VI. On a collection of rock specimens from the Island of Socotra

1883 ◽  
Vol 174 ◽  
pp. 273-294 ◽  

The specimens of rocks—about 500 in number—collected by Professor Bayley Balfour during his late exploration of the Island of Socotra, were forwarded to me for examination. Several of these specimens, as was to be expected under the circumstances, were in a condition unfavourable for precise determination, being often fragments from weathered surfaces and sometimes much decomposed. Each, however, has been described as far as the circumstances would admit, and microscopic slides have been prepared for me by Mr. Cuttell from about 80 of the more interesting. As it happens, certain of these offer difficulties which in the present state of our knowledge are almost insuperable. While the use of the microscope has dispelled much confusion in our petrological ideas and supplied us in many respects with a firm basis of knowledge, it has not in every case—owing to the novelty of this mode of research and the inherent difficulties—enabled the student to feel perfect confidence in some of his conclusions, especially when he is restricted to this method of examination. Perhaps the greatest of our petrological difficulties is the distinguishing in every case between certain highly metamorphosed rocks and those of similar chemical composition which are truly igneous. It has, indeed, been maintained by some eminent geologists that certain sedimentary materials may be so altered by the combined action of water, heat, and pressure as to be converted in situ into a rock indistinguishable from one of those commonly held to be of igneous origin. Accordingly we read not seldom of “metamorphic granite” and of “gneiss passing into granite,” for it is of these that the above opinion is commonly held. Other geologists, indeed, go yet further and make a similar assertion, not only of the more coarsely crystalline rocks such as syenite, diorite, and gabbro, but even of the more compact varieties of felstone and greenstone, which in like manner are said to afford indubitable examples of transition into beds of true sedimentary origin. As regards this view, we may admit that if a mass of clastic materials be once reduced to a molten magma its past history is obliterated; and, further, that there is no reason, so far as we know, why this melting down should not occur. In this sense, any igneous rock whatever may possibly deserve the name of metamorphic. But, while admitting the à priori possibility of such a change, I must confess to being sceptical as to whether any case of it has yet been fully proved to exist. I have studied not a few of the alleged instances patiently and, as I trust, without prejudice, always with the following results—either that there was no evidence which was conclusive on either side, or that to a practised eye there was very clear evidence against the asserted transition— i. e ., that (to refer to the instance named above) either the so-called granite was clearly only a granitoid gneiss or else that it was distinctly intrusive in the schistose rock. In these investigations the microscope is a very great help, but I freely admit that there are many cases where we cannot rely upon it alone, and must also study the rock in the field. Our knowledge at present does not enable us to pronounce upon the classificatory value of certain structures which we observe in the microscopic study of some specimens. This difficulty, however, is one which time and experience will probably remove. To admit the existence of cases where it is at present safer to suspend the judgment in no way concedes that it is impossible ultimately to arrive at a conclusion. So then, while not professing in every case from examination of hand specimens alone to decide whether a rock is a granitoid gneiss or a true granite, I believe in the distinctness of the two rocks. As it happens, some of the specimens from Socotra belong to this dubious class; and I cannot say positively, even after microscopic examination, whether in certain cases we have a granitoid gneiss or a true granite, and in others a hornblendic rock of sedimentary origin or a true diorite.

2020 ◽  
Author(s):  
Danielle Grotjahn ◽  
Saikat Chowdhury ◽  
Gabriel C. Lander

AbstractCryo-electron tomography is a powerful biophysical technique enabling three-dimensional visualization of complex biological systems. Macromolecular targets of interest identified within cryo-tomograms can be computationally extracted, aligned, and averaged to produce a better-resolved structure through a process called subtomogram averaging (STA). However, accurate alignment of macromolecular machines that exhibit extreme structural heterogeneity and conformational flexibility remains a significant challenge with conventional STA approaches. To expand the applicability of STA to a broader range of pleomorphic complexes, we developed a user-guided, focused refinement approach that can be incorporated into the standard STA workflow to facilitate the robust alignment of particularly challenging samples. We demonstrate that it is possible to align visually recognizable portions of multi-subunit complexes by providing a priori information regarding their relative orientations within cryo-tomograms, and describe how this strategy was applied to successfully elucidate the first three-dimensional structure of the dynein-dynactin motor protein complex bound to microtubules. Our approach expands the application of STA for solving a more diverse range of heterogeneous biological structures, and establishes a conceptual framework for the development of automated strategies to deconvolve the complexity of crowded cellular environments and improve in situ structure determination technologies.


