scholarly journals Electrophoretic deposition and capacitive characteristics of composite electrode materials based on CNTs and ruthenium oxide for planar supercapacitors

2021 ◽  
Vol 2086 (1) ◽  
pp. 012183
Author(s):  
Yu I Kakovkina ◽  
E A Lebedev ◽  
E P Kitsyuk ◽  
D A Kuzmin ◽  
A V Alekseyev ◽  
...  
Keyword(s):  
Electrophoretic Deposition ◽  
Composite Electrode ◽  
Electrode Materials ◽  
High Capacity ◽  
Ruthenium Oxide ◽  
Laser Engraving ◽  
Potential Applicability

Abstract In this work, a method for the formation of planar supercapacitors, which combines electrophoretic deposition of composite electrode materials based on CNTs and ruthenium oxide, and laser engraving, is proposed. The features of electrophoretic deposition are considered and the influence of the main technological modes on the morphology and composition of the formed layers of electrode materials is determined. The conducted studies of the electrophysical characteristics of the formed samples confirmed the possibility of producing planar capacitors with a high capacity and their potential applicability for a number of applications in microelectronics.

scholarly journals Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries

2017 ◽  
Vol 5 (46) ◽  
pp. 24083-24090 ◽  
Author(s):  
Hailong Lyu ◽  
Jiurong Liu ◽  
Shannon Mahurin ◽  
Sheng Dai ◽  
Zhanhu Guo ◽  
...  
Keyword(s):  
Composite Electrode ◽  
Electrode Materials ◽  
High Capacity ◽  
Lithium Ion ◽  
Chemical Oxidation ◽  
High Rate ◽  
Aromatic Polyimide ◽  
Chemical Oxidation Polymerization ◽  
Polymerization Method

Organic composite electrode materials based on aromatic polyimide (PI) and electron conductive polythiophene (PT) have been prepared by a facile in situ chemical oxidation polymerization method. The optimized composite electrode PI30PT delivers a remarkable high-rate cyclability, achieving a high capacity of 89.6 mA h g−1 at 20 C with capacity retention of 94% after 1000 cycles.

Unveiling the SEI Formation in a Potassium Ion Battery Using Distribution of Relaxation Time

2020 ◽  
Author(s):  
Yuhui Chen ◽  
Chuanchao Sheng ◽  
Fengjiao Yu ◽  
Chunmei Li ◽  
Heng Zhang ◽  
...  
Keyword(s):  
Relaxation Time ◽  
High Performance ◽  
Composite Electrode ◽  
Electrode Materials ◽  
Electrochemical Impedance ◽  
Low Cost ◽  
Solid Electrolyte Interphase ◽  
High Capacity ◽  
Sei Layer

Abstract Understanding of solid electrolyte interphase (SEI) formation process in novel battery systems is of primary importance. Alongside increasing powerful in-situ techniques, searching for readily-accessible, non-invasive, and low-cost tools to probe battery chemistry is highly demanded. Here, we applied distribution of relaxation time (DRT) analysis to interpret in-situ electrochemical impedance spectroscopy results during cycling, which is able to distinguish various electrochemical processes based on their time constants. By building direct link between SEI layer and the cell performances, it allows us track the formation and evolution process of SEI layer, diagnose the failure of cell, and unveil the reaction mechanism. For instance, in a K-ion cell using SnS2/N-doped reduced graphene oxide (N-rGO) composite electrode, we found that the ion-transport in the electrolyte phase is the main reason of cell deterioration. In the electrolyte with potassium bis(fluorosulfonyl)imide (KFSI), the porous structure of the composite electrode was reinforced by rapid formation of a robust SEI layer at SnS2/electrolyte interface and thus the KFSI-based cell delivers a high capacity and good cycleability. This method lowers the barrier of in-situ EIS analysis, and helps public researchers to explore high-performance electrode materials.

Reversible and high-capacity SnO 2 /carbon cloth composite electrode materials prepared by magnetron sputtering for Li-ion batteries

2017 ◽  
Vol 190 ◽  
pp. 56-59 ◽  
Author(s):  
Panpan Xu ◽  
Gang Wang ◽  
Junfeng Yan ◽  
Zhiyong Zhang ◽  
Manzhang Xu ◽  
...  
Keyword(s):  
Magnetron Sputtering ◽  
Composite Electrode ◽  
Electrode Materials ◽  
High Capacity ◽  
Carbon Cloth ◽  
Li Ion Batteries ◽  
Li Ion

scholarly journals Polymer Binders: Characterization and Development toward Aqueous Electrode Fabrication for Sustainability

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 631
Author(s):  
Aleksander Cholewinski ◽  
Pengxiang Si ◽  
Marianna Uceda ◽  
Michael Pope ◽  
Boxin Zhao
Keyword(s):  
Energy Storage ◽  
Electrode Materials ◽  
Storage Systems ◽  
High Capacity ◽  
Energy Storage Systems ◽  
Volume Changes ◽  
Polymer Binders ◽  
Aqueous Conditions ◽  
Aqueous Binder ◽  
Electrode Processing

