scholarly journals Constitutive model for epoxy shape memory polymer with regulable phase transition temperature

Author(s):  
Fei Zhao ◽  
Xueyao Zheng ◽  
Shichen Zhou ◽  
Bo Zhou ◽  
Shifeng Xue ◽  
...  
2010 ◽  
Vol 148-149 ◽  
pp. 1360-1363
Author(s):  
Yong Jun Wang ◽  
Zhen Qing Wang ◽  
Hong Qing Lv ◽  
Yu Long Wang

In order to investigate the performance of shape memory alloy wire, two types of alloy wire were studied. The results showed that the phase transition temperature of the superelastic wire were: Ms and Mf were 21.18 °C and 7.08 °C; As and Af were 12.32 °C and 25.13 °C. The phase transition temperature of memory effect alloy wire were that Ms =- 11.85 °C, Mf =- 29.37 °C, As = 36.77 °C, Af = 43.35 °C. By the tensile test of the SMA wire, the stress - strain curves of the two kinds of alloy wire were obtained.


2014 ◽  
Vol 23 (10) ◽  
pp. 105019 ◽  
Author(s):  
Xiaogang Guo ◽  
Liwu Liu ◽  
Yanju Liu ◽  
Bo Zhou ◽  
Jinsong Leng

Author(s):  
A. Minori ◽  
S. Jadhav ◽  
Q. He ◽  
S. Cai ◽  
M. T. Tolley

Recent work has used self-folding origami inspired composites to produce complex, scalable, affordable, and lightweight morphing structures [1]. These characteristics are of interest for engineering applications, in fields including aerospace [2] and medical devices [3]. Due to these advantages, research on self-folding smart composites has grown, with a particular focus on the use of laminate manufacturing techniques that stack layers of heterogeneous materials to generate functional composites. Previous work used this approach to manufacture self-folding origami inspired robots [1]. A simple shape memory composite design consists of a smart material (e.g. a one-way shape memory polymer, or SMP) sandwiched between patterned rigid layers. These SMPs change their shape in response to an external stimulus (e.g. temperature). Upon heating above the phase transition temperature of the polymer (Tt), the SMP contracts, causing the laminate to fold. The SMPs used in self-folding laminate composites are unidirectional and thus the laminate is unable to recover its original state without application of external force. In this work, we study the use of thermal responsive liquid crystal elastomers (LCE) for reversible self-folding and actuation of origami inspired composites using laminate manufacturing. LCEs are smart materials that exhibit reversible deformation, good strain recoverability, and tailorable properties (i.e. phase transition temperature, strain, and orientation of deformation) [4–6]. We explore two composite hinge designs using laminate manufacturing process [1, 7] with a Joule heating layer to enable self-folding: one where the LCE acts as a tensile actuator connected only on the edges of the rigid layer, which we call a tensional hinge, and a second where the LCE is attached along the patterned rigid layer hinge, which we call a flexural hinge. The angular displacements of these two hinge designs are estimated using geometric models that account for the contraction of the LCE upon heating, and compared against experimental measurements. The maximum blocked torque of the composite hinges is also measured experimentally. To demonstrate the use of LCE as an active layer for origami inspired composites, we also present a laminate crawler robot. The crawling locomotion is controlled with an electrical heating layer laminated on the LCE. These results demonstrate the possibility of using LCE to achieve rapid, reversible folding and to generate similar torques, as compared to previous work in origami inspired self-folding composite.


2021 ◽  
Vol 2109 (1) ◽  
pp. 012001
Author(s):  
Xingxing Ma ◽  
Yun Zhou ◽  
Xia Chen ◽  
Gailing Lu ◽  
Jingjing Ji ◽  
...  

Abstract For NiTi-based alloys, the phase transition temperature directly affects and limits their application fields. In order to apply the NiTi-based shape memory alloy in the wider field, it is necessary to control the phase transformation temperature. Studies have shown that the content of Ni element in the NiTi-based alloy and the precipitates of the alloy, such as NiTi2, Ni3Ti2 and Ni4Ti3, will affect the phase transition temperature of the alloy. At the same time, adding a third or even a fourth element to the NiTi binary alloy can also effectively regulate the phase transition temperature of NiTi-based alloy. We then pay attention to the problems confronting the current state of the NiTi-based shape memory alloy. We have confidence that the NiTi-based shape memory alloy have a bright future in the development and innovation of excellent properties.


Author(s):  
Uwe Lücken ◽  
Joachim Jäger

TEM imaging of frozen-hydrated lipid vesicles has been done by several groups Thermotrophic and lyotrophic polymorphism has been reported. By using image processing, computer simulation and tilt experiments, we tried to learn about the influence of freezing-stress and defocus artifacts on the lipid polymorphism and fine structure of the bilayer profile. We show integrated membrane proteins do modulate the bilayer structure and the morphology of the vesicles.Phase transitions of DMPC vesicles were visualized after freezing under equilibrium conditions at different temperatures in a controlled-environment vitrification system. Below the main phase transition temperature of 24°C (Fig. 1), vesicles show a facetted appearance due to the quasicrystalline areas. A gradual increase in temperature leads to melting processes with different morphology in the bilayer profile. Far above the phase transition temperature the bilayer profile is still present. In the band-pass-filtered images (Fig. 2) no significant change in the width of the bilayer profile is visible.


RSC Advances ◽  
2021 ◽  
Vol 11 (41) ◽  
pp. 25664-25676
Author(s):  
Abir Hadded ◽  
Jalel Massoudi ◽  
Sirine Gharbi ◽  
Essebti Dhahri ◽  
A. Tozri ◽  
...  

The present work reports a detailed study of the spin dynamics, magnetocaloric effect and critical behaviour near the magnetic phase transition temperature, of a ferrimagnetic spinel Cu1.5Mn1.5O4.


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