Constitutive Modeling of Shape Memory Effects in Semicrystalline Polymers With Stretch Induced Crystallization

2010 ◽  
Vol 132 (4) ◽  
Author(s):  
Kristofer K. Westbrook ◽  
Vikas Parakh ◽  
Taekwoong Chung ◽  
Patrick T. Mather ◽  
Logan C. Wan ◽  
...  
Keyword(s):  
Shape Memory ◽  
Constitutive Modeling ◽  
Three Dimensional ◽  
Constitutive Models ◽  
Shape Memory Polymers ◽  
One Dimensional ◽  
Chain Mobility ◽  
Shape Memory Effects ◽  
External Stimuli ◽  
Induced Crystallization

Polymers can demonstrate shape memory (SM) effects by being temporarily fixed in a nonequilibrium shape and then recover their permanent shape when exposed to heat, light, or other external stimuli. Many previously developed shape memory polymers (SMPs) use the dramatic molecular chain mobility change around the glass transition temperature Tg to realize the SM effect. In these materials, the temporary shape cannot be repeated unless it is reprogramed, and therefore the SM effect is one way. Recently, a semicrystalline SMP, which can demonstrate both one- and two-way SM effects, was developed by one of our groups (Chung, T., Rorno-Uribe, A., and Mather, P. T., 2008, “Two-Way Reversible Shape Memory in a Semicrystalline Network,” Macromolecules, 41(1), pp. 184–192). The main mechanism of the observed SM effects is due to stretch induced crystallization. This paper develops a one-dimensional constitutive model to describe the SM effect due to stretch induced crystallization. The model accurately describes the complex thermomechanical SM effect and can be used for the future development of three-dimensional constitutive models.

Three-dimensional Graphene Coated Shape Memory Polyurethane Foam with Fast Responsive Performance

2021 ◽  
Author(s):  
Tianjiao Wang ◽  
Jun Zhao ◽  
Chuanxin Weng ◽  
Tong Wang ◽  
Yayun Liu ◽  
...  
Keyword(s):  
Shape Memory ◽  
Polyurethane Foam ◽  
Three Dimensional ◽  
Shape Memory Polymers ◽  
Practical Applications ◽  
External Stimuli ◽  
Shape Memory Polyurethane

Shape memory polymers (SMPs) that change shapes as designed by external stimuli have become one of the most promising materials as actuators, sensors, and deployable devices. However, their practical applications...

scholarly journals Applications of Shape Memory Polymers in Kinetic Buildings

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Jing Li ◽  
Qiuhua Duan ◽  
Enhe Zhang ◽  
Julian Wang
Keyword(s):  
Shape Memory ◽  
Electric Fields ◽  
Constitutive Models ◽  
Shape Memory Polymers ◽  
Building Energy ◽  
Building Structures ◽  
Academic Researchers ◽  
Building Energy Saving ◽  
External Stimuli ◽  
Building Engineering

Shape memory polymers (SMPs) have attracted significant attention from both industrial and academic researchers, due to their useful and fascinating functionality. One of the most common and studied external stimuli for SMPs is temperature; other stimuli include electric fields, light, magnetic fields, water, and irradiation. Solutions for SMPs have also been extensively studied in the past decade. In this research, we review, consolidate, and report the major efforts and findings documented in the SMP literature, according to different external stimuli. The corresponding mechanisms, constitutive models, and properties (i.e., mechanical, electrical, optical, shape, etc.) of the SMPs in response to different stimulus methods are then reviewed. Next, this research presents and categorizes up-to-date studies on the application of SMPs in dynamic building structures and components. Following this, we discuss the need for studying SMPs in terms of kinetic building applications, especially about building energy saving purposes, and review recent two-way SMPs and their potential for use in such applications. This review covers a number of current advances in SMPs, with a view towards applications in kinetic building engineering.