2020 ◽  
Author(s):  
Veronica Peverelli ◽  
Tanya Ewing ◽  
Daniela Rubatto ◽  
Martin Wille ◽  
Alfons Berger ◽  
...  

Abstract. Monoclinic epidote is a low-µ (µ = 283U / 204Pb) mineral occurring in a variety of geological environments, participating in many metamorphic reactions and stable throughout a wide range of pressure–temperature conditions. Despite containing fair amounts of U, its use as a U–Pb geochronometer has been hindered by the commonly high contents of initial Pb with isotopic compositions that cannot be assumed a priori. We present U–Pb geochronology of hydrothermal-vein epidote spanning a wide range of Pb (3.9–190 µg g−1), Th (0.009–38 µg g−1) and U (2.6–530 µg g−1) contents and with µ values between 7–510 from the Albula area (eastern Swiss Alps), from the Grimsel area (central Swiss Alps) and from the Heyuan fault (Guangdong province, China). The investigated epidote samples show appreciable fractions of initial Pb that vary to different extents. A protocol has been developed for in situ U–Pb dating of epidote by spot-analysis laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) with a magmatic allanite as primary reference material. The suitability of the protocol and the reliability of the measured isotopic ratios have been ascertained by independent measurements of 238U / 206Pb and 207Pb / 206Pb ratios respectively by quadrupole and multicollector ICP–MS applied to epidote micro-separates digested and diluted in acids. For age calculation, we used the Tera–Wasserburg (207Pb / 206Pb–238U / 206Pb) diagram, which does not require corrections for initial Pb and provides the initial 207Pb / 206Pb ratio if all intra-sample analyses are co-genetic. Petrographic and microstructural data indicate that the calculated ages date the crystallization of vein epidote from a hydrothermal fluid and that the U–Pb system was not reset to younger ages by later events. Vein epidote from the Albula area formed in the Paleocene (62.7 ± 3.0 Ma) and is related to Alpine greenschist-facies metamorphism. The Miocene (19.1 ± 4.0 Ma and 16.9 ± 3.7 Ma) epidote veins from the Grimsel area formed during the Handegg phase (22–17 Ma) of the Alpine evolution of the Aar Massif. Identical initial 207Pb / 206Pb ratios reveal homogeneity in Pb isotopic compositions of the fluid across ca. 200 m. Vein epidote from the Heyuan fault is Cretaceous in age (108.1 ± 8.4 Ma) and formed during the early movements of the fault. In situ U–Pb analyses of epidote returned reliable ages of otherwise undatable epidote-quartz veins. The Tera–Wasserburg approach has proven pivotal for in situ U–Pb dating of epidote and the decisive aspect for low age uncertainties is the variability in intra-sample initial Pb fractions.


2009 ◽  
Vol 59 (4) ◽  
pp. 823-832 ◽  
Author(s):  
Ye Changqing ◽  
Wang Dongsheng ◽  
Wu Xiaohong ◽  
Qu Jiuhui ◽  
John Gregory

The speciation of Al-OH complexes in terms of Ala, Alb and Alc could be achieved by traditional ferron assay and Alb is generally considered as Al13, however, the inherent correlation between them remains an enigma. This paper presents a modified ferron assay to get precise determination of Al13 using nonlinear least squares analysis, and to clarify the correlation between Alb and Al13. Two parallel reactions conforming to pseudo-first-order kinetics can simulate the complicate reactions between polynuclear complexes and ferron successfully. Four types of experimental kinetic constant (k value) of Al-OH complexes can be observed by this method when investigating three typical aluminium solutions. Comparing with the results of 27Al NMR, the species with moderate kinetics around 0.001 s−1 can be confirmed to resemble to Al13 polycation. The other types of kinetics are also well-regulated in partially neutralized aluminium solutions with various OH/Al ratios (b values) in the range 0 ∼ 2.5. It would provide potential means to trace the in-situ formation of Al13 in dilute solutions such as coagulation with Al-based coagulants


