Management of Historical Waste From Research Reactors: The Dutch Experience

Author(s):  
Aliki van Heek ◽  
Bert Metz ◽  
Bas Janssen ◽  
Ron Groothuis

Most radioactive waste emerges as well-defined waste streams from operating power reactors. The management of this is an on-going practice, based on comprehensive (IAEA) guidelines. A special waste category however consists of the historical waste from research reactors, mostly originating from various experiments in the early years of the nuclear era. Removal of the waste from the research site, often required by law, raises challenges: the waste packages must fulfill the acceptance criteria from the receiving storage site as well as the criteria for nuclear transports. Often the aged waste containers do not fulfill today’s requirements anymore, and their contents are not well documented. Therefore removal of historical waste requires advanced characterization, sorting, sustainable repackaging and sometimes conditioning of the waste. This paper describes the Dutch experience of a historical waste removal campaign from the Petten High Flux research reactor. The reactor is still in operation, but Dutch legislation asks for central storage of all radioactive waste at the COVRA site in Vlissingen since the availability of the high- and intermediate-level waste storage facility HABOG in 2004. In order to comply with COVRA’s acceptance criteria, the complex and mixed inventory of intermediate and low level waste must be characterized and conditioned, identifying the relevant nuclides and their activities. Sorting and segregation of the waste in a Hot Cell offers the possibility to reduce the environmental footprint of the historical waste, by repackaging it into different classes of intermediate and low level waste. In this way, most of the waste volume can be separated into lower level categories not needing to be stored in the HABOG, but in the less demanding LOG facility for low-level waste instead. The characterization and sorting is done on the basis of a combination of gamma scanning with high energy resolution of the closed waste canister and low-resolution localized gamma scanning inside a hot cell. A complicating factor is that the conditioning of the waste, consisting of compacting and cementing, would require such an extensive infrastructure at the Petten site, that it appeared to be more practical to have it executed by a foreign service provider. Therefore the waste packages have to comply with cross-border transport and waste acceptance criteria, and the national legislation of this service provider too. This paper describes this historical waste project, focusing on the fast and precise characterization approach, the expert system behind it, and the sorting and repackaging effort at the Petten site.

Author(s):  
Jan Deckers

Large amounts of actual and historical low level radioactive waste, with varying characteristics, are stored and generated from the operation and maintenance of nuclear power plants, the nuclear fuel cycle, research laboratories, pharmaceutical and medical facilities. Virtual all of these waste streams can be treated by the plasma technology resulting in a final product free of organics, liquids and moisture, and meeting without a doubt the acceptance criteria for safe storage and disposal. The plasma is a highly desirable heat source. Its high temperature of up to 10.000 °C can treat the radioactive waste as is. The inorganic materials are melted into a glassy slag, containing most of the radioactive isotopes, while the organic material is vaporized into a syngas and subsequently oxidized in an afterburner. This technology is very suitable for historical waste containing mixtures of inorganic, organic, liquids, sludge, etc, with almost no waste preparation and with minimal risk for radioactive contamination and exposure. Plasma technology offers a high volume waste reduction factor (VRF) that minimizes the volume and overall costs of waste storage and disposal. In addition, as plasma technology can recondition previously conditioned waste packages that no longer meet the present acceptance criteria for final disposal, it offers a solution to the growing demand for improved quality of final waste forms. As such, plasma technology is of great value, not just to waste producers but to future generations as well. This paper describes further the principles of plasma, the different waste feed systems, off-gas treatment, operational experience and future plasma plants.


Author(s):  
P.E. Batson

Use of the STEM to obtain precise electronic information has been hampered by the lack of energy loss analysis capable of a resolution and accuracy comparable to the 0.3eV energy width of the Field Emission Source. Recent work by Park, et. al. and earlier by Crewe, et. al. have promised magnetic sector devices that are capable of about 0.75eV resolution at collection angles (about 15mR) which are great enough to allow efficient use of the STEM probe current. These devices are also capable of 0.3eV resolution at smaller collection angles (4-5mR). The problem that arises, however, lies in the fact that, even with the collection efficiency approaching 1.0, several minutes of collection time are necessary for a good definition of a typical core loss or electronic transition. This is a result of the relatively small total beam current (1-10nA) that is available in the dedicated STEM. During this acquisition time, the STEM acceleration voltage may fluctuate by as much as 0.5-1.0V.


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