scholarly journals Characterization of heteropoly acids by X-ray powder diffraction at SPring-8

2005 ◽  
Vol 61 (a1) ◽  
pp. c485-c485
Author(s):  
A. Kitano ◽  
K. Miura ◽  
K. Miyashita ◽  
N. Adachi ◽  
I. Matsuda ◽  
...  
Keyword(s):  
Powder Diffraction ◽  
Heteropoly Acids ◽  
X Ray

New horizons for the structural characterization of stainless steel slags by X-ray powder diffraction

2007 ◽  
Vol 2007 (suppl_26) ◽  
pp. 61-66 ◽  
Author(s):  
B. Peplinski ◽  
B. Adamczyk ◽  
G. Kley ◽  
K. Adam ◽  
F. Emmerling ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Powder Diffraction ◽  
Structural Characterization ◽  
X Ray ◽  
New Horizons

Distorted chiolite crystal structures of α-Na5M3F14 (M=Cr,Fe,Ga) studied by X-ray powder diffraction

2003 ◽  
Vol 18 (2) ◽  
pp. 128-134 ◽  
Author(s):  
A. Le Bail ◽  
A.-M. Mercier
Keyword(s):  
Crystal Structures ◽  
Powder Diffraction ◽  
Room Temperature ◽  
Rietveld Refinements ◽  
Space Group ◽  
X Ray ◽  
Precise Characterization

The crystal structures of the chiolite-related room temperature phases α-Na5M3F14 (MIII=Cr,Fe,Ga) are determined. For all of them, the space group is P21/n, Z=2; a=10.5096(3) Å, b=7.2253(2) Å, c=7.2713(2) Å, β=90.6753(7)° (M=Cr); a=10.4342(7) Å, b=7.3418(6) Å, c=7.4023(6) Å, β=90.799(5)° (M=Fe), and a=10.4052(1) Å, b=7.2251(1) Å, c=7.2689(1), β=90.6640(4)° (M=Ga). Rietveld refinements produce final RF factors 0.036, 0.033, and 0.035, and RWP factors, 0.125, 0.116, and 0.096, for MIII=Cr, Fe, and Ga, respectively. The MF6 polyhedra in the defective isolated perovskite-like layers deviate very few from perfect octahedra. Subtle octahedra tiltings lead to the symmetry decrease from the P4/mnc space group adopted by the Na5Al3F14 chiolite aristotype to the P21/n space group adopted by the title series. Facile twinning precluded till now the precise characterization of these compounds.

Structural characterization of two K2SnX(PO4)3 (X=Fe,Yb) with langbeinite structure

2006 ◽  
Vol 21 (3) ◽  
pp. 214-219 ◽  
Author(s):  
Abderrahim Aatiq ◽  
Btissame Haggouch ◽  
Rachid Bakri ◽  
Youssef Lakhdar ◽  
Ismael Saadoune
Keyword(s):  
Solid State ◽  
Powder Diffraction ◽  
Room Temperature ◽  
Cell Parameter ◽  
Rietveld Analysis ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Octahedral Sites ◽  
Parameter Values

Structures of two K2SnX(PO4)3(X=Fe,Yb) phosphates, obtained by conventional solid state reaction techniques at 950 °C, were determined at room temperature by X-ray powder diffraction using Rietveld analysis. The two materials exhibit the langbeinite-type structure (P213 space group, Z=4). Cubic unit cell parameter values are: a=9.9217(4) Å and a=10.1583(4) Å for K2SnFe(PO4)3 and K2SnYb(PO4)3, respectively. Structural refinements show that the two crystallographically independent octahedral sites (of symmetry 3) have a mixed Sn∕X (X=Fe,Yb) population although ordering is stronger in the Yb phase than in the Fe phase.

Synthesis, Structure, and Characterization of La1−xBax (0 ≤ x ≤ 1)

1992 ◽  
Vol 271 ◽  
Author(s):  
Joseph E. Sunstrom ◽  
Susan M. Kauzlarich
Keyword(s):  
Magnetic Susceptibility ◽  
Powder Diffraction ◽  
Single Phase ◽  
Gravimetric Analysis ◽  
Thermal Gravimetric ◽  
Temperature Dependent ◽  
X Ray ◽  
Early Transition Metal ◽  
Arc Melting

ABSTRACTThe compounds La1−xBaxTiO3 (0 ≤ × ≤ 1) have been prepared by arc melting stoichiometric amounts of LaTiO3 and BaTiO3. Single phase samples can be made for the entire stoichiometry range. The polycrystalline samples have been characterized by thermal gravimetric analysis, X-ray powder diffraction, and temperature dependent magnetic susceptibility. This series of compounds has been studied as a possible candidate for an early transition metal superconductor.

