scholarly journals Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

2016 ◽  
Vol 113 (3) ◽  
pp. 526-531 ◽  
Author(s):  
Yanxu Zhang ◽  
Daniel J. Jacob ◽  
Hannah M. Horowitz ◽  
Long Chen ◽  
Helen M. Amos ◽  
...  
Keyword(s):  
North America ◽  
Large Scale ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Small Scale ◽  
Commercial Products ◽  
Earth Observing System ◽  
Global Emission ◽  
Emission Controls ◽  
Phase Out

Observations of elemental mercury (Hg0) at sites in North America and Europe show large decreases (∼1–2% y−1) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (<1% y−1). These decreases are inconsistent with current global emission inventories indicating flat or increasing emissions over that period. However, the inventories have three major flaws: (i) they do not account for the decline in atmospheric release of Hg from commercial products; (ii) they are biased in their estimate of artisanal and small-scale gold mining emissions; and (iii) they do not properly account for the change in Hg0/HgII speciation of emissions from coal-fired utilities after implementation of emission controls targeted at SO2 and NOx. We construct an improved global emission inventory for the period 1990 to 2010 accounting for the above factors and find a 20% decrease in total Hg emissions and a 30% decrease in anthropogenic Hg0 emissions, with much larger decreases in North America and Europe offsetting the effect of increasing emissions in Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg0 concentrations and in HgII wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO2 and NOx emission controls on coal-fired utilities.

scholarly journals High-resolution measurements of elemental mercury in surface water for an improved quantitative understanding of the Baltic Sea as a source of atmospheric mercury

2017 ◽  
Author(s):  
Joachim Kuss ◽  
Siegfried Krüger ◽  
Johann Ruickoldt ◽  
Klaus-Peter Wlost
Keyword(s):  
Surface Water ◽  
High Resolution ◽  
Baltic Sea ◽  
Elemental Mercury ◽  
Ambient Air ◽  
Atmospheric Mercury ◽  
Small Scale ◽  
The Baltic Sea ◽  
Marginal Seas ◽  
The Baltic

Abstract. Marginal seas are directly subjected to anthropogenic and natural influences from land in addition to receiving inputs from the atmosphere and open ocean. Together these lead to pronounced gradients and strong dynamic changes. However, in the case of mercury emissions from these seas, estimates often fail to adequately account for the spatial and temporal variability of the elemental mercury concentration in surface water (Hg0wat). In this study, a method to measure Hg0wat at high resolution was devised and subsequently validated. The better-resolved Hg0wat dataset, consisting of about one measurement per nautical mile, yielded insight into the sea's small-scale variability and thus improved the quantification of the sea's Hg0 emissions, a major source of atmospheric mercury. Research campaigns in the Baltic Sea were carried out between 2011 and 2015 during which Hg0 both in surface water and in ambient air were measured. For the former, two types of equilibrators were used. A membrane equilibrator enabled continuous equilibration and a bottle equilibrator assured that equilibrium was reached for validation. The measurements were combined with data obtained in the Baltic Sea in 2006 from a bottle equilibrator only. The Hg0 sea-air flux was newly calculated with the combined dataset based on current knowledge of the Hg0 Schmidt number, Henry's law constant, and a widely used gas-exchange transfer velocity parameterization. By using a newly developed pump-CTD with increased pumping capability in the Hg0 equilibrator measurements, Hg0wat could also be characterized in deeper water layers. A process study carried out near the Swedish island Øland in August 2015 showed that the upwelling of Hg0-depleted water contributed to Hg0 emissions of the Baltic Sea. However, a delay of a few days after contact between the upwelled water and light was apparently necessary before the biotic and abiotic transformations of ionic to volatile Hg0 produced a distinct sea-air Hg0 concentration gradient. This study clearly showed spatial, seasonal, and interannual variability in the Hg0 sea-air flux of the Baltic Sea. The average annual Hg0 emission was 0.90 ± 0.18 Mg for the Baltic Proper and to 1.73 ± 0.32 Mg for the entire Baltic Sea, which is about half the amount entrained by atmospheric deposition. A comparison of our results with the Hg0 sea-air fluxes determined in the Mediterranean Sea and in marginal seas in East Asia were to some extent similar but they partly differed in terms of the deviations in the amount and seasonality of the flux.

