scholarly journals Applying Kalina Technology to a Bottoming Cycle for Utility Combined Cycles

Author(s):  
A. L. Kalina ◽  
H. M. Leibowitz

A new power generation technology often referred to as the Kalina cycle, is being developed as a direct replacement for the Rankine steam cycle. It may be applied to any thermal heat source, low or high temperature. Among several Kalina cycle variations there is one that is particularly well suited as a bottoming cycle for utility combined cycle applications. It is the subject of this paper. Using an ammonia/water mixture as the working fluid and a condensing system based on absorption refrigeration principles the Kalina bottoming cycle outperforms a triple pressure steam cycle by 16 percent. Additionally, this version of the Kalina cycle is characterized by an intercooling feature between turbine stages, diametrically opposite to normal reheating practice in steam plants. Energy and mass balances are presented for a 200 MWe Kalina bottoming cycle. Kalina cycle performance is compared to a triple pressure steam plant. At a peak cycle temperature of 950° F the Kalina plant produces 223.5 MW vs. 192.6 MW for the triple pressure steam plant, an improvement of 16.0 percent. Reducing the economizer pinch point to 15° F results in a performance improvement in excess of 30 percent.

Author(s):  
Kari Anne Tveitaskog ◽  
Fredrik Haglind

This paper is aimed at designing and optimizing combined cycles for marine applications. For this purpose, an in-house numerical simulation tool called DNA (Dynamic Network Analysis) and a genetic algorithm-based optimization routine are used. The top cycle is modeled as the aero-derivative gas turbine LM2500, while four options for bottoming cycles are modeled. Firstly, a single pressure steam cycle, secondly a dual-pressure steam cycle, thirdly an ORC using toluene as the working fluid and an intermediate oil loop as the heat carrier, and lastly an ABC with inter-cooling are modeled. Furthermore, practical and operational aspects of using these three machinery systems for a high-speed ferry are discussed. Two scenarios are evaluated. The first scenario evaluates the combined cycles with a given power requirement, optimizing the combined cycle while operating the gas turbine at part load. The second scenario evaluates the combined cycle with the gas turbine operated at full load. For the first scenario, the results suggest that the thermal efficiencies of the combined gas and steam cycles are 46.3% and 48.2% for the single pressure and dual pressure steam cycles, respectively. The gas ORC and gas ABC combined cycles obtained thermal efficiencies of 45.6% and 41.9%, respectively. For the second scenario, the results suggest that the thermal efficiencies of the combined gas and steam cycles are 53.5% and 55.3% for the single pressure and dual pressure steam cycles, respectively. The gas ORC and gas ABC combined cycles obtained thermal efficiencies of 51.0% and 47.8%, respectively.


Author(s):  
A. I. Kalina ◽  
H. M. Leibowitz ◽  
D. W. Markus ◽  
R. I. Pelletier

An 86 MW bottoming cycle has been designed based on the Kalina cycle principles previously reported by the authors. It is designated as Kalina Cycle System 6 (KCS6). It uses an ABB Type 13E gas turbine topping cycle to produce a 227 MW combined cycle having a heat rate (LHV) of 6460 Btu/kWh (52.8%). The working fluid is a 75% aqua ammonia mixture. Equipment and installation costs were developed for KCS6 and a baseline two-pressure steam bottoming cycle. The KCS6 turbine was designed with input from ABB. Compared to the two-pressure steam bottoming cycle, KCS6 provides an additional 12.1 MW (16.4%). The estimated cost of the bottoming cycle is $1,058/kW vs. $1,033/kW for the steam plant. The KCS6 heat acquisition equipment (boiler and recooler) and distillation/condensation subsystem represent the two major additions to cost over the steam plant. On the other hand, the turbine is less expensive, mostly due to the elimination of the large condensing stages. An economic analysis of the KCS6 plant is presented using the value of the additional output as the decision-making economic variable. The analysis is based on a model which considers capital cost, heat rate and near-term world-wide fuel prices. At $4.25/106 Btu fuel, the KCS6 costs approximately $7 million less than the value of its output.


2011 ◽  
Vol 15 (1) ◽  
pp. 29-41 ◽  
Author(s):  
Abdolreza Fazeli ◽  
Hossein Rezvantalab ◽  
Farshad Kowsary

In this study, a new combined power and refrigeration cycle is proposed, which combines the Rankine and absorption refrigeration cycles. Using a binary ammonia-water mixture as the working fluid, this combined cycle produces both power and refrigeration output simultaneously by employing only one external heat source. In order to achieve the highest possible exergy efficiency, a secondary turbine is inserted to expand the hot weak solution leaving the boiler. Moreover, an artificial neural network (ANN) is used to simulate the thermodynamic properties and the relationship between the input thermodynamic variables on the cycle performance. It is shown that turbine inlet pressure, as well as heat source and refrigeration temperatures have significant effects on the net power output, refrigeration output and exergy efficiency of the combined cycle. In addition, the results of ANN are in excellent agreement with the mathematical simulation and cover a wider range for evaluation of cycle performance.


Author(s):  
Ricardo Vasquez Padilla ◽  
Antonio Ramos Archibold ◽  
Gokmen Demirkaya ◽  
Saeb Besarati ◽  
D. Yogi Goswami ◽  
...  