Author(s):  
Nobuyoshi Fujimatsu ◽  
Isao Misu

New method and means are proposed to measure the skin friction force on an aerodynamic surface based on elastic deformations of silicon rubber and gel coatings. One of characteristics is soft and easy to deform. Object is coated by elastic polymeric film with known shear modulus. Two images between wind-on and wind-off are taken using the CCD camera. The displacement of coating is calculated from the correlation of two images. There are two ways to calibrate the skin friction force to the displacement of coatings. These methods are tested and compared to quantitative skin friction force measurement. One is based on measuring the characteristics of the polymeric film using visco-elastic measurement system. This way is called as a priori calibration. The other way is accomplished from the relation between the skin friction force measured by the PHF embedded on the object and the displacement around there and is known as In-situ method. Characteristics of the coatings such as the displacement and the time response can be easily controlled by the compounding ratio of hardener. We conduct the theoretical analysis for the elastic polymer film and propose the material properties of the coatings required to measure the surface skin friction in the wide range of flow speed. The skin friction over the plate is measured using this technique in various Reynolds number. The traditional measurement using the hot wire anemometry is conducted to validate this technique. The time averaged measurements of this technique are in good agreement with the traditional results. However, the unsteady characteristics of surface skin friction are not captured by the lack of time resolution of the CCD camera.


Plants ◽  
2019 ◽  
Vol 8 (7) ◽  
pp. 242
Author(s):  
Mathias Schuetz ◽  
Mario Fidanza ◽  
Jim Mattsson

Based on mutant phenotypes the MONOPTEROS (MP)/Auxin Response Factor 5 (ARF5) gene acts in several developmental processes including leaf vein development. Since overlapping functions among ARF genes are common, we assessed the related ARF 3-8 and 19 genes for potential overlap in expression during vein development using in-situ hybridization. Like MP/ARF5, ARF3 was expressed in preprocambial and procambial cells. ARF7 was also expressed in procambial cells, close to and during vein differentiation. ARF19 was expressed in differentiating vessel elements. To assess if genes with vein expression have overlapping functions, double mutants were generated. While arf3, 5 and 7 mutants formed leaves normally, double mutant combinations of mp/arf5 with arf3 or arf7 resulted in a breakdown of leaf formation. Instead, novel structures not present in any of the single mutants formed. The results implicate ARF3 and ARF7 in rosette leaf formation and suggest that their functions overlap and act in parallel with MP/ARF5 in this process. The observed vascular expression patterns suggest unique functions (ARF7 and 19) and potentially overlapping functions (ARF3 and 5) in vein development. Since arf3 arf5 double mutants do not form leaves, assessment of their potential combined action in vein development will require the use of conditional mutants.


2015 ◽  
Vol 8 (11) ◽  
pp. 3747-3763 ◽  
Author(s):  
E. Andersson ◽  
M. Kahnert ◽  
A. Devasthale

Abstract. Hemispheric transport of air pollutants can have a significant impact on regional air quality, as well as on the effect of air pollutants on regional climate. An accurate representation of hemispheric transport in regional chemical transport models (CTMs) depends on the specification of the lateral boundary conditions (LBCs). This study focuses on the methodology for evaluating LBCs of two moderately long-lived trace gases, carbon monoxide (CO) and ozone (O3), for the European model domain and over a 7-year period, 2006–2012. The method is based on combining the use of satellite observations at the lateral boundary with the use of both satellite and in situ ground observations within the model domain. The LBCs are generated by the global European Monitoring and Evaluation Programme Meteorological Synthesizing Centre – West (EMEP MSC-W) model; they are evaluated at the lateral boundaries by comparison with satellite observations of the Terra-MOPITT (Measurements Of Pollution In The Troposphere) sensor (CO) and the Aura-OMI (Ozone Monitoring Instrument) sensor (O3). The LBCs from the global model lie well within the satellite uncertainties for both CO and O3. The biases increase below 700 hPa for both species. However, the satellite retrievals below this height are strongly influenced by the a priori data; hence, they are less reliable than at, e.g. 500 hPa. CO is, on average, underestimated by the global model, while O3 tends to be overestimated during winter, and underestimated during summer. A regional CTM is run with (a) the validated monthly climatological LBCs from the global model; (b) dynamical LBCs from the global model; and (c) constant LBCs based on in situ ground observations near the domain boundary. The results are validated against independent satellite retrievals from the Aqua-AIRS (Atmospheric InfraRed Sounder) sensor at 500 hPa, and against in situ ground observations from the Global Atmospheric Watch (GAW) network. It is found that (i) the use of LBCs from the global model gives reliable in-domain results for O3 and CO at 500 hPa. Taking AIRS retrievals as a reference, the use of these LBCs substantially improves spatial pattern correlations in the free troposphere as compared to results obtained with fixed LBCs based on ground observations. Also, the magnitude of the bias is reduced by the new LBCs for both trace gases. This demonstrates that the validation methodology based on using satellite observations at the domain boundary is sufficiently robust in the free troposphere. (ii) The impact of the LBCs on ground concentrations is significant only at locations in close proximity to the domain boundary. As the satellite data near the ground mainly reflect the a priori estimate used in the retrieval procedure, they are of little use for evaluating the effect of LBCs on ground concentrations. Rather, the evaluation of ground-level concentrations needs to rely on in situ ground observations. (iii) The improvements of dynamic over climatological LBCs become most apparent when using accumulated ozone over threshold 40 ppb (AOT40) as a metric. Also, when focusing on ground observations taken near the inflow boundary of the model domain, one finds that the use of dynamical LBCs yields a more accurate representation of the seasonal variation, as well as of the variability of the trace gas concentrations on shorter timescales.