scholarly journals Airmass Origin in the Arctic. Part I: Seasonality

2015 ◽  
Vol 28 (12) ◽  
pp. 4997-5014 ◽  
Author(s):  
Clara Orbe ◽  
Paul A. Newman ◽  
Darryn W. Waugh ◽  
Mark Holzer ◽  
Luke D. Oman ◽  
...  
Keyword(s):  
Boundary Layer ◽  
North America ◽  
Seasonal Variations ◽  
Large Scale ◽  
Climate Model ◽  
The Arctic ◽  
Boreal Winter ◽  
Earth Observing System ◽  
The Western Pacific ◽  
System Chemistry

Abstract The first climatology of airmass origin in the Arctic is presented in terms of rigorously defined airmass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the Goddard Earth Observing System Chemistry–Climate Model (GEOSCCM) reveal that the majority of air in the Arctic below 700 mb last contacted the PBL poleward of 60°N. By comparison, 62% (±0.8%) of the air above 700 mb originates over Northern Hemisphere midlatitudes (i.e., “midlatitude air”). Seasonal variations in the airmass fractions above 700 mb reveal that during boreal winter air from midlatitudes originates primarily over the oceans, with 26% (±1.9%) last contacting the PBL over the eastern Pacific, 21% (±0.87%) over the Atlantic, and 16% (±1.2%) over the western Pacific. During summer, by comparison, midlatitude air originates primarily over land, overwhelmingly so over Asia [41% (±1.0%)] and, to a lesser extent, over North America [24% (±1.5%)]. Seasonal variations in the airmass fractions are interpreted in terms of changes in the large-scale ventilation of the midlatitude boundary layer and the midlatitude tropospheric jet.

scholarly journals Human health risk assessment of atmospheric mercury inhalation around three artisanal small-scale gold mining areas in Indonesia

2021 ◽  
Vol 1 (6) ◽  
pp. 423-433
Author(s):  
Koyomi Nakazawa ◽  
Osamu Nagafuchi ◽  
Tomonori Kawakami ◽  
Takanobu Inoue ◽  
Rosana Elvince ◽  
...  
Keyword(s):  
Health Risk ◽  
Human Health ◽  
Gold Mining ◽  
Human Health Risk ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Small Scale ◽  
Gaseous Elemental Mercury ◽  
Mining Areas ◽  
Central Sulawesi

To clarify the human health risk of inhalation of gaseous elemental mercury (GEM), we measured GEM concentrations in three artisanal small-scale gold mining (ASGM) areas of Palu (Central Sulawesi), Muara Aman (Benkulu in Sumatra), and Palangka Raya (Central Kalimantan).

scholarly journals High-resolution measurements of elemental mercury in surface water for an improved quantitative understanding of the Baltic Sea as a source of atmospheric mercury

2018 ◽  
Vol 18 (6) ◽  
pp. 4361-4376 ◽  
Author(s):  
Joachim Kuss ◽  
Siegfried Krüger ◽  
Johann Ruickoldt ◽  
Klaus-Peter Wlost
Keyword(s):  
Surface Water ◽  
High Resolution ◽  
Baltic Sea ◽  
Elemental Mercury ◽  
Ambient Air ◽  
Atmospheric Mercury ◽  
Small Scale ◽  
The Baltic Sea ◽  
Marginal Seas ◽  
The Baltic

