Design Issues for the Methane-Steam Reformer of a Chemically Recuperated Gas Turbine Cycle

Author(s):  
Carlo Carcasci ◽  
Simon Harvey

Significant research effort is currently centered on developing advanced gas turbine systems for electric power generation applications. A number of innovative gas turbine cycles have been proposed lately, including the Humid Air Turbine (HAT), and the Chemically Recuperated Gas Turbine (CRGT). The potential of the CRGT cycle lies in the ability to generate power with a high efficiency while achieving ultra-low NO emissions without the need for selective catalytic reduction of the exhaust gases. However, much of the work that has been published on such cycles is restricted to a discussion of the thermodynamic potential of the cycle, and little work has focussed on discussion of some of the specific design issues associated with such a cycle. More specifically, design of the chemical recuperation heat recovery device involves a complex design trade-off in order to achieve a design with acceptable hot and cold-side pressure drops and acceptable overall dimensions. The design of such a heat recovery device is more complex than that of a traditional heat recovery steam generator (HRSG), since the methane steam reformer must not only allow sufficient heat transfer to occur, but also allow a sufficient cold side residence time, so that the methane steam reforming reactions can come close to equilibrium, ensuring maximal methane conversion. In this work, the authors present a code capable of performing the design of a methane steam reformer heat recovery device based on a heat exchanger geometry similar to that of a traditional HRSG. The purpose of the paper is to discuss the key parameters relevant to the design of a CRGT MSR reactor, and how these parameters interact with the rest of the cycle. Various design options are discussed, and the results of a parametric analysis are presented, leading to the identification of several suitable geometries.

Author(s):  
C Carcasci ◽  
B Facchini ◽  
S Harvey

A number of innovative gas turbine cycles have been proposed lately, including the humid air turbine (HAT) and the chemically recuperated gas turbine (CRGT). The potential of the CRGT cycle lies in the ability to generate power with a high efficiency and ultra-low NOx emissions. Much of the research work published on the CRGT cycle is restricted to an analysis of the thermodynamic potential of the cycle. However, little work has been devoted to discussion of some of the relevant design and operation issues of such cycles. In this paper, part-load performance characteristics are presented for a CRGT cycle based on an aeroderivative gas turbine engine adapted for chemical recuperation. The paper also includes discussion of some of the design issues for the methane-steam reformer component of the cycle. The results of this study show that large heat exchange surface areas and catalyst volumes are necessary to ensure sufficient methane conversion in the methane steam reformer section of the cycle. The paper also shows that a chemically recuperated aeroderivative gas turbine has similar part-load performance characteristics compared with the corresponding steam-injected gas turbine (STIG) cycle.


Author(s):  
Carlo Carcasci ◽  
Bruno Facchini ◽  
Simon Harvey

Significant research effort is currently centered on developing advanced gas turbine systems for electric power generation applications. A number of innovative gas turbine cycles have been proposed lately, including the Humid Air Turbine (HAT), and the Chemically Recuperated Gas Turbine (CRGT). The potential of the CRGT cycle lies in the ability to generate power with a high efficiency while achieving ultra-low NO emissions without the need for selective catalytic reduction of the exhaust gases. Much of the research work published on the CRGT cycle is restricted to an analysis of the thermodynamic potential of the cycle. However, a detailed performance analysis of such cycles requires the development of a suitable cycle simulation code, capable of simulating cycle operation at the design point and in part load conditions. In this paper, the authors present a modular code for complex gas turbine cycle simulations. The code includes a module for design and off-design simulation of the methane-steam reformer chemical heat recovery device of a CRGT cycle. The code is then used to perform a detailed design and off-design performance analysis of a CRGT cycle based on the LM2500-STIG cycle adapted for chemical recuperation.


Author(s):  
James S. Davis ◽  
G. C. Duponteil

Selective Catalytic Reduction (SCR) is a post-combustion method to reduce the oxides of nitrogen (NOx), present in flue gases such as gas turbine exhaust streams, to N2 and water. It involves the injection of ammonia and the use of a catalyst module to promote the reaction to obtain high efficiency (60–86+%) NOx reduction. Several operating parameters can influence catalyst performance to include temperature, gas flow distribution, presence of sulfur compounds and catalyst age. This paper examines the impact of a SCR integration in a gas turbine heat recovery steam generator (HRSG) design/operation. Limitations on HRSG load and following capabilities, effect on capital cost and overall performance and current SCR system experience represent a number of areas that are examined.


2002 ◽  
Vol 125 (1) ◽  
pp. 391-397 ◽  
Author(s):  
T. Nakagaki ◽  
T. Ogawa ◽  
H. Hirata ◽  
K. Kawamoto ◽  
Y. Ohashi ◽  
...  

Micro gas turbines (MGTs) are subject to certain problems, notably low thermal efficiency of the system and high emission including NOx. The chemically recuperated gas turbine (CRGT) system introduced in this paper is one of the most promising solutions to these problems. The CRGT system we propose uses an endothermic reaction of methane steam reforming for heat recovery. It is usually thought that the reaction of methane steam reforming does not occur sufficiently to recover heat at the temperature of turbine exhaust, but we confirmed sufficient reaction occurred at such low temperature and that applications of the chemical recuperation system to some commercial MGTs are effective for increasing the efficiency.