1997 ◽  
Vol 51 (2) ◽  
pp. 247-252 ◽  
Author(s):  
Jeffrey F. Aust ◽  
Karl S. Booksh ◽  
Christopher M. Stellman ◽  
Richard S. Parnas ◽  
Michael L. Myrick

A method for real-time determination of the percent cure of epoxies via in situ fiber-optic Raman spectroscopy has been developed. This method utilizes a probe design developed for real-time monitoring of polymer curing and multivariate analysis to interpret the data and determine percent cure. This method was demonstrated to be reliable to ±0.54% of cure in laboratory samples over a 50–99% cure range. A preliminary study measuring cure percentage in an industrial, glass-reinforced composite has been shown to be reliable to ±0.82% in the 40–90% cure range.


2017 ◽  
Vol 17 (7) ◽  
pp. 4781-4797 ◽  
Author(s):  
Liang Feng ◽  
Paul I. Palmer ◽  
Hartmut Bösch ◽  
Robert J. Parker ◽  
Alex J. Webb ◽  
...  

Abstract. We use the GEOS-Chem global 3-D model of atmospheric chemistry and transport and an ensemble Kalman filter to simultaneously infer regional fluxes of methane (CH4) and carbon dioxide (CO2) directly from GOSAT retrievals of XCH4 : XCO2, using sparse ground-based CH4 and CO2 mole fraction data to anchor the ratio. This work builds on the previously reported theory that takes into account that (1) these ratios are less prone to systematic error than either the full-physics data products or the proxy CH4 data products; and (2) the resulting CH4 and CO2 fluxes are self-consistent. We show that a posteriori fluxes inferred from the GOSAT data generally outperform the fluxes inferred only from in situ data, as expected. GOSAT CH4 and CO2 fluxes are consistent with global growth rates for CO2 and CH4 reported by NOAA and have a range of independent data including new profile measurements (0–7 km) over the Amazon Basin that were collected specifically to help validate GOSAT over this geographical region. We find that large-scale multi-year annual a posteriori CO2 fluxes inferred from GOSAT data are similar to those inferred from the in situ surface data but with smaller uncertainties, particularly over the tropics. GOSAT data are consistent with smaller peak-to-peak seasonal amplitudes of CO2 than either the a priori or in situ inversion, particularly over the tropics and the southern extratropics. Over the northern extratropics, GOSAT data show larger uptake than the a priori but less than the in situ inversion, resulting in small net emissions over the year. We also find evidence that the carbon balance of tropical South America was perturbed following the droughts of 2010 and 2012 with net annual fluxes not returning to an approximate annual balance until 2013. In contrast, GOSAT data significantly changed the a priori spatial distribution of CH4 emission with a 40 % increase over tropical South America and tropical Asia and a smaller decrease over Eurasia and temperate South America. We find no evidence from GOSAT that tropical South American CH4 fluxes were dramatically affected by the two large-scale Amazon droughts. However, we find that GOSAT data are consistent with double seasonal peaks in Amazonian fluxes that are reproduced over the 5 years we studied: a small peak from January to April and a larger peak from June to October, which are likely due to superimposed emissions from different geographical regions.


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