Preparation and Characterization of the Soft Magnetic FeCo-based Amorphous Alloy with Enhanced Magnetic Properties and Thermal Stability

2000 ◽  
Vol 644 ◽  
Author(s):  
Martin Hollmark ◽  
Victor Tkatch ◽  
Sergey Khartsev ◽  
Alex Grishin

AbstractA glassy structure was formed in the Fe40Co40P14B6 alloy by melt-spinning technique. The as-quenched 2-8 mm wide and 15-30 [.proportional]m thick ribbons exhibit good soft magnetic properties: the saturation magnetization of 1.45 T, the coercive force of 4 A/m and maximum differential permeability at 60 Hz of about 90000. The FeCo-based glass crystallizes via eutectic reaction into a mixture of an austenite and a b.c. tetragonal Fe3P-like phase similar to that of the well-known Fe40Ni40P14B6metallic glass, but at temperatures about 60 K higher than the latter. The evaluation of the thermodynamic and kinetic parameters of crystallization process brought us to the conclusion that the improved thermal stability of the Fe40Co40P14B6 glass is caused by the enhanced interfacial nucleus-glass energy.

2018 ◽  
Vol 914 ◽  
pp. 73-79
Author(s):  
Chang Cheng Fang ◽  
Qing Rong Yao ◽  
Yong Qiang Xu ◽  
Huai Ying Zhou ◽  
Guang Hui Rao ◽  
...  

To understand the phase composition and improve the magnetic performances of Ce2Fe14B-type alloys, the ribbons of Ce16Fe95-xCoxB8(x=0-4.0) were prepared by melt-spinning at a quench wheel velocity of 40 m/s. The phase composition and magnetic properties of Ce16Fe95-xCoxB8(x=0-4.0) alloys were investigated. XRD results indicated that the main phase existed in the as-spun ribbons is Ce2Fe14B. The amorphous formation ability and thermal stability of as-spun ribbons were enhanced by trace cobalt addition. Co-doped samples had higher Curie temperature compared with bare Ce2Fe14B, which signified that Co atoms could substitute for Fe directly into Ce2Fe14B phase. The corrosion potential of alloys from-1089mV (vs. SCE) to-1077mV (vs. SCE) which indicated that the Co-doped provided better corrosion protection properties for the Ce-Fe-B magnet compared with bare substrate.


2018 ◽  
Vol 24 (3) ◽  
pp. 223 ◽  
Author(s):  
Andrea Školáková ◽  
Petra Hanusová ◽  
Filip Průša ◽  
Pavel Salvetr ◽  
Pavel Novák ◽  
...  

<p>In this work, Al-11Fe, Al-7Fe-4Ni and Al-7Fe-4Cr (in wt. %) alloys were prepared by combination of casting and hot extrusion. Microstructures of as-cast alloys were composed of aluminium matrix with large and coarse intermetallics such as Al<sub>13</sub>Fe<sub>4</sub>, Al<sub>13</sub>Cr<sub>2</sub> and Al<sub>5</sub>Cr. Subsequently, as-cast alloys were rapidly solidified by melt-spinning technique which led to the supersaturation of solid solution alloying elements. These rapidly solidified ribbons were milled and compacted by hot-extrusion method. Hot-extrusion caused that microstructures of all alloys were fine with uniform dispersed particles. Moreover, long-term thermal stability was tested at temperature 300 °C for as-cast and hot-extruded alloys and chromium was found to be the most suitable element for alloying to improve thermal stability.    </p>


2013 ◽  
Vol 203-204 ◽  
pp. 380-385 ◽  
Author(s):  
Małgorzata Karolus

Amorphous alloys based on iron, obtained by melt spinning technique, are modern and very promising soft magnetic materials. The thermal annealing at temperatures closed to the crystallization temperature can cause an increase of magnetic permeability more than 10 times i.e. the so called enhancement of soft magnetic properties effect (ESMP). It is usually explained by formation of iron nanocrystallites in amorphous surroundings or by formation of the relaxed amorphous phase. Such a microstructure leads to averaging out of magnetic anisotropy and cause the ESMP.


1992 ◽  
Vol 7 (12) ◽  
pp. 962-968
Author(s):  
M. Jimbo ◽  
E. Sobue ◽  
S. Tsunashima ◽  
S. Uchiyama ◽  
T. Kato

2019 ◽  
Vol 821 ◽  
pp. 250-255
Author(s):  
Vladimir S. Tsepelev ◽  
Yuri N. Starodubtsev ◽  
V.Ya. Belozerov

In this work, the effect of different inhibitors on the thermal stability of the magnetic properties in Fe73.5Cu1M3Si13.5B9 nanocrystalline alloys, where M = Nb, W, Mo, was investigated. Nanocrystalline alloy with tungsten has the greatest thermal stability. The change in the magnetic properties in the ageing process was associated with vacancies and vacancy clusters, the formation of which is facilitated by large atoms of inhibitory elements occupying free positions in the substitution solid solution.


2010 ◽  
Vol 163 ◽  
pp. 165-168 ◽  
Author(s):  
Ryszard Nowosielski ◽  
Rafał Babilas ◽  
Grzegorz Dercz ◽  
Lucjan Pająk

The work presents a crystallization process of Fe-based amorphous alloy by characterization of the influence of annealing temperature on structural changes and magnetic properties of Fe72B20Si4Nb4 metallic glass. The studies were performed on the samples in the form of ribbons and rods. Crystallization behaviour of the studied alloy was examined by X-ray diffraction (XRD) and transmission electron microscopy (TEM) methods. The studies of soft magnetic properties of tested material involved magnetic permeability, saturation induction, coercive field and magnetic after-effects measurements.


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