scholarly journals Effect of ZnFe2O4 Filler Loading on the Morphology and Mechanical Properties of Epoxidised Natural Rubber 25 (ENR 25)

Author(s):  
Suziey Syamimi Sukri ◽  
Syifa’ Muhamad Sharifuddin ◽  
Mohd Shukri Mat Nor ◽  
Fathin Asila Mohd Pabl ◽  
Julie Juliewatty Mohamed ◽  
...  
2004 ◽  
Vol 216 (1) ◽  
pp. 281-292 ◽  
Author(s):  
Jarunee Jeerupun ◽  
Jatuphorn Wootthikanokkhan ◽  
Pranee Phinyocheep

2014 ◽  
Vol 925 ◽  
pp. 308-312 ◽  
Author(s):  
Mou'ad A. Tarawneh ◽  
Sahrim Haji Ahmad ◽  
Yu Li Jiun ◽  
Radwan Dweiri ◽  
Ibrahim N. Hassan

In this paper the polymer nanocomposite of nickel zinc (NiZn) ferrite nanoparticles incorporated into the thermoplastic natural rubber nanocomposite (TPNR) were prepared via melt blending method. The effect of different NiZn loading (2-10 wt%) on morphology, tensile and dynamic mechanical properties of the obtained composites was investigated. It was found that NiZn ferrite is well dispersed in the thermoplastic natural rubber matrix. The tensile results indicated that filler loading has improved the tensile strength and Youngs modulus of the nanocomposite. However, the elongation at break decreased with increasing the percentage of NiZn. Dynamic mechanical test showed that the highest storage modulus is at 8 wt% filler. Any further increment of the filler content leads to the formation of agglomerate hence affecting the properties. The Scanning electron micrograph (SEM) micrographs reveal aspect ratio and filler orientation in the TPNR matrix also strongly promoted interfacial adhesion between the filler and the matrix to control its properties.


2013 ◽  
Vol 86 (2) ◽  
pp. 330-341 ◽  
Author(s):  
Hedayatollah Sadeghi Ghari ◽  
Azam Jalali Arani ◽  
Zahra Shakouri

ABSTRACT Rubber nanocomposites containing one type of nanofiller are common and are widely established in the research field. In this study, natural rubber (NR) based ternary nanocomposites containing both calcium carbonate and organoclay have been characterized on the basis of morphology, cure characteristics, and physico-mechanical behavior. Natural rubber nanocomposite samples containing modified silicate (Cloisite 15A) and also nano-carbonate calcium were prepared using a laboratory internal mixer. The effect of the mixing sequence on the morphology and mechanical properties of the samples was investigated. Based on results of morphology and mechanical properties, the dual fillers phase nanocomposites (hybrid nanocomposite) perform better in comparison with single filler phase nanocomposites. The reinforcing capability of nano-CaCO3 and organoclay in NR was characterized by means of cure rheometry, morphology, and mechanical properties. NR/single filler phase and two filler phase nanocomposites were prepared by simple melt mixing method. Concentration of nano-CaCO3 and organoclay in NR was 10 and 5 parts per one hundred parts of rubber by weight, respectively. The microstructure and homogeneity of the compounds was confirmed by studying the dispersion of nanoparticles in NR via X-ray diffraction and field emission scanning electron microscopy. A more pronounced effect was achieved by using dual filler based nanocomposites as compared with single filler phase nanocomposites. The obtained results reveal that hybrid nanocomposites have more adequate morphology, rheometery, and mechanical behaviors as well as swelling resistance. The effect of mixing sequence of fillers has been studied in detail. Simultaneous addition of the two nanofillers to the NR compound would lead to better nanocomposite properties compared with other mixing sequences. Also, the results show that the mixing sequence of these nanofillers in NR has little effect on the performance of the nanocomposite.


2013 ◽  
Vol 86 (4) ◽  
pp. 615-625 ◽  
Author(s):  
Oraphin Chaikumpollert ◽  
Osamu Wakisaka ◽  
Akio Mase ◽  
Yoshimasa Yamamoto ◽  
Krisda Suchiva ◽  
...  

ABSTRACT Decelerated fermentation of natural rubber latex was performed to investigate the relationship between the morphology and mechanical properties of natural rubber. Natural rubber latex was preserved with sodium hydroxymethylglycinate, as a bactericide, to decelerate the fermentation of nonrubber components such as proteins, phospholipids, carbohydrate, and so forth. Gradual increases in the viscosity of the latex and gel content of the resulting rubber took place as the preservation period was prolonged, which were distinguished from less change in the viscosity of high-ammonia natural rubber (HANR) and high gel content of its rubber. The particle size distribution was dramatically changed during decelerated fermentation, although that of the HANR latex did not change. The pH and nitrogen content of the rubbers were independent of the preservation time. Morphology of the fermented natural rubber and the HANR was observed with scanning probe microscopy. Fewer mechanical properties of the fermented natural rubber were related to the destruction of the nanomatrix structure of the nonrubber components, which resulted from the decrease in the fatty acid ester groups with bacteria as compared with the good mechanical properties of the HANR.


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