scholarly journals Porous Activated Carbon Binder-free Scleria sumatrensis Stem-Based for Supercapacitor Application

2021 ◽  
Vol 2049 (1) ◽  
pp. 012008
Author(s):  
Erman Taer ◽  
Muhammad Ali Akbar Tsalis ◽  
Apriwandi ◽  
Novi Yanti ◽  
Awitdrus ◽  
...  

Abstract Green, sustainable and effective development technique to obtain high porous activated carbon biomass based is important to boosting supercapacitor performance with environmentally friendly effect as conversion system and energy storage devices. We reported porous activated carbon binder-free Scleria sumatrensis stem-based as electrode material high performance of symmetric supercapacitor. Precursor biomass of Scleria sumatrensis stem was converted into porous carbon through simple ZnCl2 impregnated with different concentration of 0.4M, 0.5M, 0.6M, and 0.7M at high-temperature phyrolysis. All samples confirmed good amorphous carbon with small amounts of oxidative compounds. In two-electrode system, the optimum sample of ACSS0.6 significantly boosting the specific capacitance as high as 142.62 F g−1 at scan rate of 1 mV s−1. Furthermore, the optimum energy density was found to be 19.80 Wh kg−1 at a maximum power density of 71.35 W kg−1 in 1 M H2SO4 aqueous electrolyte. These results confirm that the porous activated carbon binder-free Scleria sumatrensis stem-based through simple ZnCl2 impregnated as an electrode material to boosting the electrochemical behavior of supercapacitors.

RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64704-64710 ◽  
Author(s):  
Guofu Ma ◽  
Dongyang Guo ◽  
Kanjun Sun ◽  
Hui Peng ◽  
Qian Yang ◽  
...  

Cotton-based porous activated carbons (CACs) are prepared through a simple chemical activation method using cotton fiber as carbon source and ZnCl2 as activating agent.


2019 ◽  
Vol 849 ◽  
pp. 113382 ◽  
Author(s):  
Rajkumar Srinivasan ◽  
Elanthamilan Elaiyappillai ◽  
Hepsiba Paul Pandian ◽  
Renganathan Vengudusamy ◽  
Princy Merlin Johnson ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 785
Author(s):  
Tai-Feng Hung ◽  
Tzu-Hsien Hsieh ◽  
Feng-Shun Tseng ◽  
Lu-Yu Wang ◽  
Chang-Chung Yang ◽  
...  

Rational design and development of the electrodes with high-mass loading yet maintaining the excellent electrochemical properties are significant for a variety of electrochemical energy storage applications. In comparison with the slurry-casted electrode, herein, a hierarchically porous activated carbon (HPAC) electrode with higher mass loading (8.3 ± 0.2 mg/cm2) is successfully prepared. The pouch-type symmetric device (1 cell) with the propylene carbonate-based electrolyte shows the rate capability (7.1 F at 1 mA/cm2 and 4.8 F at 10 mA/cm2) and the cycling stability (83% at 12,000 cycles). On the other hand, an initial discharge capacitance of 32.4 F and the capacitance retention of 96% after 30,000 cycles are delivered from a pouch-type symmetric supercapacitor (five cells). The corresponding electrochemical performances are attributed to the fascinating properties of the HPAC and the synergistic features of the resulting electrode.


Author(s):  
Shiying Lin ◽  
Lanlan Mo ◽  
Feijun Wang

Abstract A facile and environmentally friendly approach to produce self-doped hierachically porous carbon as electrode material for high-performance supercapacitor was demonstrated. 3D honeycomb-like hierarchically porous carbon was successfully obtained by one-step carbonization and activation of sodium carboxymethyl cellulose (CMC) via K2CO3. With the optimized temperature of carbonization and activation, the porous carbon material achieved well-shaped hierarchically pores (micro-, meso and macropores) like a honeycomb, ultrahigh specific surface area (1666 m2·g-1), as well as highly O-self-doping (3.6 at.%), endowing an excellent electrochemical properties for the electrode in three-electrode system. The porous carbon electrode material delivered a high specific capacitance of 300.8 F·g-1 at 1 A·g-1, an eminent rate capability of 228.4 F·g-1 at the current density up to 20 A·g-1 and outstanding cycle stability of 94.3% retention after 10000 cycles. Therefore, the CMC derived hierarchical porous carbon activated by K2CO3 would have promising foreground in application of supercapacitors.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Pengfei Hao ◽  
Yanjie Yi ◽  
Youming Li ◽  
Yi Hou

Abstract A green and economically viable route without any additional activation agents and templates has been developed to synthesize biomass-derived nanoporous carbon for superior electric double-layer capacitors via direct pyrolysis of dried black liquor powders, which is the main waste in pulping and paper-making industry. The resulting carbon materials present hierarchical porosity and moderate specific surface area of 1134  m 2 g − 1 {\text{m}^{2}}\hspace{0.1667em}{\text{g}^{-1}} , as well as multi-heteroatoms co-doping such as N, S, Na and K, which exist originally in black liquor. When evaluated as electrode materials for supercapacitors in 6 M KOH aqueous electrolyte, the-prepared carbon samples deliver a significantly high gravimetric capacitance of 331  F g − 1 \text{F}\hspace{0.1667em}{\text{g}^{-1}} at 0.5  A g − 1 \text{A}\hspace{0.1667em}{\text{g}^{-1}} in a three-electrode system. Moreover, the fabricated symmetric supercapacitor also possesses a gravimetric capacitance of 211  F g − 1 \text{F}\hspace{0.1667em}{\text{g}^{-1}} at 0.5  A g − 1 \text{A}\hspace{0.1667em}{\text{g}^{-1}} , with an impressive long-term cycling stability of 92 % capacitance retention after 3000 cycles. This work explores a suitable and scalable approach for mass production of high-performance electrode materials with industrial wastes on the base of cost-efficiency and environment-friendship.


2021 ◽  
Author(s):  
Muhammad Irfan ◽  
Xianhua Liu ◽  
Suraya Mushtaq ◽  
Jonnathan Cabrera ◽  
Pingping Zhang

Abstract Development of sustainable electrochemical energy storage devices faces great challenge in exploring highly efficient and low cost electrode materials. Biomass waste derived carbonaceous materials can be used as an alternative to expensive metals in supercapacitor. However, their application limited by low performance. In this study, the combination use of persimmon waste derived carbon and transition metal nitride demonstrated strong potential for supercapacitor application. Persimmon based carbonaceous gel decorated with bimetallic-nitride (N-NiCo/PC) was firstly synthesized through a green hydrothermal method. Electrochemical properties of N-NiCo/PC as electrode in 6 M KOH electrolyte solution were evaluated by using cyclic voltammetry (CV) and charge-discharge measurements. The N-NiCo/PC exhibited 895.5 F/g specific capacitance at 1 A/g current density and maintained 91.5% capacitance retention after 900 cycles. Hence, the bimetallic nitride-based-composite catalyst is a potentially suitable material for high-performance energy storage devices. In addition, this work demonstrated a promising pathway for transforming environmental waste into sustainable energy conversion materials.


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