Enhancement of Fire Retardancy in Coir Fibers Using Phosphorylation Treatment

2021 ◽  
pp. 1-9
Author(s):  
Simimol Ansera ◽  
Ajith Sudhakaran ◽  
Anita Ravindranath
Keyword(s):  
Fire Retardancy ◽  
Coir Fibers

scholarly journals Coir Fibers Treated with Henna as a Potential Reinforcing Filler in the Synthesis of Polyurethane Composites

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1128
Author(s):  
Sylwia Członka ◽  
Anna Strąkowska ◽  
Agnė Kairytė
Keyword(s):  
Mechanical Properties ◽  
High Energy ◽  
Dynamic Mechanical Properties ◽  
Milling Process ◽  
Coir Fiber ◽  
Lawsonia Inermis ◽  
Coir Fibers ◽  
Mechanical Performances ◽  
The Impact ◽  
Reinforcing Filler

In this study, coir fibers were successfully modified with henna (derived from the Lawsonia inermis plant) using a high-energy ball-milling process. In the next step, such developed filler was used as a reinforcing filler in the production of rigid polyurethane (PUR) foams. The impact of 1, 2, and 5 wt % of coir-fiber filler on structural and physico-mechanical properties was evaluated. Among all modified series of PUR composites, the greatest improvement in physico-mechanical performances was observed for PUR composites reinforced with 1 wt % of the coir-fiber filler. For example, on the addition of 1 wt % of coir-fiber filler, the compression strength was improved by 23%, while the flexural strength increased by 9%. Similar dependence was observed in the case of dynamic-mechanical properties—on the addition of 1 wt % of the filler, the value of glass transition temperature increased from 149 °C to 178 °C, while the value of storage modulus increased by ~80%. It was found that PUR composites reinforced with coir-fiber filler were characterized by better mechanical performances after the UV-aging.

scholarly journals A mechanism for fire retardancy realized by a combination of biofillers and ammonium polyphosphate in various polymer systems

Cellulose ◽  
2021 ◽  
Author(s):  
Koki Matsumoto ◽  
Tatsuya Tanaka ◽  
Masahiro Sasada ◽  
Noriyuki Sano ◽  
Kenta Masuyama
Keyword(s):  
Polymer Matrix ◽  
Synergetic Effect ◽  
Polymer System ◽  
Ammonium Polyphosphate ◽  
Fire Retardancy ◽  
Polymer Systems ◽  
Thermal Decomposition Behavior ◽  
Burning Behavior ◽  
The Matrix ◽  
Decomposition Behavior

AbstractThis study focused on realizing fire retardancy for polymer composites by using a cellulosic biofiller and ammonium polyphosphate (APP). The motivation of this study was based on revealing the mechanism of the synergetic effect of a cellulosic biofiller and APP and determining the parameters required for achieving a V-0 rating in UL94 standard regardless of the kind of polymer system used. As for the polymer matrix, polypropylene and polylactic acid were used. The flammability, burning behavior and thermal decomposition behavior of the composites were investigated through a burning test according to the UL-94 standard, cone calorimetric test and thermogravimetric analysis. As a result, the incorporation of a high amount of cellulose enabled a V-0 rating to be achieved with only a small amount of APP despite the variation of the optimum cellulose loading between the matrix polymers. Through analysis, the results indicated that APP decreased the dehydration temperature of cellulose. Furthermore, APP promoted the generation of enough water as a nonflammable gas and formed enough char until the degradation of the polymer matrix was complete. The conditions required to achieve the V-0 rating were suggested against composites incorporating APP and biofillers. Furthermore, the suggested conditions were validated by using polyoxymethylene as a highly flammable polymer.

scholarly journals Reinforcing Mechanisms of Coir Fibers in Light-Weight Aggregate Concrete

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 699
Author(s):  
Xiaoxiao Zhang ◽  
Leo Pel ◽  
Florent Gauvin ◽  
David Smeulders
Keyword(s):  
Cement Hydration ◽  
Natural Fibers ◽  
Autogenous Shrinkage ◽  
Drying Shrinkage ◽  
Hydration Reaction ◽  
Light Weight ◽  
Limited Information ◽  
Aggregate Concrete ◽  
Coir Fibers ◽  
Light Weight Aggregate

Due to the requirement for developing more sustainable constructions, natural fibers from agricultural wastes, such as coir fibers, have been increasingly used as an alternative in concrete composites. However, the influence of coir fibers on the hydration and shrinkage of cement-based materials is not clear. In addition, limited information about the reinforcing mechanisms of coir fibers in concrete can be found. The goal of this research is to investigate the effects of coir fibers on the hydration reaction, microstructure, shrinkages, and mechanical properties of cement-based light-weight aggregate concrete (LWAC). Treatments on coir fibers, namely Ca(OH)2 and nano-silica impregnation, are applied to further improve LWAC. Results show that leachates from fibers acting as a delayed accelerator promote cement hydration, and entrained water by fibers facilitates cement hydration during the whole process. The drying shrinkage of LWAC is increased by adding fibers, while the autogenous shrinkage decreases. The strength and toughness of LWAC are enhanced with fibers. Finally, three reinforcement mechanisms of coir fibers in cement composites are discussed.