Three-Dimensional Numerical Simulation of Thermomechanical Constitutive Model for Shape Memory Polymers With Application to Morphing Wing Skin

2013 ◽  
Author(s):  
Olaniyi A. Balogun ◽  
Changki Mo ◽  
A. K. Mazher ◽  
John C. Brigham
Keyword(s):  
Numerical Simulation ◽  
Finite Element ◽  
Constitutive Model ◽  
Shape Memory ◽  
Three Dimensional ◽  
Shape Memory Polymers ◽  
Thermomechanical Behavior ◽  
One Dimensional ◽  
Simulation Results ◽  
Wing Skin

This paper presents three-dimensional numerical simulation of thermomechanical constitutive model for shape memory polymers. Shape memory polymers (SMPs) are a class of smart materials with high potential for application to automotive, aerostructures, and medical devices, which can benefit from its intrinsic shape changing properties. In particular, looking at its application to aerospace substructure such as morphing wings, thermomechanical behavior of the SMPs needs to be well established and predicted. In order to predict the thermomechanical behavior of SMPs structures, a one-dimensional rheological thermomechanical constitutive model was adopted and a numerical simulation of this model was developed using a commercial finite element analysis package ABAQUS. The particular one-dimensional model was selected due to its potential to represent the key material behaviors of SMP with a relatively low number of required material constants, which is practical for engineering industrial applications. The model was expanded to a three-dimensional isotropic model and then incorporated into the finite element method by means of an ABAQUS user-defined subroutine (UMAT). The methods of three-dimensional expansion and numerical implementation are presented in this work. A time evolution of the analysis was conducted by making use of the backward difference method, which was applied to all quantities within the model including the material properties. A comparison of the numerical simulation results was carried out with the available experimental data. Numerical simulation results clearly exhibit the thermomechanical properties of the material, which include shape fixity, shape recovery, and recovery stress. Finally, a preliminary set of predictions for an unmanned aerial vehicle (UAV) morphing wing skin are also presented.

scholarly journals Harnessing reversible dry adhesion using shape memory polymer microparticles

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19616-19622
Author(s):  
Wenbing Li ◽  
Junhao Liu ◽  
Wanting Wei ◽  
Kun Qian
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Memory Effects ◽  
Reversible Adhesion ◽  
Dry Adhesion ◽  
Bonding Property ◽  
Shape Memory Effects ◽  
Polymer Microparticles

Shape memory polymers can provide excellent bonding property because of their shape memory effects. This paper proposes an adhesive unit that is capable of repeatable smart adhesion and exhibits reversible adhesion under heating.

scholarly journals Structural multi-colour invisible inks with submicron 4D printing of shape memory polymers

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wang Zhang ◽  
Hao Wang ◽  
Hongtao Wang ◽  
John You En Chan ◽  
Hailong Liu ◽  
...  
Keyword(s):  
Shape Memory ◽  
Information Hiding ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Photonic Devices ◽  
Temperature Sensitive ◽  
4D Printing ◽  
Two Photon ◽  
Shape Memory Effects ◽  
Nanoscale Structure

AbstractFour-dimensional (4D) printing of shape memory polymer (SMP) imparts time responsive properties to 3D structures. Here, we explore 4D printing of a SMP in the submicron length scale, extending its applications to nanophononics. We report a new SMP photoresist based on Vero Clear achieving print features at a resolution of ~300 nm half pitch using two-photon polymerization lithography (TPL). Prints consisting of grids with size-tunable multi-colours enabled the study of shape memory effects to achieve large visual shifts through nanoscale structure deformation. As the nanostructures are flattened, the colours and printed information become invisible. Remarkably, the shape memory effect recovers the original surface morphology of the nanostructures along with its structural colour within seconds of heating above its glass transition temperature. The high-resolution printing and excellent reversibility in both microtopography and optical properties promises a platform for temperature-sensitive labels, information hiding for anti-counterfeiting, and tunable photonic devices.

Three-dimensional constitutive model for shape-memory polymers considering temperature-rate dependent behavior

2021 ◽  
Vol 30 (3) ◽  
pp. 035030
Author(s):  
Jinsu Kim ◽  
Seung-Yeol Jeon ◽  
Seokbin Hong ◽  
Yongsan An ◽  
Haedong Park ◽  
...  
Keyword(s):  
Constitutive Model ◽  
Shape Memory ◽  
Three Dimensional ◽  
Shape Memory Polymers ◽  
Rate Dependent ◽  
Dependent Behavior ◽  
Temperature Rate

scholarly journals An analytical model for crack monitoring of the shape memory alloy intelligent concrete