Binders play an important role in electrode processing for energy storage systems. While conventional binders often require hazardous and costly organic solvents, there has been increasing development toward greener and less expensive binders, with a focus on those that can be processed in aqueous conditions. Due to their functional groups, many of these aqueous binders offer further beneficial properties, such as higher adhesion to withstand the large volume changes of several high-capacity electrode materials. In this review, we first discuss the roles of binders in the construction of electrodes, particularly for energy storage systems, summarize typical binder characterization techniques, and then highlight the recent advances on aqueous binder systems, aiming to provide a stepping stone for the development of polymer binders with better sustainability and improved functionalities.

Engineering flexible carbon nanofibers concatenated MOFs-derived hollow octahedral CoFe2O4 as anode materials for enhanced lithium storage

2021 ◽  
Author(s):  
Fangfang Xue ◽  
Yangyang Li ◽  
Chen Liu ◽  
Zhigang Zhang ◽  
Jun Lin ◽  
...  
Keyword(s):  
Mechanical Property ◽  
Anode Materials ◽  
Electrode Materials ◽  
Electronic Devices ◽  
High Capacity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Excellent Mechanical Property ◽  
Wearable Electronic ◽  
Wearable Electronic Devices

Constructing suitable electrode materials with high capacity and excellent mechanical property is indispensable for flexible lithium-ion batteries (LIBs) to satisfy the growing flexible and wearable electronic devices. Herein, a necklace-like...

scholarly journals A Theoretical Study on Reversible Solid Oxide Cells as Key Enablers of Cyclic Conversion between Electrical Energy and Fuel

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4517
Author(s):  
Saheli Biswas ◽  
Shambhu Singh Rathore ◽  
Aniruddha Pramod Kulkarni ◽  
Sarbjit Giddey ◽  
Sankar Bhattacharya
Keyword(s):  
Energy Demand ◽  
Electrode Materials ◽  
Scale Up ◽  
High Capacity ◽  
Electrical Energy ◽  
Solid Oxide ◽  
Lower Efficiency ◽  
Internal Reforming ◽  
Fuels And Chemicals ◽  
The Cost

Reversible solid oxide cells (rSOC) enable the efficient cyclic conversion between electrical and chemical energy in the form of fuels and chemicals, thereby providing a pathway for long-term and high-capacity energy storage. Amongst the different fuels under investigation, hydrogen, methane, and ammonia have gained immense attention as carbon-neutral energy vectors. Here we have compared the energy efficiency and the energy demand of rSOC based on these three fuels. In the fuel cell mode of operation (energy generation), two different routes have been considered for both methane and ammonia; Routes 1 and 2 involve internal reforming (in the case of methane) or cracking (in the case of ammonia) and external reforming or cracking, respectively. The use of hydrogen as fuel provides the highest round-trip efficiency (62.1%) followed by methane by Route 1 (43.4%), ammonia by Route 2 (41.1%), methane by Route 2 (40.4%), and ammonia by Route 1 (39.2%). The lower efficiency of internal ammonia cracking as opposed to its external counterpart can be attributed to the insufficient catalytic activity and stability of the state-of-the-art fuel electrode materials, which is a major hindrance to the scale-up of this technology. A preliminary cost estimate showed that the price of hydrogen, methane and ammonia produced in SOEC mode would be ~1.91, 3.63, and 0.48 $/kg, respectively. In SOFC mode, the cost of electricity generation using hydrogen, internally reformed methane, and internally cracked ammonia would be ~52.34, 46.30, and 47.11 $/MWh, respectively.

Toward high capacity and stable manganese-spinel electrode materials: A case study of Ti-substituted system

2014 ◽  
Vol 245 ◽  
pp. 570-578 ◽  
Author(s):  
Sihui Wang ◽  
Jiong Yang ◽  
Xiaobiao Wu ◽  
Yixiao Li ◽  
Zhengliang Gong ◽  
...  
Keyword(s):  
Electrode Materials ◽  
High Capacity

Porous diatomite-mixed 1,4,5,8-NTCDA nanowires as high-performance electrode materials for lithium-ion batteries

Nanoscale ◽  
2019 ◽  
Vol 11 (34) ◽  
pp. 15881-15891 ◽  
Author(s):  
Yong Xu ◽  
Jun Chen ◽  
Ze'en Xiao ◽  
Caixia Ou ◽  
Weixia Lv ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Composite Electrode ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Rate Performance ◽  
Transfer Impedance ◽  
Lower Charge

A novel porous diatomite composite electrode composed of NTCDA nanowires exhibits lower charge transfer impedance, higher capacity and better rate performance.

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