Electrodeposition in support: concentration gradients, an ohmic model and the genesis of branching fractals

The technique of paper-supported copper electrodeposition provides examples of well-presented fractal and dense radial structures. The growths may be developed to reveal concentration gradients around the growths at low cell overpotential. Measurements for current and length scale against time, within a mid-range of cell overpotentials, fit an ohmic model of the growth conditions. To examine the relation of growth morphology to the micrometre-scale structure, we grew first at one overpotential and then continued at a lower overpotential. Electron microscope observations of this growth reveal a distinct change in microstructure from irregular to dentritic microcrystalline from the high to low potential respectively. The interface between the growths is a distinctive compact granular deposit. The granular deposit is unstable to branching and dendrite growth.

Author(s):  
J C Walmsley ◽  
A R Lang

Interest in the defects and impurities in natural diamond, which are found in even the most perfect stone, is driven by the fact that diamond growth occurs at a depth of over 120Km. They display characteristics associated with their origin and their journey through the mantle to the surface of the Earth. An optical classification scheme for diamond exists based largely on the presence and segregation of nitrogen. For example type Ia, which includes 98% of all natural diamonds, contain nitrogen aggregated into small non-paramagnetic clusters and usually contain sub-micrometre platelet defects on {100} planes. Numerous transmission electron microscope (TEM) studies of these platelets and associated features have been made e.g. . Some diamonds, however, contain imperfections and impurities that place them outside this main classification scheme. Two such types are described.First, coated-diamonds which possess gem quality cores enclosed by a rind that is rich in submicrometre sized mineral inclusions. The transition from core to coat is quite sharp indicating a sudden change in growth conditions, Figure 1. As part of a TEM study of the inclusions apatite has been identified as a major constituent of the impurity present in many inclusion cavities, Figure 2.


2021 ◽  
Vol 555 ◽  
pp. 153110
Author(s):  
Kui Liu ◽  
Tan tan ◽  
Xuanpu Zhou ◽  
Nantao Zheng ◽  
Yue Ma ◽  
...  

2019 ◽  
Vol 295 ◽  
pp. 93-97
Author(s):  
Chang Zhao ◽  
Man Zhao ◽  
Su Ye Lv ◽  
Qing Jun Liu ◽  
Guang Jian Xing

This study prepared an SiC thin film by using the ratio frequency magnetron sputtering method, investigated the effects of different sputtering powers on the SiC material and analysed the changes in crystal morphology and photoluminescence characteristics caused by changes in the growth conditions used. It was considered that there was 6H-SiC crystal morphologies in the SiC thin film under the experimental conditions prevailing in this study. The SiC morphologies with small grain sizes intermingled and therefore formed anSiC thin film. The analyses of the photoluminescence spectra and Scanning Electron Microscope indicated that the SiC thin film materials with preferable crystal compositions could be prepared under appropriate power inputs.


1992 ◽  
Vol 38 (2) ◽  
pp. 98-103 ◽  
Author(s):  
M. A. Glazebrook ◽  
L. C. Vining ◽  
R. L. White

Most media in which the growth of shaken submerged cultures of Streptomyces akiyoshiensis was examined did not support the formation of well-dispersed mycelial suspensions. Investigation of the culture conditions promoting dispersed growth showed the pH of the culture medium to be of critical importance; an initial value of 5.5 minimized aggregation of the mycelium while supporting adequate biomass production. In cultures started at this pH, spore inocula gave better mycelial dispersal than did vegetative inocula; with spore inocula, growth morphology was also less affected by inoculum size. The composition of the nutrient solution influenced the extent of mycelial dispersal; slow growth was often associated with clumping but no clear correlation was observed between pellet formation and the ability of carbon or nitrogen sources to support rapid growth. Increasing the phosphate concentration from 0.5 to 15 mM caused a modest decrease in mycelial aggregation. Conditions promoting a well-dispersed mycelium suitable for studying the physiological control of secondary metabolism also supported the formation of 5-hydroxy-4-oxonorvaline by S. akiyoshiensis. Key words: Streptomyces akiyoshiensis, mycelial aggregation, growth conditions.


1988 ◽  
Vol 3 (3) ◽  
pp. 406-409 ◽  
Author(s):  
S. McKernan ◽  
B. C. De Cooman ◽  
C. B. Carter ◽  
D. P. Bour ◽  
J. R. Shealy

Gax In1 − x Pepilayers grown under a range of growth conditions by organometallic vapor phase epitaxy (OMVPE) on GaAs substrates have been studied in the electron microscope. The results show the presence of an ordering of the group III sublattice parallel to some of the {111} planes. Dark-field images directly reveal ordered domains of different orientations that appear not to be perfect, but contain many planar defects parallel to the growth surface.


Small ◽  
2021 ◽  
pp. 2104287
Author(s):  
Amita Ummadisingu ◽  
Aditya Mishra ◽  
Dominik J. Kubicki ◽  
Thomas LaGrange ◽  
Algirdas Dučinskas ◽  
...  
Keyword(s):  

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