Influence of the as-cast state on the crystallization process and magnetic properties for FeSiBCuNb wires

1994 ◽  
Vol 30 (6) ◽  
pp. 4794-4796 ◽  
Author(s):  
P. Marin ◽  
A.O. Olofinjana ◽  
M. Vazquez ◽  
H.A. Davies
2007 ◽  
Vol 130 ◽  
pp. 171-174 ◽  
Author(s):  
Z. Stokłosa ◽  
G. Badura ◽  
P. Kwapuliński ◽  
Józef Rasek ◽  
G. Haneczok ◽  
...  

The crystallization and optimization of magnetic properties effects in FeXSiB (X=Cu, V, Co, Zr, Nb) amorphous alloys were studied by applying X-ray diffraction methods, high resolution transmission electron microscopy (HRTEM), resistometric and magnetic measurements. The temperatures of the first and the second stage of crystallization, the 1h optimization annealing temperature and the Curie temperature were determined for different amorphous alloys. Activation energies of crystallization process were obtained by applying the Kissinger method. The influence of alloy additions on optimization effect and crystallization processes was carefully examined.


1999 ◽  
Vol 577 ◽  
Author(s):  
G P Hatch ◽  
A J Williams ◽  
I R Harris

ABSTRACTAlloys of Pr-Fe-B-Cu were cast into Cu and stainless steel tubes. It could be seen that a preferred crystallographic orientation was obtained after cooling. Fine platelets of Pr2Fe1 4B matrix phase were formed, surrounded by various grain boundary phases, and there was a significant reduction in the amount of free Fe present, in comparison to conventional slab cast alloys. In order to improve the magnetic properties in the as-cast state, two alternative routes were used. The first involved a series of two step heat treatments to develop an improved microstructure. After an optimum heat treatment of 1000 'C for 24 hours + 500°C for 3 hours, significantly improved magnetic properties were obtained for a 17.5 % Pr alloy; Br = 752 mT, Hci = 613 kAm−1 and BHmax = 96 kJm−3. The second route involved a rapid upset forging [RUF] process, with a strain rate of 11.5 s−1, to hot deform the alloys. Following post-forging heat treatments, properties of Br = 966 mT, Hci = 780 kAm−3 and BHmax = 160 kJm−3 were obtained for a 15% Pr alloy. That nature of the improvements in properties as a result of heat treatments and RUF were investigated and are discussed in the present work.


2006 ◽  
Vol 131 (1-3) ◽  
pp. 45-48 ◽  
Author(s):  
A. Kalezić-Glišović ◽  
L. Novaković ◽  
A. Maričić ◽  
D. Minić ◽  
N. Mitrović

2000 ◽  
Vol 644 ◽  
Author(s):  
Martin Hollmark ◽  
Victor Tkatch ◽  
Sergey Khartsev ◽  
Alex Grishin

AbstractA glassy structure was formed in the Fe40Co40P14B6 alloy by melt-spinning technique. The as-quenched 2-8 mm wide and 15-30 [.proportional]m thick ribbons exhibit good soft magnetic properties: the saturation magnetization of 1.45 T, the coercive force of 4 A/m and maximum differential permeability at 60 Hz of about 90000. The FeCo-based glass crystallizes via eutectic reaction into a mixture of an austenite and a b.c. tetragonal Fe3P-like phase similar to that of the well-known Fe40Ni40P14B6metallic glass, but at temperatures about 60 K higher than the latter. The evaluation of the thermodynamic and kinetic parameters of crystallization process brought us to the conclusion that the improved thermal stability of the Fe40Co40P14B6 glass is caused by the enhanced interfacial nucleus-glass energy.


2002 ◽  
Vol 189 (3) ◽  
pp. 877-881 ◽  
Author(s):  
A. Saad ◽  
V. Cremaschi ◽  
J. Moya ◽  
B. Arcondo ◽  
H. Sirkin

2015 ◽  
Vol 60 (3) ◽  
pp. 1987-1992
Author(s):  
M. Nabiałek

AbstractThis work presents the results of investigations into the structural and magnetic properties of the bulk amorphous alloy: Fe64Co10Y6B20. The structure, thermal stability and magnetic properties of the alloy were studied using: X-ray diffractometry, differential scanning calorimetry (DSC), and a vibrating sample magnetometer (VSM), respectively. The investigations were performed on samples of the alloy in both the ‘as-cast’ state, and the state resulting from a process of isothermal annealing at a temperature of 750 K for 30 minutes.The aim of the conducted studies was to relax the structure and improve the soft magnetic properties of the investigated alloy. The results show that annealing the alloy at a temperature well below its crystallisation temperature leads to an increase in the value of the saturation magnetisation and a decrease in the value of the coercivity. Utilising the ‘approach to the ferromagnetic saturation’ theorem, the nature of structural defects within the investigated material has been established. For both ‘as-cast’ and isothermally-annealed samples, the magnetisation process has been found to be connected with the existence of linear structural defects.


2016 ◽  
Vol 61 (1) ◽  
pp. 445-450
Author(s):  
K. Błoch

This paper presents studies relating to the structure, soft magnetic properties and thermal stability of the following bulk amorphous alloys: Fe61Co10Ti3-xY6+xB20 (x = 0, 1). On the basis of the performed X-ray diffraction studies and Mössbauer spectroscopy, it was found that investigated samples were amorphous in the as-cast state. The DSC curve obtained for Fe61Co10Ti2Y7B20 alloy exhibited one exothermic peak, while for the Fe61Co10Ti3Y6B20 sample, two peaks were distinguishable. The change in the chemical structure of the investigated alloys has a major effect on their soft magnetic properties; especially on coercivity and saturation magnetization. On the basis of the magnetization curves analysis, the spin wave stiffness parameter Dsp were determined for the investigated alloys.


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