt), where C0, Ce and C, are organic C contents initially, at equilibrium and at time k respectively, and k is the rate of loss of organic C from soil, was employed in the study. The parameter k was calculated both for %C (kc) and for weight of organic C/volume of soil (k,), determined by correcting for differences in sampling depth due to changes in bulk density upon cultivation. Mean annual rainfall largely determined both C, and Ce, presumably by influencing the amount of dry matter produced. Values of kc and kw varied greatly among the soils studied. For the 0-0.1 m depth, kw was 0.065, 0.080, 0.180, 0.259, 0.069 and 1.224 year-1 respectively for Waco (black earth - initially grassland), Langland-Logie (grey brown and red clays - brigalow), Cecilvale (grey, brown and red clays - poplar box), Billa Billa (grey, brown and red clays - belah), Thallon (grey, brown and red clays - coolibah) and Riverview (red earths - silver-leaved ironbark). The k values were significantly correlated with organic Chrease activity ratio (r = 0.99***) and reciprocal of clay content (r = 0.97**) of the virgin soils. In stepwise multiple regression analysis, aggregation index (for kc values) or exchangeable sodium percentage (for kw) and organic C/urease activity ratio of soils were significantly associated with the overall rate of loss of organic C. It was inferred, therefore, that the relative inaccessibility and protection of organic matter against microbial and enzymic attack resulted in reduced organic C loss. Losses of organic C from the deeper layers (0-0.2 m, 0-0.3 m) were observed in Waco, Langlands-Logie, Cecilvale and Riverview soils, although generally rate of loss decreased with depth.

Potential for biological denitrification of fertilizer nitrogen in sugarcane soils

1996 ◽  
Vol 47 (1) ◽  
pp. 67 ◽  
Author(s):  
KL Weier ◽  
CW McEwan ◽  
I Vallis ◽  
VR Catchpoole ◽  
RJ Myers
Keyword(s):  
Nitrous Oxide ◽  
Sampling Period ◽  
Field Studies ◽  
N Loss ◽  
Total N ◽  
Biological Denitrification ◽  
Sugarcane Crop ◽  
Ratoon Sugarcane ◽  
Red Earth ◽  
Crop Management Systems

Nitrogen (N) fertilizer is being lost from sugarcane soils following application to the crop. This study was conducted to estimate the quantity of N being lost from the soil through biological denitrification and to determine the proportion of gaseous N being emitted either as N2O or as N2. Field studies were conducted on four different soils (humic gley, alluvial massive earth, red earth and gleyed podzolic), and on different crop management systems, by installing plastic (PVC) cylinders (23.5 cm diam., 25 cm long) in the soil to a depth of 20 cm beside the plant row in a ratoon sugarcane crop. 15N-labelled KNO3 was applied as a band across each cylinder to a depth of 2.5 cm at a rate of 160 kg N/ha. After rainfall or irrigation, the cylinders were capped for 3 h intervals and gas in the headspace sampled in the morning and afternoon, for up to 4 days. Denitrification losses from the humic gley ranged from 247 g N/ha.day for cultivated plots to 1673 g N/ha.day for no-till plots. Over the sampling period, this was equivalent to 3.2% and 19.7% of the N applied, respectively. Nitrous oxide accounted for 46% to 78% of the total N lost. For the alluvial, massive earth and the red earth and gleyed podzolic, losses over the sampling period ranged from 25 to 117 g N/h.day and represented <1% of the N applied. Recovery of 15N in the soil ranged from 67% at the first sampling on the red earth soil to 4.9% at the third sampling on the alluvial, massive earth soil. In a glasshouse study, intact soil cores (23.5 cm diam., 20 cm long), taken from the humic gley and the alluvial, massive earth, were waterlogged after band application of 15N-labelled KNO3 at a rate of 160 kg N/ha. Gas samples from the headspace were taken after 3 h, and then morning and afternoon for the next 14 days. Denitrification losses ranged from 13.2 to 38.6% of N applied with the majority of gaseous N loss occurring as N2. Total recoveries after 14 days, including the evolved gases, ranged from 68.7 to 88.2%. We conclude that denitrification is a major cause of fertilizer N loss from fine-textured soils, with nitrous oxide the major gaseous N product when soil nitrate concentrations are high.

