CFD Applications on Selective Catalytic NOx Reduction (SCR) Systems

Author(s):  
Jia Mi ◽  
Dan A. Pitsko ◽  
Tim Haskew

For the last several years, CFD modeling has been successfully used in Southern Company as one of the design and analysis tools to provide engineering insight to retrofitting Selective Catalytic NOx Reduction (SCR) systems to coal-fired steam power generation plants. SCR technology is the most effective method for reducing NOx emissions by at least 75% ∼ 90%. This paper will summarize a few selected CFD applications that were proved to be essential in the SCR design and optimization processes. For validation purposes, some of the CFD results, such as pressure drop, were compared with the available measurement data from the scaled physical flow models. They generally agreed well.

2001 ◽  
Author(s):  
Bradley R. Adams ◽  
Dave H. Wang

Abstract A DOE-funded program was used to understand the mechanisms that control the formation of NOx during the combustion of steelmaking by-product fuels and to investigate possible low-cost control options to minimize the NOx emissions. This paper discusses the CFD modeling results of NOx emissions in a reheat furnace. The reheat furnace has a total of 20 burners distributed over three firing zones. The furnace is fired at a rate of 250 × 106 Btu/hr and an overall stoichiometric ratio of 1.06 (fuel lean). Fuels with heating values of approximate 500 Btu/SCF were examined, including coke oven gas (COG), blast furnace gas (BFG) and a blend of COG, BFG, natural gas (NG) and nitrogen. A good range of process variables was modeled to examine effects of fuel type, air preheat, stoichiometric ratio, firing rate and burner stoichiometry distribution on NOx emissions. Modeling results indicated that NOx formation in the reheat furnace is dominated by thermal NO, with some variation depending on the fuel fired. Temperature profiles showed an effective separation of the furnace interior into top and bottom zones as a result of the steel slab barrier. Higher temperatures characterized the bottom zone and elevated NOx levels as a result of the confined space and enhanced fuel air mixing provided by the slab supports. Results also showed that reburning of NOx plays a significant role in final NOx emissions with 30–40% of NOx formed being reduced by reburning in most cases. Modeling identified that operating the side burners in each burner zone slightly substoichiometric (while maintaining the overall furnace stoichiometry at 1.06) provided significant NOx reduction via reburning. NOx reductions of 23% and 30% were predicted when firing with COG and COG-NG-Air fuels, respectively. Overall furnace exit temperatures and heat flux profiles were not significantly affected by the biased firing.


Author(s):  
Lars O. Nord ◽  
David R. Schoemaker ◽  
Helmer G. Andersen

A study was initiated to investigate the possibility of significantly reducing the NOx emissions at a power plant utilizing, among other manufacturers, ALSTOM GT11 type gas turbines. This study is limited to one of the GT11 type gas turbines on the site. After the initial study phase, the project moved on to a mechanical implementation stage, followed by thorough testing and tuning. The NOx emissions were to be reduced at all ambient conditions, but particularly at cold conditions (below 0°C) where a NOx reduction of more than 70% was the goal. The geographical location of the power plant means cold ambient conditions for a large part of the year. The mechanical modifications included the addition of Helmholtz damper capacity with an approximately 30% increase in volume for passive thermo-acoustic instability control, significant piping changes to the fuel distribution system in order to change the burner configuration, and installation of manual valves for throttling of the fuel gas to individual burners. Subsequent to the mechanical modifications, significant time was spent on testing and tuning of the unit to achieve the wanted NOx emissions throughout a major part of the load range. The tuning was, in addition to the main focus of the NOx reduction, also focused on exhaust temperature spread, combustion stability, CO emissions, as well as other parameters. The measurement data was acquired through a combination of existing unit instrumentation and specific instrumentation added to aid in the tuning effort. The existing instrumentation readings were polled from the control system. The majority of the added instrumentation was acquired via the FieldPoint system from National Instruments. The ALSTOM AMODIS plant-monitoring system was used for acquisition and analysis of all the data from the various sources. The project was, in the end, a success with low NOx emissions at part load and full load. As a final stage of the project, the CO emissions were also optimized resulting in a nice compromise between the important parameters monitored, namely NOx emissions, CO emissions, combustion stability, and exhaust temperature distribution.


Author(s):  
Kal Raman ◽  
Edmund Schindler

As part of a much larger Ontario Power Generation NOx reduction program, two separate turnkey contracts were awarded to RJM Corporation to convert the four units at the Lakeview Generating Station located on lake Ontario near downtown Toronto. Lakeview Station Units 1, 2, 5 and 6 are 300 MWe, B&W split furnace, radiant boilers firing bituminous coal. Units 1 & 2 have 24 burners and Units 5 & 6 have 18 burners all located on the front wall. The original B&W register style burners were used as a basis to reduce NOx emissions to the maximum amount possible by means of burner modifications using RJM’s low NOx burner components. This upgrade reduced NOX by more than 50% from the original burner baseline, simultaneously maintained CO below 100 ppm and maintaining a reasonable increase in baseline LOI, with no effect on boiler steam temperatures or performance. RJM Corporation was selected on a competitive bid basis to perform these contracts on a turnkey basis. Stone and Webster prepared the specification and acted as the OPGI engineer throughout the project. The details of the retrofit and the results of the conversion are presented in this paper.