Author(s):  
K. Frankfort ◽  
J. Rich

This paper describes the market research efforts which established the performance parameters, the design criteria and the product specification for a new 10,000 shp regenerative cycle gas turbine system which incorporates a two-stage intercooled centrifugal compressor and features a thermal efficiency which exceeds 43 percent.


Author(s):  
Emmanuel Appiah ◽  
Kshitij Gawande

Abstract Construction of combined cycle gas turbine (CCGT) plants, which are combination of a simple cycle gas turbine (Brayton cycle) and a steam power cycle (Rankine cycle), have increased in recent years due to their high efficiency, low emissions, relative compact size, and minimal delivery time, among other advantages. One key component of CCGT is a heat recovery steam generator (HRSG). The HRSG is basically a heat exchanger composed of a series of preheaters (economizers), evaporator, reheaters, and superheaters. Combustion gas from gas turbine is used as an energy source for steam generation in the HRSG. Due to high mass flowrate of combustion turbine exhausts gas and injection of water to reduce NOx contents, high vibration and severe noise are created. The noise induces acoustic resonance in the HRSG duct cavities. The high vibration together with the acoustic resonance creates large forces. These forces have been attributed to excitation mechanisms including fluid elastic instability, random turbulence excitation, and periodic wake shedding. Some of the forces are transmitted to the attached pipes. Integrity of the piping system to withstand the forces depends on rigid and variable pipe supports. It is therefore paramount to determine the load induced into the supports to design them adequately. The purpose of this paper is to provide relative magnitude of loads experienced at various pipe supports as a function of distance from the HRSG (load decay). This knowledge is expected to help support designers to optimize material allocation to ensure pipe system integrity at optimum cost.


Author(s):  
Roberto Carapellucci ◽  
Lorena Giordano

Repowering existing power plants represents a potential route to meet the increasing energy demand, in a context of more and more stringent environmental regulations, hindering the construction of new facilities. Conventionally, repowering is operated into existing steam power plants, thus allowing to increase the design capacity to such an extent that depends on the type of strategy to exploit the waste heat from the additional gas turbine. In this study a new repowering concept is proposed. It involves the integration of an additional unit based on a gas turbine into an existing combined cycle gas turbine (CCGT). Based on this concept, two repowering options are examined. In the first one (Option A), the waste heat from gas turbine flue gases is used to produce steam in a one pressure level steam generator. In the second option (Option B), the exhaust waste heat recovery promotes the generation of a synthesis gas in a methane steam reformer. The integration of the additional unit is operated by the injection of superheated steam (Option A) and the reformed fuel (Option B) into the combustor of the main power plant, thus allowing for a further increase in power output of both topping and bottoming cycles. The simulation study allows to compare the repowering options with respect to the potential increase of power capacity, as well as in terms of energy marginal performance parameters.


Author(s):  
William P. Hancock

The paper describes the application and development of the offshore gas turbine from its infancy on Lake Maracaibo, Venezuela up to the current mature technology. North Sea developments are described, particularly in the Norwegian sector which was an important contributor to advancing the state of the art. The first application of the second generation aero engine and of the very high pressure centrifugal gas compressor were important milestones which have made significant contributions to the economic recovery of North Sea hydrocarbons. The author describes the current efforts to further optimise gas turbine installation, and operating costs. Cheaper and lighter gas turbine facilities require, not only increases in specific power, but also considerable innovation from the Engineers responsible for the application of this machinery. For the future, fewer units of even larger ratings are foreseen, applied as high efficiency simple cycles with limited heat recovery.


Author(s):  
Qian Liu ◽  
Hongtao Zheng ◽  
Fumin Pan ◽  
Gang Pan ◽  
Ren Yang

Plasma is proposed as a prospective tool for chemical heat recovery process without restriction from reaction temperature. The author designed DBD catalytic reactors and carried out extensive experiments to investigate methane conversion and products yield and analyze the effect laws of steam to methane ratio, resident time and reaction temperature on methane steam reforming (MSR). Based on extensive experimental studies of steam reforming, a detailed reaction mechanism for the plasma-assisted MSR was developed and evaluated by comparison of experimentally derived and numerically predicted conversion and products yield. The comparisons showed the kinetic model well predicted methane conversion and products yield in different operating conditions. By employing the kinetic model and path flux analysis module the kinetic effects of low temperature non-equilibrium plasma assisted CH4 steam reforming on the methane conversion was studied without catalyst. The results showed that CH3 recombination was the limiting reaction for CO production; meantime O was the critical species for CO production. By adding Ni catalyst can reduce methyl recombination and promote hydroxyl into oxygen, which is beneficial to heat recovery. The proposed research ensures the effect laws and characters of MSR by plasma, and contribute to improve the objective products concentration and furthermore the energy efficiency.


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