Systematic Fluid Selection for Organic Rankine Cycles and Performance Analysis for a Combined High and Low Temperature Cycle

Author(s):  
Maximilian Roedder ◽  
Matthias Neef ◽  
Christoph Laux ◽  
Klaus-P. Priebe

The organic Rankine cycle (ORC) is an established thermodynamic process that converts waste heat to electric energy. Due to the wide range of organic working fluids available the fluid selection adds an additional degree-of-freedom to the early design phase of an ORC process. Despite thermodynamic aspects such as the temperature level of the heat source, other technical, economic, and safety aspects have to be considered. For the fluid selection process in this paper, 22 criteria were identified in six main categories while distinguishing between elimination (EC) and tolerance criteria (TC). For an ORC design, the suggested method follows a practical engineering approach and can be used as a structured way to limit the number of interesting working fluids before starting a detailed performance analysis of the most promising candidates. For the first time, the selection process is applied to a two-stage reference cycle, which uses the waste heat of a large reciprocating engine for cogeneration power plants. It consists of a high temperature (HT) and a low temperature (LT) cycle in which the condensation heat of the HT cycle provides the heat input of the LT cycle. After the fluid selection process, the detailed thermodynamic cycle design is carried out with a thermodynamic design tool that also includes a database for organic working fluids. The investigated ORC cycle shows a net thermal efficiency of about 17.4% in the HT cycle with toluene as the working fluid and 6.2% in LT cycle with isobutane as the working fluid. The electric efficiency of the cogeneration plant increases from 40.4% to 46.97% with the both stages of the two-stage ORC in operation.

Author(s):  
Maximilian Rödder ◽  
Matthias Neef ◽  
Christoph Laux ◽  
Klaus-P. Priebe

The organic Rankine cycle (ORC) is an established thermodynamic process that converts waste heat to electric energy. Due to the wide range of organic working fluids available the fluid selection adds an additional degree of freedom to the early design phase of an ORC process. Despite thermodynamic aspects such as the temperature level of the heat source, other technical, economic and safety aspects have to be considered. For the fluid selection process in this paper, 22 criteria were identified in six main categories while distinguishing between elimination and tolerance criteria. For an ORC design, the suggested method follows a practical engineering approach and can be used as a structured way to limit the number of interesting working fluids before starting a detailed performance analysis of the most promising candidates. For the first time the selection process is applied to a two-stage reference cycle which uses the waste heat of a large reciprocating engine for cogeneration power plants. It consists of a high temperature and a low temperature cycle in which the condensation heat of the high temperature (HT) cycle provides the heat input of the low temperature (LT) cycle. After the fluid selection process the detailed thermodynamic cycle design is carried out with a thermodynamic design tool that also includes a database for organic working fluids. The investigated ORC cycle shows a net thermal efficiency of about 17,4% in the high temperature cycle with Toluene as the working fluid and 6,2% in low temperature cycle with iso-Butane as the working fluid. The electric efficiency of the cogeneration plant increases from 40,4% to 46,97% with the both stages of the two-stage ORC in operation.


Author(s):  
Sergio Peralta ◽  
Cesar Celis

Abstract This work describes a working fluid selection process for an ORC based power plant that uses as heat source waste heat from a petroleum distillation furnace. Sixteen (16) organic fluids previously considered for similar applications are analyzed based on environmental, safety and physical properties. Two different power plants layouts, a basic one and another featuring an internal heat exchanger (IHE), are analyzed. The combinations between working fluids and plant layouts seek to maximize the ORC-based power plant thermal efficiency. ORC exergy destruction and exergy efficiency are also accounted for. In this work, the close interrelation between working fluids thermo-physical properties and expander dimensionless characteristics is also assessed. The main results indicate that R245ca and R245fa are the working fluid leading to both the highest thermal (∼16%) and exergy efficiencies (∼23%), and the lowest exergy destructions (∼703 kW). Based on required properties of the selected working fluid, an axial turbine design seems to be the most appropriate ORC expander technology for the particular application discussed in this paper. The outcomes from this work will be used as the basis for the detailed design of the components of an ORC-based power plant focused on increasing the overall efficiency of petroleum distillation processes.