Author(s):  
Jose Plasencia ◽  
Nathanael Inkson ◽  
Ole Jørgen Nydal

AbstractThis paper reports experimental research on the flow behavior of oil-water surfactant stabilized emulsions in different pipe diameters along with theoretical and computational fluid dynamics (CFD) modeling of the relative viscosity and inversion properties. The pipe flow of emulsions was studied in turbulent and laminar conditions in four pipe diameters (16, 32, 60, and 90 mm) at different mixture velocities and increasing water fractions. Salt water (3.5% NaCl w/v, pH = 7.3) and a mineral oil premixed with a lipophilic surfactant (Exxsol D80 + 0.25% v/v of Span 80) were used as the test fluids. The formation of water-in-oil emulsions was observed from low water fractions up to the inversion point. After inversion, unstable water-in-oil in water multiple emulsions were observed under different flow regimes. These regimes depend on the mixture velocity and the local water fraction of the water-in-oil emulsion. The eddy turbulent viscosity calculated using an elliptic-blending k-ε model and the relative viscosity in combination act to explain the enhanced pressure drop observed in the experiments. The inversion process occurred at a constant water fraction (90%) and was triggered by an increase of mixture velocity. No drag reduction effect was detected for the water-in-oil emulsions obtained before inversion.


2018 ◽  
Author(s):  
Hariyotejo Pujowidodo ◽  
Ahmad Indra Siswantara ◽  
Budiarso ◽  
Asyari Daryus ◽  
Gun Gun Ramdlan Gunadi

2020 ◽  
Vol 5 (3) ◽  
pp. 18-33
Author(s):  
Sylwia Janta-Lipińska ◽  

The nitrogen oxides in a flame of burning fuel can be created by many mechanisms. The amount of NOx concentration emitted to the ground atmosphere mainly depends on the type of fuel burned in the industrial and heating boilers. Changes in the country's thermal policy and requirements that are set for us by the European Union States are forcing us to reduce greenhouse gas emissions. Directed metered ballast method is one of the most attractive techniques for reducing NOx emissions. In recent years, moisture injection technology is still investigated on low and medium power thermal power boilers operating on gaseous fuel. The goal of this work was to perform the investigations of the process of a moisture injection into the zones of decisive influence (SDW-I and SDW-II) on steam and water boilers: DKVR 10-13, DKVR 20-13, DE 25-14 and PTVM-50. The obtained results clearly show how the proposed method affects NOx reduction and boiler efficiency.


Energies ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 2442 ◽  
Author(s):  
Jussi Ekström ◽  
Matti Koivisto ◽  
Ilkka Mellin ◽  
Robert Millar ◽  
Matti Lehtonen

In future power systems, a large share of the energy will be generated with wind power plants (WPPs) and other renewable energy sources. With the increasing wind power penetration, the variability of the net generation in the system increases. Consequently, it is imperative to be able to assess and model the behavior of the WPP generation in detail. This paper presents an improved methodology for the detailed statistical modeling of wind power generation from multiple new WPPs without measurement data. A vector autoregressive based methodology, which can be applied to long-term Monte Carlo simulations of existing and new WPPs, is proposed. The proposed model improves the performance of the existing methodology and can more accurately analyze the temporal correlation structure of aggregated wind generation at the system level. This enables the model to assess the impact of new WPPs on the wind power ramp rates in a power system. To evaluate the performance of the proposed methodology, it is verified against hourly wind speed measurements from six locations in Finland and the aggregated wind power generation from Finland in 2015. Furthermore, a case study analyzing the impact of the geographical distribution of WPPs on wind power ramps is included.


Author(s):  
Alexandrina Untaroiu ◽  
Amy L. Throckmorton ◽  
Houston G. Wood ◽  
Paul E. Allaire

A ventricular assist device (VAD) effectively relieves the workload from a native heart, which has been weakened by disease, and increases blood flow supplied to the body to maintain normal physiologic function. The device must be able to operate over a wide range of conditions. Designed to operate at a single, best-efficiency operating point, it must frequently perform at off-design conditions due to a fluctuating flow rate demanded by the human body and a time varying flow within the pump, due to the beating of the native heart. The design and optimization of a blood pump is a challenging and complex process. Pump design equations are used to estimate the initial dimensions of the pump regions. Computational fluid dynamics (CFD) analyses are then performed to optimize the blood flow path according to specific design criteria under steady flow conditions [1].


Processes ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 1966
Author(s):  
Shiyong Yu ◽  
Jichao Zhang

A systematic modeling approach was scrutinized to develop a kinetic model and a novel monolith channel geometry was designed for NH3 selective catalytic reduction (NH3-SCR) over Cu-ZSM-5. The redox characteristic of Cu-based catalysts and the variations of NH3, NOx concentration, and NOx conversion along the axis in porous media channels were studied. The relative pressure drop in different channels, the variations of NH3 and NOx conversion efficiency were analyzed. The model mainly considers NH3 adsorption and desorption, NH3 oxidation, NO oxidation, and NOx reduction. The results showed that the model could accurately predict the NH3-SCR reaction. In addition, it was found that the Cu-based zeolite catalyst had poor low-temperature catalytic performance and good high-temperature activity. Moreover, the catalytic reaction of NH3-SCR was mainly concentrated in the upper part of the reactor. In addition, the hexagonal channel could effectively improve the diffusion rate of gas reactants to the catalyst wall, reduce the pressure drop and improve the catalytic conversion efficiencies of NH3 and NOx.


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