Abstract. Marginal seas are directly subjected to anthropogenic and natural influences from land in addition to receiving inputs from the atmosphere and open ocean. Together these lead to pronounced gradients and strong dynamic changes. However, in the case of mercury emissions from these seas, estimates often fail to adequately account for the spatial and temporal variability of the elemental mercury concentration in surface water (Hg0wat). In this study, a method to measure Hg0wat at high resolution was devised and subsequently validated. The better-resolved Hg0wat dataset, consisting of about one measurement per nautical mile, yielded insight into the sea's small-scale variability and thus improved the quantification of the sea's Hg0 emission. This is important because global marine Hg0 emissions constitute a major source of atmospheric mercury. Research campaigns in the Baltic Sea were carried out between 2011 and 2015 during which Hg0 both in surface water and in ambient air were measured. For the former, two types of equilibrators were used. A membrane equilibrator enabled continuous equilibration and a bottle equilibrator assured that equilibrium was reached for validation. The measurements were combined with data obtained in the Baltic Sea in 2006 from a bottle equilibrator only. The Hg0 sea–air flux was newly calculated with the combined dataset based on current knowledge of the Hg0 Schmidt number, Henry's law constant, and a widely used gas exchange transfer velocity parameterization. By using a newly developed pump–CTD with increased pumping capability in the Hg0 equilibrator measurements, Hg0wat could also be characterized in deeper water layers. A process study carried out near the Swedish island Øland in August 2015 showed that the upwelling of Hg0-depleted water contributed to Hg0 emissions of the Baltic Sea. However, a delay of a few days after contact between the upwelled water and light was apparently necessary before the biotic and abiotic transformations of ionic to volatile Hg0 produced a distinct sea–air Hg0 concentration gradient. This study clearly showed spatial, seasonal, and interannual variability in the Hg0 sea–air flux of the Baltic Sea. The average annual Hg0 emission was 0.90  ±  0.18 Mg for the Baltic proper and extrapolated to 1.73  ±  0.32 Mg for the entire Baltic Sea, which is about half the amount entrained by atmospheric deposition. A comparison of our results with the Hg0 sea–air fluxes determined in the Mediterranean Sea and in marginal seas in East Asia were to some extent similar but they partly differed in terms of the deviations in the amount and seasonality of the flux.

scholarly journals The Atmospheric Mercury Network: measurement and initial examination of an ongoing atmospheric mercury record across North America

2013 ◽  
Vol 13 (22) ◽  
pp. 11339-11349 ◽  
Author(s):  
D. A. Gay ◽  
D. Schmeltz ◽  
E. Prestbo ◽  
M. Olson ◽  
T. Sharac ◽  
...  
Keyword(s):  
North America ◽  
Dry Deposition ◽  
Meteorological Data ◽  
Model Development ◽  
Elemental Mercury ◽  
High Elevation ◽  
Atmospheric Mercury ◽  
Federal State ◽  
Initial Examination ◽  
Depth Analysis

Abstract. The National Atmospheric Deposition Program (NADP) developed and operates a collaborative network of atmospheric-mercury-monitoring sites based in North America – the Atmospheric Mercury Network (AMNet). The justification for the network was growing interest and demand from many scientists and policy makers for a robust database of measurements to improve model development, assess policies and programs, and improve estimates of mercury dry deposition. Many different agencies and groups support the network, including federal, state, tribal, and international governments, academic institutions, and private companies. AMNet has added two high-elevation sites outside of continental North America in Hawaii and Taiwan because of new partnerships forged within NADP. Network sites measure concentrations of atmospheric mercury fractions using automated, continuous mercury speciation systems. The procedures that NADP developed for field operations, data management, and quality assurance ensure that the network makes scientifically valid and consistent measurements. AMNet reports concentrations of hourly gaseous elemental mercury (GEM), two-hour gaseous oxidized mercury (GOM), and two-hour particulate-bound mercury less than 2.5 microns in size (PBM2.5). As of January 2012, over 450 000 valid observations are available from 30 stations. AMNet also collects ancillary meteorological data and information on land use and vegetation, when available. We present atmospheric mercury data comparisons by time (3 yr) at 21 individual sites and instruments. Highlighted are contrasting values for site locations across the network: urban versus rural, coastal versus high elevation and the range of maximum observations. The data presented should catalyze the formation of many scientific questions that may be answered through further in-depth analysis and modeling studies of the AMNet database. All data and methods are publically available through an online database on the NADP website (http://nadp.sws.uiuc.edu/amn/). Future network directions are to foster new network partnerships and continue to collect, quality assure, and post data, including dry deposition estimates, for each fraction.

scholarly journals GNAQPMS-Hg v1.0, a global nested atmospheric mercury transport model: model description, evaluation and application to trans-boundary transport of Chinese anthropogenic emissions