Long term trends in total nitrogen of a vertisol subjected to zero-tillage, nitrogen application and stubble retention

Soil Research ◽  
1992 ◽  
Vol 30 (2) ◽  
pp. 223 ◽  
Author(s):  
RC Dalal
Keyword(s):  
Management Practices ◽  
N Recovery ◽  
Zero Tillage ◽  
Fertilizer N ◽  
Total N ◽  
Leaching Losses ◽  
Stubble Retention ◽  
Long Term Trends ◽  
Apparent N Recovery

The effects of conservation practices, zero-tillage and stubble retention, on long-term trends in total N (0-0.1 m depth) of a Vertisol used mainly for wheat cropping were studied in a semi-arid subtropical environment (28�12'S. and 152�06' E.) in Queensland. Trends in total N content of a Vertisoi (65% clay, pH 7.2) were discerned during a 22-year period of management practices including: zero-tillage (ZT) and conventional tillage (CT); stubble retention (SR) and stubble burning (SB); and fertilizer N application of nil (Nl), 23 kg N ha-1 yr-1 (N2) and 69 kg N ha-1 yr-1 (N3). Soil total N (0-0.1 m) declined under all treatments at an overall rate of 25f 2 kg N ha-1 yr-1 although after 22 years soil under ZT, SR and N3 treatments still contained higher soil total N than under CT, SB and N1 treatments. Apparent fertilizer N recovery in the soil-plant system was poor (34 64%) under CTSB, CTSR and ZTSB and ZTSR treatments, because N removed by the wheat crop was equivalent to less than 20% of fertilizer N in the first 12 years of management practices, due mainly to disease. Deep leaching losses of NO3-N was the likely factor for poor recovery of N. The ZTSR treatment showed better apparent N recovery than the CTSB treatment, most likely due to greater immobilization of fertilizer N, more N uptake in grain due to additional available soil water and hence less leaching losses of NO3-N. Under the current cultural practices, soil total N (0-0.1 m) may decline further to reach a steady state (about 1000 kg N ha-1). However, the apparent N recovery in the soil-plant system can be increased by disease control (for example, resistant cultivars and winter-summer crop rotations) and optimum utilisation of soil water (opportunity cropping) to minimize NO3-N leaching losses and to maximise production of crop biomass.

Treatment of Wastewater in the Rhizosphere of Wetland Plants – The Root-Zone Method

1987 ◽  
Vol 19 (1-2) ◽  
pp. 107-118 ◽  
Author(s):  
Hans Brix
Keyword(s):  
Wastewater Treatment ◽  
Root Zone ◽  
Treatment Plant ◽  
Wetland Plants ◽  
Treated Wastewater ◽  
Treatment Standards ◽  
Nitrogen And Phosphorus ◽  
Zone Method ◽  
Total N ◽  
N Removal

The present paper describes the theoretical basis of wastewater treatment in the rhizosphere of wetland plants, the so-called “root-zone method”, along with the first working experiences from eight treatment plants in Denmark. Mechanically treated wastewater is led horizontally through the rhizosphere of wetland plants. During the passage of the wastewater through the rhizosphere, the wastewater is cleaned by microbiological degradation and by physical/chemical processes. The wetland plants supply oxygen to the heterotrophic microorganisms in the rhizosphere and stabilize the hydraulic conductivity of the soil. Nitrogen is removed by denitrification and phosphorus and heavy metals are bound in the soil. The first working experiences from Denmark show, that as far as BOD is concerned root-zone treatment plants are very nearly up to conventional secondary treatment standards already from the first growing season (removal efficiency: 51-95%). For the nutrients nitrogen and phosphorus the results vary (total-N removal: 10-88%; total-P removal: 11-94%). The removal efficiencies depended mainly on the composition of the soils and the degree of surface runoff in each treatment plant. It is concluded that root-zone treatment plants seem to be a viable alternative to conventional wastewater treatment technology, especially suitable for single households and small to medium sized communities. There is, however, still very little information on the removal processes for nitrogen (denitrification), on the effect of soil type and on the required surface area to load ratio,

