scholarly journals Crystallization and mechanical properties of carbon nanotube/continuous carbon fiber/metallocene polypropylene composites

2021 ◽  
Author(s):  
Hongsheng Tan ◽  
Xiuxue Guo ◽  
Hao Tan ◽  
Qinglu Zhang ◽  
Changheng Liu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Nanotube ◽  
Carbon Fiber ◽  
Metallocene Catalyst ◽  
Scanning Calorimetry ◽  
Polypropylene Composites ◽  
Dynamic Mechanical ◽  
Continuous Carbon Fiber ◽  
Melting And Crystallization

Abstract In this work, a high fluidity polypropylene prepared with the metallocene catalyst (mPP) was used as matrix, carbon nanotube (CNT) and continuous carbon fiber (CCF) were added to prepare composites, and their mechanical properties, melting and crystallization behavior were investigated. In the mechanical properties, the effects of tension force in the preparation process and compatibilizer maleic anhydride grafted polypropylene (MAPP) on the tensile strength of the composites were researched. The results show that the tensile strength of the composites increases first and then decreases with the increase of tractive force. In addition, the melting and crystallization behaviors and dynamic mechanical behaviors of mPP, CNT/mPP and CNT/CCF/mPP composites were characterized and studied by a differential scanning calorimetry (DSC) and dynamic mechanical analyzer (DMA). The results show that the melting point (Tm ), crystallization temperature (Tc ) and storage modulus (E') of CNT/mPP are all increased by adding 1wt% CNT, especially the Tc is increased by 8.8 ºC. It shows that after CNT was added to mPP as inorganic carbon material, it plays a prominent role in heterogeneous nucleation. After CCF was composited with CNT/mPP, the composites with CCF content of 30 and 42wt% were prepared, and their Tm , Tc , crystallinity (Xc ) and E' were all improved, especially E' was greatly improved, such as the initial E' was increased by 5.64 and 11.74 times. Even at the end of the curve, the E' of the composites with CF is still significantly higher than that of mPP and CNT/mPP. It indicates that adding CCF will greatly improved the deformation resistance and load deformation temperature of mPP.

STRAIN-INDUCED CRYSTALLIZATION AND MECHANICAL PROPERTIES OF NBR COMPOSITES WITH CARBON NANOTUBE AND CARBON BLACK

2012 ◽  
Vol 85 (2) ◽  
pp. 207-218 ◽  
Author(s):  
Sang-Ryeoul Ryu ◽  
Jong-Whan Sung ◽  
Dong-Joo Lee
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Nanotube ◽  
Carbon Black ◽  
Scanning Calorimetry ◽  
Multiwalled Carbon ◽  
Extension Ratio ◽  
The Matrix ◽  
Strain Induced Crystallization ◽  
Induced Crystallization

Abstract The mechanical properties and strain-induced crystallization (SIC) of elastomeric composites were investigated as functions of the extension ratio (λ), multiwalled carbon nanotube (CNT) content, and carbon black (CB) content. The tensile strength and modulus gradually increase with increasing CNT content when compared with the matrix and the filled rubbers with same amount of CB. Both properties of rubber with CB and CNT show the magnitude of each CNT and CB component following the Pythagorean Theorem. The ratio of tensile modulus is much higher than that of tensile strength because of the CNT shape/orientation and an imperfect adhesion between CNT and rubber. The tensile strength and modulus of the composite with a CNT content of 9 phr increases up to 31% and 91%, respectively, compared with the matrix. Differential scanning calorimetry (DSC) analysis reveals that the degree of SIC increases with an increase in CNT content. Mechanical properties have a linear relation with the latent heat of crystallization (LHc), depending on the CNT content. As the extension ratio increases, the glass-transition temperature (Tg) of the composite increases for CB- and CNT-reinforced cases. However, the LHc has a maximum of λ = 1.5 for the CNT-reinforced case, which relates to a CNT shape and an imperfect adhesion with rubber. Based on these results, the reinforcing mechanisms of CNT and CB are discussed.

scholarly journals Synergistic effect on static and dynamic mechanical properties of carbon fiber-multiwalled carbon nanotube hybrid polycarbonate composites

RSC Advances ◽  
2016 ◽  
Vol 6 (72) ◽  
pp. 67954-67967 ◽  
Author(s):  
Arun Singh Babal ◽  
Bhanu Pratap Singh ◽  
Jeevan Jyoti ◽  
Sushant Sharma ◽  
Abhishek Kumar Arya ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotube ◽  
Carbon Fiber ◽  
Synergistic Effect ◽  
Dynamic Mechanical Properties ◽  
Multiwalled Carbon Nanotube ◽  
Multiwalled Carbon ◽  
Dynamic Mechanical ◽  
Functionalized Mwcnts

The synergistic effect of reinforced non-functionalized and functionalized MWCNTs accompanied by CF is observed on the mechanical properties in a polycarbonate matrix.