2014 ◽  
Vol 7 (5) ◽  
pp. 6949-6996
Author(s):  
H. S. Chen ◽  
Z. F. Wang ◽  
J. Li ◽  
X. Tang ◽  
B. Z. Ge ◽  
...  
Keyword(s):  
North America ◽  
East Asia ◽  
Aqueous Phase ◽  
Wet Deposition ◽  
Transport Model ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Model Description ◽  
Anthropogenic Emissions ◽  
Comparison Results

Abstract. Atmospheric mercury (Hg) is a toxic pollutant and can be transported over the whole globe due to its long lifetime in the atmosphere. For the purpose of assessing Hg hemispheric transport and better characterizing regional Hg pollution, a global nested atmospheric Hg transport model (GNAQPMS-Hg) has been developed. In GNAQPMS-Hg, the gas and aqueous phase Hg chemistry representing the transformation among three forms of Hg: elemental mercury (Hg(0)), divalent mercury (Hg(II)), and primary particulate mercury (Hg(P)) are calculated. A detailed description of the model, including mercury emissions, gas and aqueous phase chemistry, and dry and wet deposition is given in this study. Worldwide observations including extensive data in China have been collected for model evaluation. Comparison results show that the model reasonably simulates the global mercury budget and the spatial–temporal variation of surface mercury concentrations and deposition. Overall, model predictions of annual total gaseous mercury (TGM) and wet deposition agree with observations within a factor of two, and within a factor of five for oxidized mercury and dry deposition. The model performs significantly better in North America and Europe than in East Asia. This can probably be attributed to the large uncertainties in emission inventories, coarse model resolution and to the inconsistency between the simulation and observation periods in East Asia. Compared to the global simulation, the nested simulation shows improved skill at capturing the high spatial variability of Hg concentrations and deposition over East Asia. In particular, the root mean square error (RMSE) of simulated Hg wet deposition over East Asia is reduced by 24% in the nested simulation. Model sensitivity studies indicate that Chinese primary anthropogenic emissions account for 30 and 62% of surface mercury concentrations and deposition over China, respectively. Along the rim of the western Pacific, the contributions from Chinese sources are 11 and 15.2% over the Korean Peninsula, 10.4 and 8.2% over Southeast Asia, and 5.7 and 5.9% over Japan. But for North America, Europe and West Asia, the contributions from China are all below 5%.

scholarly journals The Atmospheric Mercury Network: measurement and initial examination of an ongoing atmospheric mercury record across North America

2013 ◽  
Vol 13 (4) ◽  
pp. 10521-10546 ◽  
Author(s):  
D. A. Gay ◽  
D. Schmeltz ◽  
E. Prestbo ◽  
M. Olson ◽  
T. Sharac ◽  
...  
Keyword(s):  
North America ◽  
Dry Deposition ◽  
Meteorological Data ◽  
Model Development ◽  
Elemental Mercury ◽  
High Elevation ◽  
Atmospheric Mercury ◽  
Federal State ◽  
Initial Examination ◽  
Depth Analysis

Abstract. The National Atmospheric Deposition Program (NADP) developed and operates a collaborative network of atmospheric mercury monitoring sites based in North America – the Atmospheric Mercury Network (AMNet). The justification for the network was growing interest and demand from many scientists and policy makers for a robust database of measurements to improve model development, assess policies and programs, and improve estimates of mercury dry deposition. Many different agencies and groups support the network, including federal, state, tribal, and international governments, academic institutions, and private companies. AMNet has added two high elevation sites outside of continental North America in Hawaii and Taiwan because of new partnerships forged within NADP. Network sites measure concentrations of atmospheric mercury fractions using automated, continuous mercury speciation systems. The procedures that NADP developed for field operations, data management, and quality assurance ensure that the network makes scientifically valid and consistent measurements. AMNet reports concentrations of hourly gaseous elemental mercury (GEM), two-hour gaseous oxidized mercury (GOM), and two-hour particulate-bound mercury less than 2.5 microns in size (PBM2.5). As of January 2012, over 450 000 valid observations are available from 30 stations. The AMNet also collects ancillary meteorological data and information on land-use and vegetation, when available. We present atmospheric mercury data comparisons by time (3 yr) at 22 unique site locations. Highlighted are contrasting values for site locations across the network: urban versus rural, coastal versus high-elevation and the range of maximum observations. The data presented should catalyze the formation of many scientific questions that may be answered through further in-depth analysis and modeling studies of the AMNet database. All data and methods are publically available through an online database on the NADP website (http://nadp.isws.illinois.edu/amn/). Future network directions are to foster new network partnerships and continue to collect, quality assure, and post data, including dry deposition estimates, for each fraction.