Synergistic effects of hybrid nanofillers on graphene oxide reinforced epoxy coating on corrosion resistance and fire retardancy

2021 ◽  
pp. 51640
Author(s):  
Siti Maznah Kabeb ◽  
Azman Hassan ◽  
Faiz Ahmad ◽  
Zurina Mohamad ◽  
Zalilah Sharer ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Graphene Oxide ◽  
Synergistic Effects ◽  
Epoxy Coating ◽  
Fire Retardancy

Enhanced thermal and fire retardancy properties of polypropylene reinforced with a hybrid graphene/glass-fibre filler

2018 ◽  
Vol 156 ◽  
pp. 95-102 ◽  
Author(s):  
Dimitrios G. Papageorgiou ◽  
Zoe Terzopoulou ◽  
Alberto Fina ◽  
Fabio Cuttica ◽  
George Z. Papageorgiou ◽  
...  
Keyword(s):  
Glass Fibre ◽  
Fire Retardancy ◽  
Fibre Filler ◽  
Graphene Glass

Fire retardancy effect of migration in polypropylene nanocomposites induced by modified interlayer

2003 ◽  
Vol 82 (2) ◽  
pp. 379-385 ◽  
Author(s):  
Gy. Marosi ◽  
A. Márton ◽  
A. Szép ◽  
I. Csontos ◽  
S. Keszei ◽  
...  
Keyword(s):  
Fire Retardancy ◽  
Polypropylene Nanocomposites

Characterization and Utilization of Coconut Fibers of the Caribbean

2014 ◽  
Vol 1611 ◽  
pp. 95-104 ◽  
Author(s):  
Nadira Mathura ◽  
Duncan Cree ◽  
Ryan P. Mulligan
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Micrographs ◽  
Saline Water ◽  
Gauge Length ◽  
Scanning Electron Micrographs ◽  
Coir Fiber ◽  
Coir Fibers ◽  
The Caribbean ◽  
Scanning Electron

ABSTRACTIn many tropical countries coconut (coir) fiber production is a major source of income for rural communities. The Caribbean has an abundance of coconuts but research into utilizing its by-products is limited. Environmentally friendly coir fibers are natural polymers generally discarded as waste material in this region. Research has shown that coir fiber from other parts of the world has successfully been recycled. This paper therefore investigates the mechanical properties of Caribbean coir fiber for potential applications in civil engineering.Approximately four hundred fibers were randomly taken from a coir fiber stack and subjected to retting in both distilled and saline water media. The mechanical properties of both the retted and unretted coir fibers were evaluated at weekly increments for a period of 3 months. Tensile strength test, x-ray diffraction analysis and scanning electron micrographs were used to assess trends and relationships between fiber gauge lengths, diameter, tensile strength and Young’s modulus. Diameters ranged between 0.11 mm-0.46 mm, while fiber samples were no longer than 250 mm in length. The tensile strength and strain at break decreased as the gauge length increased for both unretted and retted fibers. The opposite occurred for the relationship between the gauge length and Young’s modulus. Additionally, the tensile strength and modulus decreased as the fiber diameter increased. Neither distilled nor saline water improved the coir fiber’s crystalline index. Scanning electron micrographs qualitatively assessed fiber surfaces and captured necking and microfibril degradation at the fractured ends.The analysis revealed that the tensile strength, modulus, strain at break and crystallinity properties of the Caribbean coir fibers were comparable to commercially available coir fiber which are currently being used in many building applications.

scholarly journals Influence of colemanite on the fire retardancy of ethylene-vinyl acetate and ethylene-methyl acrylate copolymers

2017 ◽  
Vol 144 ◽  
pp. 401-410 ◽  
Author(s):  
Florian Cavodeau ◽  
Amandine Viretto ◽  
Belkacem Otazaghine ◽  
José-Marie Lopez-Cuesta ◽  
Christelle Delaite
Keyword(s):  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Ethylene Vinyl Acetate ◽  
Fire Retardancy ◽  
Ethylene Methyl Acrylate
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