Comparison of multivariate calibration methods for quantitative analysis of multicomponent mixture of air toxic organic compounds by FTIR

1998 ◽  
Vol 33 (7) ◽  
pp. 1419-1436 ◽  
Author(s):  
Binghe Gu ◽  
Junde Wang ◽  
Xuetie Zhou ◽  
Xuan Wu ◽  
Fang Liu ◽  
...  
Cellulose ◽  
2019 ◽  
Vol 27 (1) ◽  
pp. 157-170 ◽  
Author(s):  
Chamseddine Guizani ◽  
Sanna Hellstén ◽  
Joanna Witos ◽  
Herbert Sixta

Abstract We investigate in this paper the potential of Raman spectroscopy for the quantification of protic ionic liquid components (acid and base) and water, in ionic liquid/water mixtures, taking 1.5-Diazabicyclo[4.3.0]non-5-enium acetate ([DBNH][OAc]) as a case study. We show that the combination of Raman spectroscopy and chemometrics is quite successful for the quantitative analysis of the ionic liquid components and water in mixtures over wide concentration ranges. The finding of the present work suggest that Raman spectroscopy should be considered more universally for the in-line monitoring and control of processes involving ionic liquid/H2O mixtures.


1987 ◽  
Vol 19 (3-4) ◽  
pp. 471-482 ◽  
Author(s):  
W. J. Weber ◽  
B. E. Jones ◽  
L. E. Katz

The addition of powdered activated carbon (PAC) to activated sludge treatment systems to enhance removal of specific toxic organic compounds from wastewater was evaluated. Nine organic compounds encompassing a range of solubility, volatility, biodegradability, and adsorptive properties were studied. Kate and equilibrium investigations were conducted to quantify the removal mechanisms of volatilization, biodegradation, biosorption, and carbon adsorption. Results from steady-state bioreactor studies showed that the addition of less than 100 mg/ℓ powdered activated carbon to the influent did not enhance the removal of the biodegradable target compounds investigated: benzene, toluene, ethylbenzene, o-xylene, chlorobenzene, and nitrobenzene. Significantly improved removals of the poorly degradable and non-biodegradable compounds 1,2-dichlorobenzene, 1,2,4-trichlorobenzene, and lindane occurred at influent powdered carbon concentrations in the 12.5 to 25 mg/ℓ range. Influent powdered carbon concentrations of 100 mg/ℓ effected overall removals of greater than 90%. The addition of powdered activated carbon not only reduced effluent concentrations but also reduced the amounts of the volatile compounds stripped to the atmosphere.


Robotics ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 45
Author(s):  
Roberto Pagani ◽  
Cristina Nuzzi ◽  
Marco Ghidelli ◽  
Alberto Borboni ◽  
Matteo Lancini ◽  
...  

Since cobots are designed to be flexible, they are frequently repositioned to change the production line according to the needs; hence, their working area (user frame) needs to be often calibrated. Therefore, it is important to adopt a fast and intuitive user frame calibration method that allows even non-expert users to perform the procedure effectively, reducing the possible mistakes that may arise in such contexts. The aim of this work was to quantitatively assess the performance of different user frame calibration procedures in terms of accuracy, complexity, and calibration time, to allow a reliable choice of which calibration method to adopt and the number of calibration points to use, given the requirements of the specific application. This has been done by first analyzing the performances of a Rethink Robotics Sawyer robot built-in user frame calibration method (Robot Positioning System, RPS) based on the analysis of a fiducial marker distortion obtained from the image acquired by the wrist camera. This resulted in a quantitative analysis of the limitations of this approach that only computes local calibration planes, highlighting the reduction of performances observed. Hence, the analysis focused on the comparison between two traditional calibration methods involving rigid markers to determine the best number of calibration points to adopt to achieve good repeatability performances. The analysis shows that, among the three methods, the RPS one resulted in very poor repeatability performances (1.42 mm), while the three and five points calibration methods achieve lower values (0.33 mm and 0.12 mm, respectively) which are closer to the reference repeatability (0.08 mm). Moreover, comparing the overall calibration times achieved by the three methods, it is shown that, incrementing the number of calibration points to more than five, it is not suggested since it could lead to a plateau in the performances, while increasing the overall calibration time.


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