scholarly journals Quantification of Uncertainty in High-Resolution Temperature Scenarios for North America

2012 ◽  
Vol 25 (9) ◽  
pp. 3373-3389 ◽  
Author(s):  
Guilong Li ◽  
Xuebin Zhang ◽  
Francis Zwiers ◽  
Qiuzi H. Wen
Keyword(s):  
High Resolution ◽  
North America ◽  
General Circulation ◽  
Large Scale ◽  
Climate Models ◽  
Internal Variability ◽  
General Circulation Models ◽  
First Century ◽  
Small Scale ◽  
Twenty First Century

A framework for the construction of probabilistic projections of high-resolution monthly temperature over North America using available outputs of opportunity from ensembles of multiple general circulation models (GCMs) and multiple regional climate models (RCMs) is proposed. In this approach, a statistical relationship is first established between RCM output and that from the respective driving GCM and then this relationship is applied to downscale outputs from a larger number of GCM simulations. Those statistically downscaled projections were used to estimate empirical quantiles at high resolution. Uncertainty in the projected temperature was partitioned into four sources including differences in GCMs, internal variability simulated by GCMs, differences in RCMs, and statistical downscaling including internal variability at finer spatial scale. Large spatial variability in projected future temperature changes is found, with increasingly larger changes toward the north in winter temperature and larger changes in the central United States in summer temperature. Under a given emission scenario, downscaling from large scale to small scale is the most important source of uncertainty, though structural errors in GCMs become equally important by the end of the twenty-first century. Different emission scenarios yield different projections of temperature change. This difference increases with time. The difference between the IPCC’s Special Report on Emissions Scenarios (SRES) A2 and B1 in the median values of projected changes in 30-yr mean temperature is small for the coming 30 yr, but can become almost as large as the total variance due to internal variability and modeling errors in both GCM and RCM later in the twenty-first century.

Small-Scale Science to Large-Scale Profession

2000 ◽  
Vol 45 (4) ◽  
pp. 396-398
Author(s):  
Roger Smith
Keyword(s):  
Large Scale ◽  
Small Scale

Development of Physics Learning Module Based on Guided Inquiry with Light Wave Material in Class XI of Senior High School

2020 ◽  
Vol 1 (1) ◽  
pp. 1-10
Author(s):  
Evi Rahmawati ◽  
Irnin Agustina Dwi Astuti ◽  
N Nurhayati
Keyword(s):  
Large Scale ◽  
Learning Strategy ◽  
Student Response ◽  
Average Score ◽  
Small Scale ◽  
Design Development ◽  
Teacher Response ◽  
Student Responses ◽  
Analysis Design ◽  
Scientific Skills

IPA Integrated is a place for students to study themselves and the surrounding environment applied in daily life. Integrated IPA Learning provides a direct experience to students through the use and development of scientific skills and attitudes. The importance of integrated IPA requires to pack learning well, integrated IPA integration with the preparation of modules combined with learning strategy can maximize the learning process in school. In SMP 209 Jakarta, the value of the integrated IPA is obtained from 34 students there are 10 students completed and 24 students are not complete because they get the value below the KKM of 68. This research is a development study with the development model of ADDIE (Analysis, Design, Development, Implementation, and Evaluation). The use of KPS-based integrated IPA modules (Science Process sSkills) on the theme of rainbow phenomenon obtained by media expert validation results with an average score of 84.38%, average material expert 82.18%, average linguist 75.37%. So the average of all aspects obtained by 80.55% is worth using and tested to students. The results of the teacher response obtained 88.69% value with excellent criteria. Student responses on a small scale acquired an average score of 85.19% with highly agreed criteria and on the large-scale student response gained a yield of 86.44% with very agreed criteria. So the module can be concluded receiving a good response by the teacher and students.

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