2019 ◽  
Vol 31 (1) ◽  
pp. 100-116 ◽  
Author(s):  
Bingfei Liu ◽  
Qingfei Wang ◽  
Kai Yin ◽  
Liwen Wang
Keyword(s):  
Shape Memory Alloy ◽  
Constitutive Model ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Three Dimensional ◽  
Three Dimensional Model ◽  
One Dimensional ◽  
Monitoring Model ◽  
Crack Monitoring ◽  
The One

A theoretical model for the crack monitoring of the shape memory alloy intelligent concrete is presented in this work. The mechanical properties of shape memory alloy materials are first given by the experimental test. The one-dimensional constitutive model of the shape memory alloys is reviewed by degenerating from a three-dimensional model, and the behaviors of the shape memory alloys under different working conditions are then discussed. By combining the electrical resistivity model and the one-dimensional shape memory alloy constitutive model, the crack monitoring model of the shape memory alloy intelligent concrete is given, and the relationships between the crack width of the concrete and the electrical resistance variation of the shape memory alloy materials for different crack monitoring processes of shape memory alloy intelligent concrete are finally presented. The numerical results of the present model are compared with the published experimental data to verify the correctness of the model.

A comprehensive review on thermomechanical constitutive models for shape memory polymers

2020 ◽  
Vol 31 (10) ◽  
pp. 1243-1283 ◽  
Author(s):  
Ebrahim Yarali ◽  
Ali Taheri ◽  
Mostafa Baghani
Keyword(s):  
Shape Memory ◽  
Smart Materials ◽  
Constitutive Equations ◽  
Constitutive Relations ◽  
Shape Memory Polymer ◽  
Constitutive Models ◽  
Shape Memory Polymers ◽  
Typical Application ◽  
Comprehensive Review ◽  
Thermally Responsive

Shape memory polymers are a class of smart materials, which are capable of fixing their deformed shapes, and can return to their original shape in reaction to external stimulus such as heat. Also due to their exceptional properties, they are mostly used in four-dimensional printing applications. To model and investigate thermomechanical response of shape memory polymers mathematically, several constitutive equations have been developed over the past two decades. The purpose of this research is to provide an up-to-date review on structures, classifications, applications of shape memory polymers, and constitutive equations of thermally responsive shape memory polymers and their composites. First, a comprehensive review on the properties, structure, and classifications of shape memory polymers is conducted. Then, the proposed models in the literature are presented and discussed, which, particularly, are focused on the phase transition and thermo-viscoelastic approaches for conventional, two-way as well as multi-shape memory polymers. Then, a statistical analysis on constitutive relations of thermally activated shape memory polymers is carried out. Finally, we present a summary and give some concluding remarks, which could be helpful in selection of a suitable shape memory polymer constitutive model under a typical application.

A large deformation framework for shape memory polymers: Constitutive modeling and finite element implementation

2012 ◽  
Vol 24 (1) ◽  
pp. 21-32 ◽  
Author(s):  
Mostafa Baghani ◽  
Reza Naghdabadi ◽  
Jamal Arghavani
Keyword(s):  
Finite Element ◽  
Constitutive Model ◽  
Shape Memory ◽  
Finite Deformation ◽  
Deformation Gradient ◽  
Strain Tensor ◽  
Three Dimensional ◽  
Shape Memory Polymers ◽  
Small Strain ◽  
Internal Variables

Shape memory polymers commonly experience both finite deformations and arbitrary thermomechanical loading conditions in engineering applications. This motivates the development of three-dimensional constitutive models within the finite deformation regime. In the present study, based on the principles of continuum thermodynamics with internal variables, a three-dimensional finite deformation phenomenological constitutive model is proposed taking its basis from the recent model in the small strain regime proposed by Baghani et al. (2012). In the constitutive model derivation, a multiplicative decomposition of the deformation gradient into elastic and inelastic stored parts (in each phase) is adopted. Moreover, employing the mixture rule, the Green–Lagrange strain tensor is related to the rubbery and glassy parts. In the constitutive model, the evolution laws for internal variables are derived during both cooling and heating thermomechanical loadings. Furthermore, we present the time-discrete form of the proposed constitutive model in the implicit form. Using the finite element method, we solve several boundary value problems, that is, tension and compression of bars and a three-dimensional beam made of shape memory polymers, and investigate the model capabilities as well as its numerical counterpart. The model is validated by comparing the predicted results with experimental data reported in the literature that shows a good agreement.

Sign in / Sign up

Export Citation Format

Share Document