X-ray powder diffraction structural characterization of Ba1-xEuxTiO3 ternary oxides

2005 ◽  
Vol 40 (7) ◽  
pp. 703-708 ◽  
Author(s):  
D.-Y. Lu ◽  
M. Sugano ◽  
W.-H. Su ◽  
T. Koda
Keyword(s):  
Powder Diffraction ◽  
Structural Characterization ◽  
X Ray ◽  
Ternary Oxides

Preparation and characterization of iron oxide pillared montmorillonite

Clay Minerals ◽  
1988 ◽  
Vol 23 (4) ◽  
pp. 367-377 ◽  
Author(s):  
D. H. Doff ◽  
N. H. J. Gangas ◽  
J. E. M. Allan ◽  
J. M. D. Coey
Keyword(s):  
Magnetic Properties ◽  
Iron Oxide ◽  
Powder Diffraction ◽  
Mössbauer Spectra ◽  
Pillared Clay ◽  
Cross Linking ◽  
X Ray ◽  
Pillared Montmorillonite ◽  
Mossbauer Spectra

AbstractPillared smectites in which the pillars consist of iron oxide are expected to have interesting and unusual magnetic properties. Several possible routes by which such materials might be made have been investigated, namely intercalation of hydroxy-Fe(III) polycations, mixed hydroxy-Fe(III)/Al polycations, phenanthroline-Fe(II) cations, and trinuclear Fe(III) acetato cations into Na-montmorillonite. Only the last of these yielded a pillared clay (PILC) on calcination. The products have been characterized using X-ray powder diffraction and 57Fe Mössbauer spectroscopy. The precursor Fe-PILC has a d-spacing of 21 Å and expands to 23 Å on solvation with glycol. The calcined Fe-PILC has a d-spacing of 19 Å (gallery height 9·4 Å) and does not expand with glycol, confirming cross-linking of the layers. From Mössbauer spectra at 4·2 K it is estimated that there are of the order of some hundred Fe atoms per pillar.

scholarly journals Preparation and Characterization of Quinoxaline-Pyrene-Based Conjugated Copolymers for Organic Photovoltaic Devices

Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1098
Author(s):  
Bakhet A. Alqurashy ◽  
Bader M. Altayeb ◽  
Sulaiman Y. Alfaifi ◽  
Majed Alawad ◽  
Ahmed Iraqi ◽  
...  
Keyword(s):  
Molecular Orbital ◽  
Powder Diffraction ◽  
Bulk Heterojunction ◽  
Gel Permeation Chromatography ◽  
Band Gap Energy ◽  
Slight Reduction ◽  
X Ray ◽  
Highest Occupied Molecular Orbital ◽  
Lowest Unoccupied Molecular Orbital

In this study, two novel conjugated polymers, poly(4,5,9,10-tetrakis((2-ethylhexyl)oxy]pyrene-alt-2,3-bis(3-(octyloxy)phenyl)-5,8-di(2-thienyl)-6,7-difluoroquinoxaline) (PPyQxff) and poly(4,5,9,10-tetrakis((2-ethylhexyl)oxy)pyren-alt-2,3-bis(3-(octyloxy)phenyl)-5,8-di(2-thienyl)quinoxaline) (PPyQx), consisting of quinoxaline units with and without fluorine substituents, as electron-accepting moieties and pyrene flanked with dithienyl units as electron-donating moieties were prepared via Stille polymerization reactions for use as electron donor materials in bulk heterojunction (BHJ) solar cells. PPyQxff and PPyQx were characterized by X-ray powder diffraction (XRD), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), cyclic voltammetry (CV), UV−VIS absorption, and nuclear magnetic resonance (NMR) spectroscopy. PPyQxff and PPyQx revealed excellent solution processability in common organic solvents. PPyQxff and PPyQx presented decomposition temperatures above 300 °C. The inclusion of F atoms to the quinoxaline moiety made a slight reduction in the highest occupied molecular orbital (HOMO) level, relative to the unfluorinated polymer, but had no impact on the lowest unoccupied molecular orbital (LUMO) level. PPyQxff and PPyQx exhibited similar physical properties with strong and broad absorbance from 400 to 700 nm and an optical band-gap energy of 1.77 eV. The X-ray powder diffraction study indicated that PPyQxff possessed a reduced π–π stacking distance relative to PPyQx.

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