Systematic Fluid Selection for Organic Rankine Cycles (ORC) and Performance Analysis for a Combined High and Low Temperature Cycle

Author(s):  
Maximilian Rödder ◽  
Matthias Neef ◽  
Christoph Laux ◽  
Klaus-P. Priebe

The organic Rankine cycle (ORC) is an established thermodynamic process that converts waste heat to electric energy. Due to the wide range of organic working fluids available the fluid selection adds an additional degree of freedom to the early design phase of an ORC process. Despite thermodynamic aspects such as the temperature level of the heat source, other technical, economic and safety aspects have to be considered. For the fluid selection process in this paper, 22 criteria were identified in six main categories while distinguishing between elimination and tolerance criteria. For an ORC design, the suggested method follows a practical engineering approach and can be used as a structured way to limit the number of interesting working fluids before starting a detailed performance analysis of the most promising candidates. For the first time the selection process is applied to a two-stage reference cycle which uses the waste heat of a large reciprocating engine for cogeneration power plants. It consists of a high temperature and a low temperature cycle in which the condensation heat of the high temperature (HT) cycle provides the heat input of the low temperature (LT) cycle. After the fluid selection process the detailed thermodynamic cycle design is carried out with a thermodynamic design tool that also includes a database for organic working fluids. The investigated ORC cycle shows a net thermal efficiency of about 17,4% in the high temperature cycle with Toluene as the working fluid and 6,2% in low temperature cycle with iso-Butane as the working fluid. The electric efficiency of the cogeneration plant increases from 40,4% to 46,97% with the both stages of the two-stage ORC in operation.

Author(s):  
Maximilian Roedder ◽  
Matthias Neef ◽  
Christoph Laux ◽  
Klaus-P. Priebe

The organic Rankine cycle (ORC) is an established thermodynamic process that converts waste heat to electric energy. Due to the wide range of organic working fluids available the fluid selection adds an additional degree-of-freedom to the early design phase of an ORC process. Despite thermodynamic aspects such as the temperature level of the heat source, other technical, economic, and safety aspects have to be considered. For the fluid selection process in this paper, 22 criteria were identified in six main categories while distinguishing between elimination (EC) and tolerance criteria (TC). For an ORC design, the suggested method follows a practical engineering approach and can be used as a structured way to limit the number of interesting working fluids before starting a detailed performance analysis of the most promising candidates. For the first time, the selection process is applied to a two-stage reference cycle, which uses the waste heat of a large reciprocating engine for cogeneration power plants. It consists of a high temperature (HT) and a low temperature (LT) cycle in which the condensation heat of the HT cycle provides the heat input of the LT cycle. After the fluid selection process, the detailed thermodynamic cycle design is carried out with a thermodynamic design tool that also includes a database for organic working fluids. The investigated ORC cycle shows a net thermal efficiency of about 17.4% in the HT cycle with toluene as the working fluid and 6.2% in LT cycle with isobutane as the working fluid. The electric efficiency of the cogeneration plant increases from 40.4% to 46.97% with the both stages of the two-stage ORC in operation.


2014 ◽  
Vol 35 (3) ◽  
pp. 145-154
Author(s):  
Piotr Cyklis ◽  
Ryszard Kantor ◽  
Tomasz Ryncarz ◽  
Bogusław Górski ◽  
Roman Duda

Abstract The requirements for environmentally friendly refrigerants promote application of CO2 and water as working fluids. However there are two problems related to that, namely high temperature limit for CO2 in condenser due to the low critical temperature, and low temperature limit for water being the result of high triple point temperature. This can be avoided by application of the hybrid adsorption-compression system, where water is the working fluid in the adsorption high temperature cycle used to cool down the CO2 compression cycle condenser. The adsorption process is powered with a low temperature renewable heat source as solar collectors or other waste heat source. The refrigeration system integrating adsorption and compression system has been designed and constructed in the Laboratory of Thermodynamics and Thermal Machine Measurements of Cracow University of Technology. The heat source for adsorption system consists of 16 tube tulbular collectors. The CO2 compression low temperature cycle is based on two parallel compressors with frequency inverter. Energy efficiency and TEWI of this hybrid system is quite promising in comparison with the compression only systems.


