Particulate reinforcement and formaldehyde adsorption of modified nanocrystalline cellulose in urea-formaldehyde resin adhesive

2013 ◽  
Vol 27 (9) ◽  
pp. 1023-1031 ◽  
Author(s):  
Hao Zhang ◽  
Ying She ◽  
Shuping Song ◽  
Qian Lang ◽  
Junwen Pu
RSC Advances ◽  
2021 ◽  
Vol 11 (40) ◽  
pp. 25010-25017
Author(s):  
Li Lu ◽  
Yan Wang ◽  
Tianhua Li ◽  
Supeng Wang ◽  
Shoulu Yang ◽  
...  

Reactions between CaCO3 and CH2O2 during polycondensation of UF resin produce Ca2+. Ionic bond complexation binds Ca2+ with UF resin. The UF resin crystalline percentage decreases from 26.86% to 22.71%. IB strength of resin bonded fiberboard increases from 0.75 to 0.94 MPa.


2018 ◽  
Vol 69 (3) ◽  
pp. 247-252
Author(s):  
Timuçin Bardak ◽  
Eser Sozen ◽  
Kadir Kayahan ◽  
Selahattin Bardak

2011 ◽  
Vol 197-198 ◽  
pp. 147-150 ◽  
Author(s):  
Wei Wang ◽  
Li Bin Zhu ◽  
Ji You Gu ◽  
Xiang Li Weng ◽  
Hai Yan Tan

Through the study of the effects of different dosage of additives on the properties of urea formaldehyde resin adhesive prepared at low mole ratio of formaldehyde/urea, optimize the synthetic process of the UF resin which is used at the E0 grade plywood. The results showed that the product synthesized under the following condition: the mole ratio of formaldehyde/urea is 0.99:1, the dosage of the specific additive is 1.0% and that of melamine is 3-4%, had a good comprehensive performance and the formaldehyde emission of the plywood meets the E0 grade which is environmental-friendly.


RSC Advances ◽  
2014 ◽  
Vol 4 (73) ◽  
pp. 39037-39044 ◽  
Author(s):  
Tong-Xin Shang ◽  
Ming-Yang Zhang ◽  
Xiao-Juan Jin

The urea-formaldehyde resin adhesive in waste medium density fiberboard play a role in modifying the activated carbons.


2012 ◽  
Vol 427 ◽  
pp. 148-152 ◽  
Author(s):  
Qing Guo Tang ◽  
Fei Wang ◽  
Hong Xia Shao ◽  
Yan Ding

The artificial plywood materials were prepared using natural minerals and inorganic oxide powders as the main fillers for urea-formaldehyde resin adhesive instead of flour. The method mentioned above has advantages in saving food resources, reducing cost of plywood, improving the quality of plywood and decreasing the release amount of free formaldehyde. On the basis of the research achievement both domestic, foreign and our experimental data, this paper mainly discussed the effect of filler on adhesive properties, bond strength of plywood, and free formaldehyde content, which provided reference for development of green environmental protection and low cost urea-formaldehyde resin adhesive minerals composite filler.


2013 ◽  
Vol 774-776 ◽  
pp. 1232-1236
Author(s):  
Nan Zhe Zhang

In order to prepare urea-formaldehyde (UF) resin adhesive with good performance for glass wool products, we used polyvinyl alcohol (PVA), p-toluenesulfonamide (PTSA) and methanol to modify UF resin, optimized the molar ratio of formaldehyde (F) / urea (U) and reaction components ratio by orthogonal test, reduced the content of free formaldehyde in UF resin, and enhanced the water resistance, flexibility and stability of UF resin.


2013 ◽  
Vol 27 (20) ◽  
pp. 2191-2203 ◽  
Author(s):  
Zhang Yanhua ◽  
Gu Jiyou ◽  
Tan Haiyan ◽  
Jiang XiangKai ◽  
Shi Junyou ◽  
...  

2012 ◽  
Vol 621 ◽  
pp. 79-82
Author(s):  
Gui Hua Chen ◽  
Jian Han ◽  
Xiao Huan Zhang

This study aimed at exploring a producing method of urea-formaldehyde resin that contained low free formaldehyde. Effects of the pH value of addition stage, the pH value and the temperature of polycondensation stage on the properties of the resin were analyzed. The experimental results showed that controlling the pH value of addition stage to 7.5-8.0, regulating the pH value of polycondensation stage to 4.8-5.1, and keeping the temperature of polycondensation stage to 88-92°C, a low toxic urea-formaldehyde resin adhesive was obtained which contained free formaldehyde 0.08%. Using this resin adhesive, the bonding strength of the plywood reached 1.7MPa, formaldehyde emission of the plywood was 0.7mg/l, reaching the grade E1.


2013 ◽  
Vol 562-565 ◽  
pp. 846-851
Author(s):  
Hao Zhang ◽  
Ying She ◽  
Shu Ping Song ◽  
Jun Wen Pu

Nanocrystalline cellulose (NCC) was used for improving the formaldehyde (HCHO) emission and bonding strength of urea formaldehyde (UF) resin adhesive in fiberboard and plywood. The original NCC was modified by 3-aminopropyltriethoxysilane (APTES) and the wetting property with UF resin adhesive was improved by 26.4%. The UF resin adhesive with modified NCC was characterized by X-ray powder diffraction (XRD), thermogravimetric analysis (TG) and Fourier transform infrared (FT-IR). The crystal region of UF resin adhesive was influenced by NCC and the diffraction intensity of the peak at 2θ = 22.82° was enhanced significantly. The thermal stability of UF resin adhesive with 1.0% modified NCC increased by 4.9%. And modified NCC led hydroxyl groups into the UF resin adhesive. HCHO emission and bonding strength of the UF resin adhesive with modified NCC were tested according to Chinese National Standards GB/T 17657-1999 and GB/T 9846-2004. The HCHO emission of fiberboard and plywood with 1.5% modified NCC decreased by 13.0% and 53.2%, respectively. The bonding strength of fiberboard increased by 158.3% (from 0.12 MPa of control group to 0.31 MPa of fiberboard with 1.5% modified NCC), while 1.5% modified NCC led to a 23.6% increase in the plywood.


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