Sublimation in a Wilson chamber

About fifty years ago Professor C. T. R. Wilson began a classical series of experiments (Wilson 1895 to 1933) on the condensation of water vapour in both dust-free and ordinary air. The only reference to ice throughout that work is as follows (Wilson 1897 c , p. 299): ‘It is assumed here that the cloud-particles are actually liquid drops and not ice crystals, in spite of the fact that the condensation begins at temperatures much below the freezing-point and that the temperature when the particles are fully grown is, as we shall see, also slightly below the freezing-point.’ In the present paper experiments are described in which the final temperatures after expansion are much lower. These confirm that down to surprisingly low temperatures only liquid water droplets are formed, but they show that after a threshold low temperature is passed ice particles begin to be formed. These ice particles are not formed by the freezing of water droplets but by the direct sublimation of water vapour to ice crystals, and the process has some essential differences from the condensation of water vapour at higher temperatures. The experiments also indicate that in ordinary outdoor air there are no sublimation nuclei on which the ice crystals form when the air is supersaturated at temperatures between 0 and — 32° C.

2014 ◽  
Vol 986-987 ◽  
pp. 80-83
Author(s):  
Xiao Xue Zhang ◽  
Zhen Feng Wang ◽  
Cui Hua Li ◽  
Jian Hong Liu ◽  
Qian Ling Zhang

N-methyl-N-allylpyrrolidinium bis (trifluoromethanesulfonyl) imide (PYR1ATFSI) with substantial supercooling behavior is synthesized to develop low temperature electrolyte for lithium-ion batteries. Additive fluoroethylene carbonate (FEC) in LiTFSI/PYR1ATFSI/EC/PC/EMC is found that it can reduce the freezing point. LiFePO4/Li coin cells with the FEC-PYR1ATFSI electrolyte exhibit good capacity retention, reversible cycling behavior at low temperatures. The good performance can be attributed to the decrease in the freezing point and the polarization of the composite electrolyte.


2005 ◽  
Vol 95 (11) ◽  
pp. 1279-1286 ◽  
Author(s):  
E. Gamliel-Atinsky ◽  
D. Shtienberg ◽  
H. Vintal ◽  
Y. Nitzni ◽  
A. Dinoor

Temperature and wetness conditions required for development and maturation of Didymella rabiei pseudothecia were determined in a series of experiments conducted in controlled-environmental conditions. Initial stages of pseudothecium formation occurred at temperatures ranging from 5 to 15°C. Incubation at low temperatures was essential for subsequent pseudothecium maturation. This requirement was satisfied for chickpea stem segments incubated at 5 or 10°C for three consecutive weeks or during periods of 3 or 5 days, separated by periods at higher temperatures. Following the low-temperature requirement, subsequent pseudothecium development was independent of temperature in the range tested (5 to 20°C). Wetness was essential for pseudothecium production: pseudothecia formed and matured on stem segments maintained continuously wet but also on those exposed to periods of three or five wet days, separated by dry periods. The dispersal of D. rabiei ascospores was studied using chickpea plants as living traps in the field. Trap plants were infected mainly when exposed during rain but also in rainless periods. Results of this study enabled us to describe the developmental events leading to the production of the teleomorph stage and the dispersal of ascospores by D. rabiei in the Mediterranean climate of Israel.


2014 ◽  
Vol 1081 ◽  
pp. 279-283 ◽  
Author(s):  
Nan Zhang ◽  
Juan Liao ◽  
Tao Zhang ◽  
Wen Zhan Ji

Thermal deformation of concrete at low temperature expands from-20°C to-50°C and contracts from-30°C to-10°C. Based on previous studies, the paper tries to explain the deformaion trend by analyzing freezing point of bulk solution and pore solution in saturated hardened cement paste. The result shows that it is critical to thermal deformation of cement-based materials at low temperature that pore solution in the pores smaller than 8 nm freezes.


2019 ◽  
Author(s):  
Alexei Korolev ◽  
Ivan Heckman ◽  
Mengistu Wolde ◽  
Andrew S. Ackerman ◽  
Ann M. Fridlind ◽  
...  

Abstract. This study attempts identification of mechanisms of secondary ice production (SIP) based on the observation of small faceted ice crystals (hexagonal plates or columns) with characteristic sizes smaller than 100 μm. Due to their young age, such small ice crystals can be used as tracers for identifying the conditions for SIP. Observations reported here were conducted in oceanic tropical mesoscale convective systems (MCS) and mid-latitude frontal clouds in the temperature range from 0 °C to −15 °C heavily seeded by aged ice particles. It was found that both in MCSs and frontal clouds, SIP was observed right above the melting layer and extended to the higher altitudes with colder temperatures. It is proposed that the initiation of SIP above the melting layer is related to the circulation of liquid drops through the melting layer. Liquid drops formed via melting ice particles are advected by the convective updrafts above the melting layer, where they impact with aged ice, freeze and shatter. The ice splinters generated by shattering initiate the chain reaction of SIP. The size of the splinters generated during SIP were estimated as 10 μm or less. In most SIP cases, small secondary ice particles spatially correlated with liquid phase, vertical updrafts and aged rimed ice particles. However, in many cases neither graupel nor liquid drops were observed in the SIP regions, and therefore, the conditions for an active Hallett-Mossop process were not met. A principal conclusion of this work is that the freezing drop shattering mechanism is alone among established SIP mechanisms is plausibly accounting for the measured ice concentrations in the observed conditions. No other SIP mechanisms could be confidently identified from the airborne in-situ observations.