Energies ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 480 ◽  
Author(s):  
Gábor Györke ◽  
Axel Groniewsky ◽  
Attila Imre

One of the most crucial challenges of sustainable development is the use of low-temperature heat sources (60–200 °C), such as thermal solar, geothermal, biomass, or waste heat, for electricity production. Since conventional water-based thermodynamic cycles are not suitable in this temperature range or at least operate with very low efficiency, other working fluids need to be applied. Organic Rankine Cycle (ORC) uses organic working fluids, which results in higher thermal efficiency for low-temperature heat sources. Traditionally, new working fluids are found using a trial-and-error procedure through experience among chemically similar materials. This approach, however, carries a high risk of excluding the ideal working fluid. Therefore, a new method and a simple rule of thumb—based on a correlation related to molar isochoric specific heat capacity of saturated vapor states—were developed. With the application of this thumb rule, novel isentropic and dry working fluids can be found applicable for given low-temperature heat sources. Additionally, the importance of molar quantities—usually ignored by energy engineers—was demonstrated.


2010 ◽  
Vol 42 ◽  
pp. 322-325
Author(s):  
Xiu Fang Liu ◽  
Fa Hui Wang ◽  
Fan Mao Meng

A two-stage cascade pre-cooling test bed was designed and set up to develop a -30°C /-60°C pre-cooling equipment. An internal heater exchanger and a condenser were set in low-temperature cycle. Theoretically the two stages can work stably at setting temperature and the low-temperature cycle can operate independently with aided starting of the high-temperature cycle. The experimental results indicate that the test bed can provide cooling capacity steadily at -46°C and -100°C respectively and the low-temperature cycle cannot operate alone for compressor overload protection. Based on the analysis, the possible reasons and detailed suggestions were put forward.


Author(s):  
Sergio Peralta ◽  
Cesar Celis

Abstract This work describes a working fluid selection process for an ORC based power plant that uses as heat source waste heat from a petroleum distillation furnace. Sixteen (16) organic fluids previously considered for similar applications are analyzed based on environmental, safety and physical properties. Two different power plants layouts, a basic one and another featuring an internal heat exchanger (IHE), are analyzed. The combinations between working fluids and plant layouts seek to maximize the ORC-based power plant thermal efficiency. ORC exergy destruction and exergy efficiency are also accounted for. In this work, the close interrelation between working fluids thermo-physical properties and expander dimensionless characteristics is also assessed. The main results indicate that R245ca and R245fa are the working fluid leading to both the highest thermal (∼16%) and exergy efficiencies (∼23%), and the lowest exergy destructions (∼703 kW). Based on required properties of the selected working fluid, an axial turbine design seems to be the most appropriate ORC expander technology for the particular application discussed in this paper. The outcomes from this work will be used as the basis for the detailed design of the components of an ORC-based power plant focused on increasing the overall efficiency of petroleum distillation processes.


Energies ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 4014 ◽  
Author(s):  
Abubakr Ayub ◽  
Costante M. Invernizzi ◽  
Gioele Di Marcoberardino ◽  
Paolo Iora ◽  
Giampaolo Manzolini

This study aims to provide a thermodynamic comparison between supercritical CO2 cycles and ORC cycles utilizing flue gases as waste heat source. Moreover, the possibility of using CO2 mixtures as working fluids in transcritical cycles to enhance the performance of the thermodynamic cycle is explored. ORCs operating with pure working fluids show higher cyclic thermal and total efficiencies compared to supercritical CO2 cycles; thus, they represent a better option for high-temperature waste heat recovery provided that the thermal stability at a higher temperature has been assessed. Based on the improved global thermodynamic performance and good thermal stability of R134a, CO2-R134a is investigated as an illustrative, promising working fluid mixture for transcritical power cycles. The results show that a total efficiency of 0.1476 is obtained for the CO2-R134a mixture (0.3 mole fraction of R134a) at a maximum cycle pressure of 200 bars, which is 15.86% higher than the supercritical carbon dioxide cycle efficiency of 0.1274, obtained at the comparatively high maximum pressure of 300 bars. Steam cycles, owing to their larger number of required turbine stages and lower power output, did not prove to be a suitable option in this application.