Author(s):  
Ahmad K. Sleiti ◽  
Mohammed Al-Khawaja

Abstract Refrigeration systems contribute to the critical environmental concerns including global warming and ozone depletion. It is necessary to develop new systems that use renewable energy resources and waste heat to perform the cooling function with eco-friendly working fluids. This improves the energy efficiency of the power systems and minimizes the harmful effects of conventional refrigeration systems. This paper introduces an analysis of a regenerative thermo-mechanical refrigeration system that is powered with renewable heat sources (solar, geothermal) or waste heat (from internal combustion engines, gas power plants, and steam power plants). The system operates at the supercritical conditions of the working fluids. The performance of the system is evaluated based on power efficiency, the COP, and the expander-compressor diameters. Also, a number of working fluids were compared with each other based on their performance and environmental effects. There is a trade-off between high-performance fluids and their environmental effects. Using R32 as a working fluid at Th = 150 °C and Tc1 = 40 °C, the system produces a cooling capacity of 1 kW with power efficiency of 10.23%, expander diameter of 53.12 mm and compressor diameter of 75.4mm. The regenerator increases the power efficiency by about 1%. However, the size of the regenerator is small (Dr = 6.5 mm, Lr = 142 mm].


Energies ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 480 ◽  
Author(s):  
Gábor Györke ◽  
Axel Groniewsky ◽  
Attila Imre

One of the most crucial challenges of sustainable development is the use of low-temperature heat sources (60–200 °C), such as thermal solar, geothermal, biomass, or waste heat, for electricity production. Since conventional water-based thermodynamic cycles are not suitable in this temperature range or at least operate with very low efficiency, other working fluids need to be applied. Organic Rankine Cycle (ORC) uses organic working fluids, which results in higher thermal efficiency for low-temperature heat sources. Traditionally, new working fluids are found using a trial-and-error procedure through experience among chemically similar materials. This approach, however, carries a high risk of excluding the ideal working fluid. Therefore, a new method and a simple rule of thumb—based on a correlation related to molar isochoric specific heat capacity of saturated vapor states—were developed. With the application of this thumb rule, novel isentropic and dry working fluids can be found applicable for given low-temperature heat sources. Additionally, the importance of molar quantities—usually ignored by energy engineers—was demonstrated.


2014 ◽  
Vol 35 (3) ◽  
pp. 145-154
Author(s):  
Piotr Cyklis ◽  
Ryszard Kantor ◽  
Tomasz Ryncarz ◽  
Bogusław Górski ◽  
Roman Duda

Abstract The requirements for environmentally friendly refrigerants promote application of CO2 and water as working fluids. However there are two problems related to that, namely high temperature limit for CO2 in condenser due to the low critical temperature, and low temperature limit for water being the result of high triple point temperature. This can be avoided by application of the hybrid adsorption-compression system, where water is the working fluid in the adsorption high temperature cycle used to cool down the CO2 compression cycle condenser. The adsorption process is powered with a low temperature renewable heat source as solar collectors or other waste heat source. The refrigeration system integrating adsorption and compression system has been designed and constructed in the Laboratory of Thermodynamics and Thermal Machine Measurements of Cracow University of Technology. The heat source for adsorption system consists of 16 tube tulbular collectors. The CO2 compression low temperature cycle is based on two parallel compressors with frequency inverter. Energy efficiency and TEWI of this hybrid system is quite promising in comparison with the compression only systems.


Author(s):  
Bo Liu ◽  
Franck David ◽  
Philippe Riviere ◽  
Christophe Coquelet ◽  
Renaud Gicquel

A two stage Rankine cycle for power generation is presented in this paper. It is made of a water steam Rankine cycle and an Organic Rankine bottoming Cycle. By using an organic working fluid with higher density than water, it is possible to reduce the installation size and to use an air-cooled condenser. Following our previous studies, 3 high critical temperature organic fluids, R245fa, R365mfc, isopentane (iC5) and ammonia are tested as potential candidates for this application. The performances of the two stage Rankine cycle operating with those different working fluids are evaluated for a nuclear plant case. The size of system components (heat exchangers and turbine) is estimated for each tested fluid. The influences of their thermodynamic and transport properties are analyzed. In addition, an estimation of the installation cost is done by introducing cost functions.