Long term trends in fertility of soils under continuous cultivation and cereal cropping in southern Queensland. IV. Loss of organic carbon from different density functions

Soil Research ◽  
1986 ◽  
Vol 24 (2) ◽  
pp. 301 ◽  
Author(s):  
RC Dalal ◽  
RJ Mayer
Keyword(s):  
Clay Content ◽  
Continuous Cultivation ◽  
Heavy Fraction ◽  
Light Fraction ◽  
Organic C ◽  
Ethanol Mixture ◽  
Total Soil ◽  
Long Term Trends ◽  
The Difference

Six southern Queensland soils used for cereal cropping for cultivation periods ranging from 20 to 70 years were subjected to density fractionation. The soils were separated into fractions with densities of <2, 2.0-2.2, 2.2-2.4 and >2.4 Mg m-3 using bromoform-ethanol mixture. The < 2 Mg m-3 fraction (light fraction) contained only 1.8-3.2% of the total soil weight, but accounted for 15-32% of total soil organic C. In five clay soils the rate of loss of organic C from the light fraction was 2-11 times greater than that from the heavy fraction (>2 Mg m-3). The higher the clay content the larger was the difference between these two fractions in rate of loss of organic C. It is inferred that the heavy fraction was closely associated with clay in these soils. In a sandy soil, rate of loss of organic C from the heavy fraction was similar to that from the whole soil.

Comparative Labelling and Biokinetic Studies of 99mTc-EDTA(Sn) and 99mTc-DTPA(Sn)

1977 ◽  
Vol 16 (01) ◽  
pp. 30-35 ◽  
Author(s):  
N. Agha ◽  
R. B. R. Persson
Keyword(s):  
Complex Formation ◽  
Significant Influence ◽  
Room Temperature ◽  
Ph Value ◽  
Maximum Activity ◽  
Reduction Step ◽  
Labelling Yield ◽  
Different Temperatures ◽  
Kinetics Of

SummaryGelchromatography column scanning has been used to study the fractions of 99mTc-pertechnetate, 99mTcchelate and reduced hydrolyzed 99mTc in preparations of 99mTc-EDTA(Sn) and 99mTc-DTPA(Sn). The labelling yield of 99mTc-EDTA(Sn) chelate was as high as 90—95% when 100 μmol EDTA · H4 and 0.5 (Amol SnCl2 was incubated with 10 ml 99mTceluate for 30—60 min at room temperature. The study of the influence of the pH-value on the fraction of 99mTc-EDTA shows that pH 2.8—2.9 gave the best labelling yield. In a comparative study of the labelling kinetics of 99mTc-EDTA(Sn) and 99mTc- DTPA(Sn) at different temperatures (7, 22 and 37°C), no significant influence on the reduction step was found. The rate constant for complex formation, however, increased more rapidly with increased temperature for 99mTc-DTPA(Sn). At room temperature only a few minutes was required to achieve a high labelling yield with 99mTc-DTPA(Sn) whereas about 60 min was required for 99mTc-EDTA(Sn). Comparative biokinetic studies in rabbits showed that the maximum activity in kidneys is achieved after 12 min with 99mTc-EDTA(Sn) but already after 6 min with 99mTc-DTPA(Sn). The long-term disappearance of 99mTc-DTPA(Sn) from the kidneys is about five times faster than that for 99mTc-EDTA(Sn).

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