Proceedings ◽  
2020 ◽  
Vol 65 (1) ◽  
pp. 25
Author(s):  
Antonio Garrido Marijuan ◽  
Roberto Garay ◽  
Mikel Lumbreras ◽  
Víctor Sánchez ◽  
Olga Macias ◽  
...  

District heating networks deliver around 13% of the heating energy in the EU, being considered as a key element of the progressive decarbonization of Europe. The H2020 REnewable Low TEmperature District project (RELaTED) seeks to contribute to the energy decarbonization of these infrastructures through the development and demonstration of the following concepts: reduction in network temperature down to 50 °C, integration of renewable energies and waste heat sources with a novel substation concept, and improvement on building-integrated solar thermal systems. The coupling of renewable thermal sources with ultra-low temperature district heating (DH) allows for a bidirectional energy flow, using the DH as both thermal storage in periods of production surplus and a back-up heating source during consumption peaks. The ultra-low temperature enables the integration of a wide range of energy sources such as waste heat from industry. Furthermore, RELaTED also develops concepts concerning district heating-connected reversible heat pump systems that allow to reach adequate thermal levels for domestic hot water as well as the use of the network for district cooling with high performance. These developments will be demonstrated in four locations: Estonia, Serbia, Denmark, and Spain.


Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 209
Author(s):  
Xuanming Ji ◽  
Panpan Ge ◽  
Song Xiang ◽  
Yuanbiao Tan

In this work, the effect of double-ageing heat treatments on the microstructural evolution and mechanical behaviour of a metastable β-titanium Ti-3.5Al-5Mo-4V alloy is investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The double-ageing treatments are composed of low-temperature pre-ageing and high-temperature ageing, where the low-temperature pre-ageing is conducted at 300 °C or 350 °C for different times, and the high-temperature ageing is conducted at 500 °C for 8 h. The results show that the phase transformation sequence is altered with the time spent during the first ageing stage, the isothermal ω phase is precipitated in the pre-ageing process of the alloy at 300 °C and 350 °C with the change in the ageing time, and the ω phase is finally transformed into the α phase with the extension of pre-ageing time. The existence time of the ω phase is shortened as the pre-ageing temperature increases. The microhardness of the alloy increases with increasing pre-ageing time and temperature. Compared with single-stage ageing, the ω phase formed in the pre-ageing stage changes the response to subsequent high-temperature ageing. After the two-stage ageing treatment, the precipitation size of the α phase is obviously refined after the double-ageing treatment. A microhardness test shows that the microhardness of the two-stage aged alloy increases with extended pre-ageing time.


2003 ◽  
Vol 125 (2) ◽  
pp. 223-229 ◽  
Author(s):  
Gunnar Tamm ◽  
D. Yogi Goswami

A combined thermal power and cooling cycle proposed by Goswami is under intensive investigation, both theoretically and experimentally. The proposed cycle combines the Rankine and absorption refrigeration cycles, producing refrigeration while power is the primary goal. A binary ammonia-water mixture is used as the working fluid. This cycle can be used as a bottoming cycle using waste heat from a conventional power cycle or as an independent cycle using low temperature sources such as geothermal and solar energy. An experimental system was constructed to demonstrate the feasibility of the cycle and to compare the experimental results with the theoretical simulation. Results showed that the vapor generation and absorption condensation processes work experimentally, exhibiting expected trends, but with deviations from ideal and equilibrium modeling. The potential for combined turbine work and refrigeration output was evidenced in operating the system. Analysis of losses showed where improvements could be made, in preparation for further testing over a broader range of operating conditions.


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