Copolyamide-Imide Membrane with Low CTE and CME for Potential Space Optical Applications

Polyimide diffractive membrane lens can be used in space optical telescope to reduce the size and mass of an imaging system. However, traditional commercial aromatic polyimide membrane is hard to meet the challenging requirements of dimensional stability and optical homogeneity for optical use. Based on molecular structure design and the optimization of fabrication process, the prepared copolyamide-imide membrane achieved the desired performance of membrane as an optical material. It showed a very low coefficient of thermal expansion (CTE), which is 0.95 ppm/°C over a temperature range of −150–100 °C and relatively low coefficient of moisture expansion (CME), which is only 13.30 ppm/% RH (0~90% RH). For the optical use, the prepared copolyamide-imide membrane (φ200 mm) achieved good thickness uniformity with wave-front error smaller than λ/30 (λ = 632 nm) in RMS (root mean square). Besides, it simultaneously meets the optical, thermal, and mechanical requirements for space telescope use. Copolyamide-imide membranes in this research with good comprehensive performance can be used as large aperture membrane optical system architectures.

Hydrothermal polymerization of porous aromatic polyimide networks and machine learning-assisted computational morphology evolution interpretation

We report on the hydrothermal polymerization (HTP) of porous polyimide (PI) networks using the medium H2O and the comonomers 1,3,5-tris(4-aminophenyl)benzene (TAPB) and pyromellitic acid (PMA).

A perylene-based aromatic polyimide with multiple carbonyls enabling high-capacity and stable organic lithium and sodium ion batteries

We have synthesized a perylene-based aromatic polyimide (PI) through the polycondensation of perylene dianhydride with a 2,6-DAAQ. The battery cells with the PI cathode exhibited high discharge capacities of 209 mA h g−1 (Li+/Li) and 207 mA h g−1 (Na+/Na) at 200 mA g−1.