Author(s):  
Haiyang Hu ◽  
Linchuan Tian ◽  
Hui Hu

Ice accretion on exposed surfaces of aero-engine components has been widely recognized as a significant hazard to aviation safety in cold weathers. Icing process due to the impingement of the supercooled water droplets suspended in the cloud onto the cold surfaces of inlet components of aeroengines have been studied extensively for decades. Since ice particles were believed to simply bounce off from the exposed surfaces of aero-engine components, ice crystals in the clouds were initially considered not to pose a threat to aviation safety. Therefore, the ice accretion process due to the impacting of ice crystals onto the surfaces of hot engine componentes has not been studied until recently. It has been found recently that, tiny ice particles in the cloud may be partial/full melting upon impacting onto the hot surfaces of aero-engine components, such as heated Inlet Guide Vanes (IGV) and various probes. The partially/fully melted ice crystals were found to stick onto the hot surfaces and form thin water film, which would intercept more oncoming ice particles and lead to significant ice accretion over the surfaces of the hot engine components. The ice crystal induced ice accumulation on the critical aero-engine components has been found to cause significant engine performance loss and erroneous data being read from the probes. In the present study, a series of experimental investigations were conducted to elucidate the underlying physics of the dynamic ice accretion process pertinent to ice crystal icing phenomena. A novel ice crystal icing test rig with the capacity of generating controllable amount of ice crystals and flying speed up to 100 m/s was developed in a temperature-controllable environment chamber for the ice crystal icing studies. By using a high-speed imaging system, a digital particle image velocimetry(PIV), and an Infrared (IR) thermal imaging system, a comprehensive experimental campaign was performed to characterize the transient impacting process of ice crystals, dynamic ice accretion and unsteady heat transfer process associated with the impacting of ice crystals onto heated surfaces, in comparison to those due to the impingement of supercooled water droplets. By using an ultra-sensitive force sensor and a high-speed image system, a comparative study is conducted to examine the differences in the transient impinging dynamics of single water droplets, supercooled water droplets, and ice crystals onto solid surfaces with different wettability and stiffness. By upgrading the unique Icing Research Tunnel of Iowa State University (i.e., ISU-IRT) with additional ice crystal icing capability, a set of explorative studies are also conducted to examine the characteristics of the dynamic ice accretion processes over the heated surfaces of an aero-engine Inlet Guide Vane (IGV) model under both ice crystal icing and supercooled droplet icing conditions. The anti-/de-icing performance of a novel hybrid strategy by integrating icephobic coatings and minimized surface heating are also evaluated under both supercooled water droplet icing and ice crystal icing conditions. The new findings derived from the present studies are very helpful to gain further insights into the ice crystal icing phenomena for the development of more effective and robust anti-/de-icing strategies to ensure safer and more efficient aircraft/aero-engine operations in cold weathers.


1948 ◽  
Vol 21 (1) ◽  
pp. 94-111
Author(s):  
S. D. Gehman ◽  
D. E. Woodford ◽  
C. S. Wilkinson

Abstract The low temperature stiffening of elastomers frequently limits their usefulness. A new laboratory test for measuring their stiffness at low temperatures is described. Strips of the stocks to be tested are mounted around a cylindrical rack in a vertical, cylindrical insulated chamber. The temperature in the chamber is controlled by cooling the base externally with dry ice and by a moderate regulated flow of precooled air through dry ice in the bottom of the chamber. This system gives stable temperatures which are easily controlled. The chamber can be rotated to attach the samples in succession, by means of projecting top grips, to a suitably mounted torsion wire. The stiffness is measured by the angle of twist of the sample when the torsion head is rotated 180°. The relative modulus for any temperature is calculated as the ratio of the modulus at this temperature to that at 25° C. Plots of angle of twist against temperature show a rather sharp break at the low temperature end of the curve. This determines a somewhat subjective “freezing point”. Curves are given to illustrate the wide variety of low temperature stiffening characteristics for elastomers. In unplasticized stocks the chemical composition of the monomers is the dominating factor for these properties for various synthetic rubbers. The stiffness of elastomers which are capable of crystallization on stretching, such as Hevea, Neoprene, and Butyl rubber, depends not only on temperature but also on time of exposure. To study these effects, the foregoing apparatus was used in a cold room. A rather long induction period occurs, during which the stiffness is essentially constant. It then increases and eventually reaches a larger constant value. Several months may be required to complete these changes. x-Ray examination of Hevea and Butyl proved that the increased stiffness on long exposure is due to crystallization. No change was observed in the stiffness of GR-S in the period of 2.5 months at − 30° C. Reduction in the speed of retraction is a critical measure of the deterioration of high elasticity at low temperatures. It gives a wide differeniation at moderately low temperatures between Butyl rubber and Hevea or GR-S, whereas a slow modulus test does not.


