Potential Reduction of Fugitive Methane Emissions at Compressor Stations and Storage Facilities Powered by Natural Gas Engines

2014 ◽  
Author(s):  
Derek Johnson ◽  
April Covington

The American Gas Association (AGA) and the United States (US) Energy Information Administration (EIA) report that natural gas reserves, production, and consumption are increasing. Current estimates show over 100 years worth of recoverable reserves. As production increases, the natural gas pipeline interstate will grow or at least experience increased throughput. With the industry expanding at rapid rates and the high global warming potential of methane (21 over a 100 year period), it is important to identify potential sources for reductions in fugitive methane emissions. This research group conducted leak and loss audits at five natural gas compressor station and storage facilities. The majority of methane losses were associated with the operation of the lean-burn, natural gas engines (open crankcases, exhaust), compressor seal vents, and open liquid storage tanks. This paper focuses on the potential reduction in fugitive methane emissions of the discovered industry weaknesses through application of various proven technologies. As engines are not perfectly sealed, blow-by of intake air, fuel, and combustion gases occurs past the piston rings. In order to prevent a build-up of pressure within the crankcase, it must be vented. Diesel engines have lower hydrocarbon emissions from their crankcases due to the short duration of fuel addition after compression of the intake charge. Lean-burn, natural gas engines, like conventional gasoline engines, compress both the fuel and intake air during the compression stroke. During the 1960s, many passenger vehicles adopted positive crankcase ventilation (PCV) or closed crankcase ventilation (CCV) systems to reduce significantly hydrocarbon emissions from engines. Currently, some heavy-duty on-road engines still have open crankcase systems and most off-road engines have crankcases simply vented to the atmosphere. In this paper, researchers will examine the potential reduction in methane emissions that could be realized with the installation of retrofitted CCV systems at these locations. In addition to the reduction of methane losses from the crankcase, it is realized that with proper plumbing, flow control, and safety parameters, all of the losses typically vented to atmosphere could be ducted into the engine intake for combustion. Preliminary results show that applications of closed crankcase systems could reduce emissions from these sites by 1–11% while modifying these systems to include the losses from compressor seal vents and storage tanks could yield potential reductions in methane emissions by 10–57%.

Author(s):  
Paul S. Wang ◽  
Allen Y. Chen

Large natural gas engines that introduce premixed fuel and air into the engine cylinders allow a small fraction of fuel to evade combustion, which is undesirable. The premixed fuel and air combust via flame propagation. Ahead of the flame front, the unburned fuel and air are driven into crevices, where conditions are not favorable for oxidation. The unburned fuel is a form of waste and a source of potent greenhouse gas emissions. A concept to vent unburned fuel into the crankcase through built-in slots in the liner during the expansion stroke has been tested. This venting process occurs before the exhaust valve opens and the unburned fuel sent into the crankcase can be recycled to the intake side through a closed crankcase ventilation system. The increased communication between the cylinder and the crankcase changes the ring pack dynamics, which results in higher oil consumption. Oil consumption was measured using a sulfur tracer technique. Careful design is required to achieve the best tradeoff between reductions in unburned hydrocarbon emissions and oil control.


2015 ◽  
Vol 49 (13) ◽  
pp. 8132-8138 ◽  
Author(s):  
Derek R. Johnson ◽  
April N. Covington ◽  
Nigel N. Clark

2020 ◽  
Vol 59 (34) ◽  
pp. 14423-14428 ◽  
Author(s):  
Deniz Zengel ◽  
Pirmin Koch ◽  
Bentolhoda Torkashvand ◽  
Jan‐Dierk Grunwaldt ◽  
Maria Casapu ◽  
...  

2020 ◽  
pp. 146808742097775
Author(s):  
Ziqing Zhao ◽  
Zhi Wang ◽  
Yunliang Qi ◽  
Kaiyuan Cai ◽  
Fubai Li

To explore a suitable combustion strategy for natural gas engines using jet ignition, lean burn with air dilution, stoichiometric burn with EGR dilution and lean burn with EGR dilution were investigated in a single-cylinder natural gas engine, and the performances of two kinds of jet ignition technology, passive jet ignition (PJI) and active jet ignition (AJI), were compared. In the study of lean burn with air dilution strategy, the results showed that AJI could extend the lean limit of excess air ratio (λ) to 2.1, which was significantly higher than PJI’s 1.6. In addition, the highest indicated thermal efficiency (ITE) of AJI was shown 2% (in absolute value) more than that of PJI. Although a decrease of NOx emission was observed with increasing λ in the air dilution strategy, THC and CO emissions increased. Stoichiometric burn with EGR was proved to be less effective, which can only be applied in a limited operation range and had less flexibility. However, in contrast to the strategy of stoichiometric burn with EGR, the strategy of lean burn with EGR showed a much better applicability, and the highest ITE could achieve 45%, which was even higher than that of lean burn with air dilution. Compared with the most efficient points of lean burn with pure air dilution, the lean burn with EGR dilution could reduce 78% THC under IMEP = 1.2 MPa and 12% CO under IMEP = 0.4 MPa. From an overall view of the combustion and emission performances under both low and high loads, the optimum λ would be from 1.4 to 1.6 for the strategy of lean burn with EGR dilution.


Author(s):  
Patrick Lott ◽  
Olaf Deutschmann

AbstractHigh engine efficiency, comparably low pollutant emissions, and advantageous carbon dioxide emissions make lean-burn natural gas engines an attractive alternative compared to conventional diesel or gasoline engines. However, incomplete combustion in natural gas engines results in emission of small amounts of methane, which has a strong global warming potential and consequently makes an efficient exhaust gas aftertreatment system imperative. Palladium-based catalysts are considered as most effective in low temperature methane conversion, but they suffer from inhibition by the combustion product water and from poisoning by sulfur species that are typically present in the gas stream. Rational design of the catalytic converter combined with recent advances in catalyst operation and process control, particularly short rich periods for catalyst regeneration, allow optimism that these hurdles can be overcome. The availability of a durable and highly efficient exhaust gas aftertreatment system can promote the widespread use of lean-burn natural gas engines, which could be a key step towards reducing mankind’s carbon footprint.


Author(s):  
Marc E. Baumgardner ◽  
Daniel B. Olsen

Due to current and future exhaust emissions regulations, oxidation catalysts are increasingly being added to the exhaust streams of large-bore, 2-stroke, natural gas engines. Such catalysts have been found to have a limited operational lifetime, primarily due to chemical (i.e. catalyst poisoning) and mechanical fouling resulting from the carry-over of lubrication oil from the cylinders. It is critical for users and catalyst developers to understand the nature and rate of catalyst deactivation under these circumstances. This study examines the degradation of an exhaust oxidation catalyst on a large-bore, 2-stroke, lean-burn, natural gas field engine over the course of 2 years. Specifically this work examines the process by which the catalyst was aged and tested and presents a timeline of catalyst degradation under commercially relevant circumstances. The catalyst was aged in the field for 2 month intervals in the exhaust slipstream of a GMVH-12 engine and intermittently brought back to the Colorado State Engines and Energy Conversion Laboratory for both engine testing and catalyst surface analysis. Engine testing consisted of measuring catalyst reduction efficiency as a function of temperature as well as the determination of the light-off temperature for several exhaust components. The catalyst surface was analyzed via SEM/EDS and XPS techniques to examine the location and rate of poison deposition. After 2 years on-line the catalyst light-off temperature had increased ∼55°F (31°C) and ∼34 wt% poisons (S, P, Zn) were built up on the catalyst surface, both of which represent significant catalyst deactivation.


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