scholarly journals The nanostructuring of ultra-high-molecular-weight polyethylene in thermal and mechanical fields as revealed by DSC

2021 ◽  
Vol 2103 (1) ◽  
pp. 012095
Author(s):  
L P Myasnikova ◽  
A K Borisov ◽  
Yu M Boiko ◽  
A P Borsenko ◽  
V F Drobot’ko ◽  
...  

Abstract The ultra-high-molecular-weight polyethylene reactor powders are widely used for the actively developing solvent-free method for producing high-strength high-modulus PE filaments, which includes the compaction and sintering of a powder followed by orientational hardening. To find an appropriate regime of the technological process, it is important to know how the nanostructure changes when transforming from a powder to a precursor for hardening. Nanocrystalline lamellae are characteristics of the powder structure. For the first time, the DSC technique was used to follow changes in the thickness distribution of lamellae in ultra-high-molecular-weight polyethylene reactor powder on its way to a precursor for orientation hardening. It was found that the percentage of thick (>15 nm) and thin (10 nm) lamellae in compacted samples and those sintered at temperatures lower than the melting temperature of PE (140°C) remains nearly the same. However, significant changes in the content of lamellae of different thicknesses were observed in the samples sintered at 145°C with subsequent cooling under different conditions. The influence of the lamellae thickness distribution in precursors on the mechanical characteristics of oriented filaments was discussed.

2018 ◽  
Vol 89 (16) ◽  
pp. 3362-3373 ◽  
Author(s):  
Shenglei Xiao ◽  
Charles Lanceron ◽  
Peng Wang ◽  
Damien Soulat ◽  
Hang Gao

Recently, triaxial braids made from ultra-high molecular weight polyethylene (UHMWPE) have been recognized as one of the most popular composite reinforcements in the aerospace and defense fields. To further explore the mechanical characteristics of this material, a detailed experimental study on tensile behavior is reported in this paper. The triaxial braids show a “double-peak” phenomenon in tensile strength and deformation, caused by axial yarns and the in-plane shearing of bias yarns. The evolution of the braiding angle, measured during these tensile tests, is discussed according to the braiding parameters (initial braiding angle, number of axial yarns). Using the high conductivity properties of the UHMWPE material, the temperature caused by inter-yarn friction during tensile tests is also studied. This temperature is related to the evolution of the braiding angle. The temperature increases with the increasing number of axial yarns and decreases with increasing braiding angle. This study provides an experimental database on the influence of braiding parameters on the tensile behavior of triaxial braids.


2019 ◽  
Vol 7 (20) ◽  
pp. 3310-3318 ◽  
Author(s):  
Ke Wu ◽  
Samuel P. Douglas ◽  
Gaowei Wu ◽  
Alexander J. MacRobert ◽  
Elaine Allan ◽  
...  

We report here for the first time how a copper coating bond to ultra-high molecular weight polyethylene (UHMWPE) via low temperature aerosol assisted chemical vapour deposition.


2006 ◽  
Vol 101 (4) ◽  
pp. 2619-2626 ◽  
Author(s):  
Atsuhiko Yamanaka ◽  
Yoshinobu Izumi ◽  
Tooru Kitagawa ◽  
Takaya Terada ◽  
Hideki Sugihara ◽  
...  

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Giangiacomo Minak ◽  
Tommaso M. Brugo ◽  
Cristiano Fragassa

Ultra-high-molecular-weight polyethylene (UHMWPE) is a subgroup of the thermoplastic polyethylene characterized by extremely long chains and, as result, in a very tough and resistant material. Due to remarkable specific mechanical properties, its use is gradually being extended to multiple fields of application. This study describes, perhaps for the first time, how the UHMWPE can represent a valid material solution in the design and optimization of suspensions for automotive use, especially in the case of extremely lightweight vehicles, such as solar cars. In particular, in this design study, UHMWPE rods permitted to assure specific kinematic trajectories, functionalities, and overall performance in an exceptionally light suspension systems, developed for an innovative multioccupant solar vehicle. These rods reduced the weight by 88% with respect to the classic design solutions with similar functions, offering, at the same time, high stiffness and accuracy in the movements. An experimental campaign was conducted to evaluate the ratcheting behaviour and other mechanical properties needed for a proper design and use.


2008 ◽  
Vol 1083 ◽  
Author(s):  
Dmitry M. Rein ◽  
Yachin Cohen ◽  
Avner Ronen ◽  
Eyal Zussman ◽  
Kim Shuster

ABSTRACTThe electrospinning method was employed to fabricate extremely fine nanofibers of ultra-high molecular weight polyethylene (UHMWPE) for the first time, using a mixture of solvents with different dielectric constant and conductivity. A novel experimental device for elevated temperature electrospinning of highly volatile and quickly crystallizing polymer solutions and melts was developed. The possibility to produce the highly oriented nanofibers from ultra-high molecular weight polymers suggests new ways for fabrication of ultra-strong, porous, surface modified fibers and single-component nanocomposite yarn with improved properties.


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