2020 ◽  
Vol 20 (3) ◽  
pp. 1391-1429 ◽  
Author(s):  
Alexei Korolev ◽  
Ivan Heckman ◽  
Mengistu Wolde ◽  
Andrew S. Ackerman ◽  
Ann M. Fridlind ◽  
...  

Abstract. This study attempts a new identification of mechanisms of secondary ice production (SIP) based on the observation of small faceted ice crystals (hexagonal plates or columns) with typical sizes smaller than 100 µm. Due to their young age, such small ice crystals can be used as tracers for identifying the conditions for SIP. Observations reported here were conducted in oceanic tropical mesoscale convective systems (MCSs) and midlatitude frontal clouds in the temperature range from 0 to −15 ∘C and heavily seeded by aged ice particles. It was found that in both MCSs and frontal clouds, SIP was observed right above the melting layer and extended to higher altitudes with colder temperatures. The roles of six possible mechanisms to generate the SIP particles are assessed using additional observations. In most observed SIP cases, small secondary ice particles spatially correlated with liquid-phase, vertical updrafts and aged rimed ice particles. However, in many cases, neither graupel nor liquid drops were observed in the SIP regions, and therefore, the conditions for an active Hallett–Mossop process were not met. In many cases, large concentrations of small pristine ice particles were observed right above the melting layer, starting at temperatures as warm as −0.5 ∘C. It is proposed that the initiation of SIP above the melting layer is stimulated by the recirculation of large liquid drops through the melting layer with convective turbulent updrafts. After re-entering a supercooled environment above the melting layer, they impact with aged ice, freeze, and shatter. The size of the splinters generated during SIP was estimated as 10 µm or less. A principal conclusion of this work is that only the freezing-drop-shattering mechanism could be clearly supported by the airborne in situ observations.


Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1184
Author(s):  
Alirio Benavides ◽  
Pedro Benjumea ◽  
Farid Cortés ◽  
Marco Ruiz

The physicochemical properties of petroleum-derived jet fuels mainly depend on their chemical composition, which can vary from sample to sample as a result of the diversity of the crude diet processed by the refinery. Jet fuels are exposed to very low temperatures both at altitude and on the ground in places subject to extreme climates and must be able to maintain their fluidity at these low temperatures otherwise the flow of fuel to turbine engines will be reduced or even stopped. In this work, an experimental evaluation of the effect of chemical composition on low-temperature fluidity properties of jet fuels (freezing point, crystallization onset temperature and viscosity at −20 °C) was carried out. Initially, a methodology based on gas chromatography coupled to mass spectrometry (GC–MS) was adapted to determine the composition of 70 samples of Jet A1 and Jet A fuels. This methodology allowed quantifying the content, in weight percentage, of five main families of hydrocarbons: paraffinic, naphthenic, aromatic, naphthalene derivatives, and tetralin- and indane-derived compounds. Fuel components were also grouped into 11 classes depending on structural characteristics and the number of carbon atoms in the compound. The latter compositional approach allowed obtaining more precise model regressions for predicting the composition–property dependence and identifying individual components or hydrocarbon classes contributing to increased or decreased property values.


2020 ◽  
Vol 56 (67) ◽  
pp. 9640-9643
Author(s):  
Yang Yang ◽  
Panlong Li ◽  
Nan Wang ◽  
Zhong Fang ◽  
Congxiao Wang ◽  
...  

A novel fluorinated electrolyte is formulated with low freezing point and solvation energy, realizing high performance batteries that operate at low temperatures.


Author(s):  
John Davenport

The embryos of Icelandic capelin (which spawn subtidally) tolerate as low temperatures, and are as euryhaline, as those of Balsfjord capelin which spawn intertidally. The median lethal lower temperature for Icelandic capelin eggs exposed for 6 h to low temperatures in frozen seawater films (34‰) is -6.3°C. The median lethal high salinity (6 h exposure) is 88.3‰. Eggs were reared and hatched successfully in all salinities from 1.5 to 34‰. When exposed to high salinities capelin eggs shrink in a matter of seconds (shrinkage being manifested in depressions of the chorion), but resume a normal shape in a few minutes as salts diffuse into the perivitelline fluid. Evidence is presented to show that mortality in frozen seawater films is due to osmotic dehydration, rather than to a final invasion by ice crystals. A model of freezing avoidance in capelin eggs is described.


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