Improving the efficiency of thermodynamic cycles plays a fundamental role in reducing the cost of solar power plants. These plants work normally with Rankine cycles which present some disadvantages due to the thermodynamic behavior of steam at low pressures. These disadvantages can be reduced by introducing alternatives such as combined cycles which combine the best features of each cycle. In this paper a combined Rankine-Goswami cycle (RGC) is proposed and a thermodynamic analysis is conducted. The Goswami cycle, used as a bottoming cycle, uses ammonia-water mixture as the working fluid and produces power and refrigeration while power is the primary goal. This bottoming cycle, reduces the energy losses in the traditional condenser and eliminates the high specific volume and poor vapor quality presented in the last stages of the lower pressure turbine in the Rankine cycle. In addition, the use of absorption condensation in the Goswami cycle, for regeneration of the strong solution, allows operating the low pressure side of the cycle above atmospheric pressure which eliminates the need for maintaining a vacuum pressure in the condenser. The performance of the proposed combined Rankine-Goswami cycle, under full load, was investigated for applications in parabolic trough solar thermal plants for a range from 40 to 50 MW sizes. A sensitivity analysis to study the effect of the ammonia concentration, condenser pressure and rectifier concentration on the cycle efficiency, network and cooling was performed. The results indicate that the proposed RGC provide a difference in net power output between 15.7 and 42.3% for condenser pressures between 1 to 9 bars. The maximum effective first law and exergy efficiencies for an ammonia mass fraction of 0.5 are calculated as 36.7% and 24.7% respectively for the base case (no superheater or rectifier process).


1995 ◽  
Vol 117 (1) ◽  
pp. 10-15 ◽  
Author(s):  
C. H. Marston ◽  
M. Hyre

The performance of a triple-pressure steam cycle has been compared with a single-stage Kalina cycle and an optimized three-stage Kalina cycle as the bottoming sections of a gas turbine combined cycle power plant. A Monte Carlo direct search was used to find the optimum separator temperature and ammonia mass fraction for the three-stage Kalina cycle for a specific plant configuration. Both Kalina cycles were more efficient than the triple pressure steam cycle. Optimization of the three-stage Kalina cycle resulted in almost a two percentage point improvement.


Author(s):  
Raveendra Nath R ◽  
C. Vijaya Bhaskar Reddy ◽  
K.Hemachandra Reddy

In this paper, a thermodynamic investigation is done on a Kalina-flash cycle. This work is initially validated with the Kalina cycle power plant, Wich is commissioned in Husavic. Low-temperature Kalina-flash is considered for this study. This cycle is working with the ammonia-water mixture. The Kalina-flash cycle was optimized in the view of exergy and thermal efficiency. A multi-objective genetic algorithm is used to accomplish optimization. The optimum values of the objective functions are observed to be 40.20 and 11.70% respectively. At last, The influence of the separator inlet dryness fraction, basic ammonia mass fraction, temperature and flash pressure ratio on the first and second law efficiencies are analysed.


Author(s):  
C M Invernizzi ◽  
P Iora ◽  
R Sandrini

This article investigates the possibility to enhance the performance of a biomass organic Rankine cycle (ORC) plant by adding an externally fired gas turbine (EFGT), yielding a combined EFGT + ORC system. A typical ORC configuration is first modelled and validated on data available from an existing unit 1.5 MW reference plant. Then, different working fluids belonging to the methyl-substituted benzene series and linear methylpolysiloxanes have been evaluated for the ORC section on the basis of both thermodynamics considerations and design issues of the regenerator and the turbine. Results of the simulations of the combined cycle (CC) referred to a furnace size of about unit 9 MW, assuming a maximum GT inlet temperature of 800 °C, show a maximum efficiency of 23 per cent, obtained in the case where toluene is adopted as a working fluid for the bottoming section. This value is about 4 points per cent higher than the efficiency of the corresponding simple ORC. Finally, to conclude, some preliminary considerations are given regarding the techno-economic feasibility of the combined configuration, suggesting the need of a further investigation on the possible technological solution for the furnace which represents the main uncertainty in the resulting costs of the CC.


2020 ◽  
Vol 12 (2) ◽  
pp. 484 ◽  
Author(s):  
Nima Javanshir ◽  
Seyed Mahmoudi S. M. ◽  
M. Akbari Kordlar ◽  
Marc A. Rosen

A cogeneration cycle for electric power and refrigeration, using an ammonia-water solution as a working fluid and the geothermal hot water as a heat source, is proposed and investigated. The system is a combination of a modified Kalina cycle (KC) which produces power and an absorption refrigeration cycle (ARC) that generates cooling. Geothermal water is supplied to both the KC boiler and the ARC generator. The system is analyzed from thermodynamic and economic viewpoints, utilizing Engineering Equation Solver (EES) software. In addition, a parametric study is carried out to evaluate the effects of decision parameters on the cycle performance. Furthermore, the system performance is optimized for either maximizing the exergy efficiency (EOD case) or minimizing the total product unit cost (COD case). In the EOD case the exergy efficiency and total product unit cost, respectively, are calculated as 34.7% and 15.8$/GJ. In the COD case the exergy efficiency and total product unit cost are calculated as 29.8% and 15.0$/GJ. In this case, the cooling unit cost, c p , c o o l i n g , and power unit cost, c p , p o w e r , are achieved as 3.9 and 11.1$/GJ. These values are 20.4% and 13.2% less than those obtained when the two products are produced separately by the ARC and KC, respectively. The thermoeconomic analysis identifies the more important components, such as the turbine and absorbers, for modification to improve the cost-effectiveness of the system.


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