Mechanical properties of vapor-grown carbon fiber composites with thermoplastic matrices

1999 ◽  
Vol 14 (7) ◽  
pp. 2871-2880 ◽  
Author(s):  
Gary G. Tibbetts ◽  
John J. McHugh
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Fiber ◽  
Surface Preparation ◽  
Fiber Surface ◽  
Three Dimensions ◽  
Injection Molding Process ◽  
Carbon Fiber Composites ◽  
Molding Process ◽  
Polypropylene Composites

This article discusses the mechanical properties of vapor-grown carbon fiber (VGCF)/nylon and VGCF/polypropylene composites. Fibers in the as-produced condition yielded composites with marginally improved mechanical properties. Microscopic examination of these composites clearly showed regions of uninfiltrated fibers, which could account for the unsatisfactory mechanical properties. The infiltration of the fibers by both polymers was improved by carefully ball milling the raw fiber so as to reduce the diameter of the fiber clumps to less than 300 μm. Properties of composites made with ball-milled material were improved in every respect. VGCF reinforcement in nylon slightly improved the tensile strength and doubled the modulus, while VGCF in polypropylene doubled the tensile strength and quadrupled the modulus compared to unreinforced material. Moreover, the composites were sufficiently improved that differences in fiber surface preparation became important. For example, air-etched fibers and fibers covered with low concentrations of aromatics produced polypropylene composites with significantly better mechanical properties than did fibers whose surfaces were heavily coated with aromatics. Both the tensile strength and the modulus of the composites fabricated with clean fibers exceeded theoretical values for composites made with fibers randomly oriented in three dimensions, indicating that the injection-molding process oriented the fibers to some extent.

Mechanical properties of carbon nanotube/carbon fiber reinforced thermoplastic polymer composite

2015 ◽  
Vol 38 (9) ◽  
pp. 2001-2008 ◽  
Author(s):  
Wenbo Liu ◽  
Lizhi Li ◽  
Shu Zhang ◽  
Fan Yang ◽  
Rongguo Wang
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotube ◽  
Carbon Fiber ◽  
Polymer Composite ◽  
Thermoplastic Polymer ◽  
Fiber Reinforced ◽  
Carbon Fiber Reinforced

scholarly journals Styrene–Acrylic Emulsion with “Transition Layer” for Damping Coating: Synthesis and Characterization

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1406
Author(s):  
Daoyuan Chen ◽  
Mingjin Ding ◽  
Zhixiong Huang ◽  
Yanbing Wang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Transition Layer ◽  
Testing Machine ◽  
Dynamic Mechanical Properties ◽  
Mechanical Analysis ◽  
Latex Film ◽  
Seeded Emulsion Polymerization ◽  
Acrylic Emulsion ◽  
Dynamic Mechanical

In order to study the dynamic mechanical properties of styrene–acrylic latex with a core/shell structure, a variety of latexes were synthesized by semi-continuous seeded emulsion polymerization based on “particle design” with the same material. The latexes were characterized by rotary viscosimeter, dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), transmission electron microscope (TEM), dynamic mechanical analysis (DMA), and universal testing machine. The effects of difference at the glass transition temperature (Tg) of core and shell and the introduction of the “transition layer” on the damping and mechanical properties of latex film were studied. The results indicate that as the Tg of core and shell gets closer, the better the compatibility of core and shell, from phase separation to phase continuity. Furthermore, the introduction of the “transition layer” can effectively improve the tensile strength and tan δ (max) of the latex film. The tensile strength and maximum loss factor (f = 1 Hz) of latex with the “transition layer” increased by 36.73% and 29.11% respectively compared with the latex without the “transition layer”. This work provides a reference for the design of emulsion for damping coating.

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