2021 ◽  
Vol 19 (2) ◽  
pp. 100-106
Author(s):  
A. V. Dmitrenko ◽  
M. I. Kolpakov

Studying the issues of recovery of low-potential energy at smallscale energy facilities allowed to show the promising character of the organic Rankine cycle (ORC) technology as a technology for recovery or conversion of low-potential energy.The most promising developments in the field of the use and recovery of waste heat are described regarding application of ORC, which is widely used in geothermal sources, hot water boilers, gas turbine plants. Due to the constantly growing diversity of working fluids, ORC can be used within a wide temperature range from 100°C to over 350°C. Also, developments are underway in the design of ORC generators to increase reliability of its individual system units, such as turbines and expanders. Based on the above factors, it can be concluded that with a deeper study of the problems of adopting ORC technologies, they can become a very promising direction in development of heat power engineering.It has been determined that the main factor hindering the widespread adoption of the ORC technology is associated with high cost of heat exchange equipment due to increased heat exchange surfaces. It is shown that design of mini power plants and energy centres based on the use of low-potential energy requires improvement of mathematical modelling methods to reliably determine operating modes and characteristics of each of the units. Methods for modelling evaporation and condensation systems, including turbines and expanders using organic low-boiling working fluids, should be considered among the methods that are highly sought after. The methods for selecting a working fluid for ORC devices also have a significant impact on characteristics of the installation determining the range of cycle operating temperatures and pressures. The solution of the above problems can lead to a reduction in the cost of heat exchange equipment, and, consequently, to a decrease in costs for design of ORC generators. 


Proceedings ◽  
2020 ◽  
Vol 65 (1) ◽  
pp. 25
Author(s):  
Antonio Garrido Marijuan ◽  
Roberto Garay ◽  
Mikel Lumbreras ◽  
Víctor Sánchez ◽  
Olga Macias ◽  
...  

District heating networks deliver around 13% of the heating energy in the EU, being considered as a key element of the progressive decarbonization of Europe. The H2020 REnewable Low TEmperature District project (RELaTED) seeks to contribute to the energy decarbonization of these infrastructures through the development and demonstration of the following concepts: reduction in network temperature down to 50 °C, integration of renewable energies and waste heat sources with a novel substation concept, and improvement on building-integrated solar thermal systems. The coupling of renewable thermal sources with ultra-low temperature district heating (DH) allows for a bidirectional energy flow, using the DH as both thermal storage in periods of production surplus and a back-up heating source during consumption peaks. The ultra-low temperature enables the integration of a wide range of energy sources such as waste heat from industry. Furthermore, RELaTED also develops concepts concerning district heating-connected reversible heat pump systems that allow to reach adequate thermal levels for domestic hot water as well as the use of the network for district cooling with high performance. These developments will be demonstrated in four locations: Estonia, Serbia, Denmark, and Spain.


2003 ◽  
Vol 125 (2) ◽  
pp. 223-229 ◽  
Author(s):  
Gunnar Tamm ◽  
D. Yogi Goswami

A combined thermal power and cooling cycle proposed by Goswami is under intensive investigation, both theoretically and experimentally. The proposed cycle combines the Rankine and absorption refrigeration cycles, producing refrigeration while power is the primary goal. A binary ammonia-water mixture is used as the working fluid. This cycle can be used as a bottoming cycle using waste heat from a conventional power cycle or as an independent cycle using low temperature sources such as geothermal and solar energy. An experimental system was constructed to demonstrate the feasibility of the cycle and to compare the experimental results with the theoretical simulation. Results showed that the vapor generation and absorption condensation processes work experimentally, exhibiting expected trends, but with deviations from ideal and equilibrium modeling. The potential for combined turbine work and refrigeration output was evidenced in operating the system. Analysis of losses showed where improvements could be made, in preparation for further testing over a broader range of operating conditions.


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