Some characterizations of a new metal–organic framework (n-C14H29NH3)2CdCl4 and the role of hydrogen bonding

2018 ◽  
Vol 91 (8) ◽  
pp. 840-861
Author(s):  
M. M. Abdelkader ◽  
W. M. Gamal
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal–organic framework

RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian
Keyword(s):  
Hydrogen Bonding ◽  
Theoretical Calculation ◽  
Proton Transport ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Transport Channel ◽  
Proton Conducting ◽  
Metal Organic ◽  
Organic Framework

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.

Preferential adsorption of ethane over ethylene on a Zr-based metal-organic framework: impacts of C-H···N hydrogen bonding

2021 ◽  
Author(s):  
Yaping Zhang ◽  
Daofei Lv ◽  
Jiayu Chen ◽  
Zewei Liu ◽  
Chongxiong Duan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Surface Area ◽  
Energy Efficient ◽  
Metal Organic Framework ◽  
Bet Surface Area ◽  
Preferential Adsorption ◽  
Metal Organic ◽  
Organic Framework

The separation of ethylene/ethane mixture using energy-efficient technologies is important but challenging. Here, we prepared a Zr-based metal-organic framework (MOF-545) possessing high Brunauer-Emmett-Teller (BET) surface area of 2265.4 m2/g, and...

scholarly journals Hydrogenation of CO2 to Methanol by Pt Nanoparticles Encapsulated in UiO-67: Deciphering the Role of the Metal–Organic Framework

2019 ◽  
Vol 142 (2) ◽  
pp. 999-1009 ◽  
Author(s):  
Emil S. Gutterød ◽  
Andrea Lazzarini ◽  
Torstein Fjermestad ◽  
Gurpreet Kaur ◽  
Maela Manzoli ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Pt Nanoparticles ◽  
Hydrogenation Of Co2 ◽  
Metal Organic ◽  
Organic Framework

High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal–Organic Framework

2014 ◽  
Vol 136 (35) ◽  
pp. 12444-12449 ◽  
Author(s):  
Qun Tang ◽  
Yiwei Liu ◽  
Shuxia Liu ◽  
Danfeng He ◽  
Jun Miao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

Uncovering the Role of Metal–Organic Framework Topology on the Capture and Reactivity of Chemical Warfare Agents

2020 ◽  
Vol 32 (11) ◽  
pp. 4609-4617 ◽  
Author(s):  
Florencia A. Son ◽  
Megan C. Wasson ◽  
Timur Islamoglu ◽  
Zhijie Chen ◽  
Xinyi Gong ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Chemical Warfare Agents ◽  
Chemical Warfare ◽  
Warfare Agents ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Hydrogen-Bonding Linkers Yield a Large-Pore, Non-Catenated, Metal-Organic Framework with pcu Topology

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 697 ◽  
Author(s):  
Mohammad S. Yazdanparast ◽  
Victor W. Day ◽  
Tendai Gadzikwa
Keyword(s):  
Hydrogen Bonding ◽  
Pore Volume ◽  
Reliable Method ◽  
Metal Organic Framework ◽  
Low Density ◽  
Paddle Wheel ◽  
Accessible Volume ◽  
New Material ◽  
Metal Organic ◽  
Organic Framework

Pillared paddle-wheel-based metal-organic framework (MOF) materials are an attractive target as they offer a reliable method for constructing well-defined, multifunctional materials. A drawback of these materials, which has limited their application, is their tendency to form catenated frameworks with little accessible volume. To eliminate this disadvantage, it is necessary to investigate strategies for constructing non-catenated pillared paddle-wheel MOFs. Hydrogen-bonding substituents on linkers have been postulated to prevent catenation in certain frameworks and, in this work, we present a new MOF to further bolster this theory. Using 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid, BPDC-(NH2)2, linkers and dipyridyl glycol, DPG, pillars, we assembled a MOF with pcu topology. The new material is non-catenated, exhibiting large accessible pores and low density. To the best of our knowledge, this material constitutes the pcu framework with the largest pore volume and lowest density. We attribute the lack of catenation to the presence of H-bonding substituents on both linkers.

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