Effect of water vapor on the activity and stability of Pd/SZ and Co/ZrO2 in dual-catalyst treatment of simulated exhaust from lean-burn natural gas engines

2010 ◽  
Vol 96 (3-4) ◽  
pp. 421-433 ◽  
Author(s):  
Burcu Mirkelamoglu ◽  
Umit S. Ozkan
2020 ◽  
Vol 59 (34) ◽  
pp. 14423-14428 ◽  
Author(s):  
Deniz Zengel ◽  
Pirmin Koch ◽  
Bentolhoda Torkashvand ◽  
Jan‐Dierk Grunwaldt ◽  
Maria Casapu ◽  
...  

2020 ◽  
pp. 146808742097775
Author(s):  
Ziqing Zhao ◽  
Zhi Wang ◽  
Yunliang Qi ◽  
Kaiyuan Cai ◽  
Fubai Li

To explore a suitable combustion strategy for natural gas engines using jet ignition, lean burn with air dilution, stoichiometric burn with EGR dilution and lean burn with EGR dilution were investigated in a single-cylinder natural gas engine, and the performances of two kinds of jet ignition technology, passive jet ignition (PJI) and active jet ignition (AJI), were compared. In the study of lean burn with air dilution strategy, the results showed that AJI could extend the lean limit of excess air ratio (λ) to 2.1, which was significantly higher than PJI’s 1.6. In addition, the highest indicated thermal efficiency (ITE) of AJI was shown 2% (in absolute value) more than that of PJI. Although a decrease of NOx emission was observed with increasing λ in the air dilution strategy, THC and CO emissions increased. Stoichiometric burn with EGR was proved to be less effective, which can only be applied in a limited operation range and had less flexibility. However, in contrast to the strategy of stoichiometric burn with EGR, the strategy of lean burn with EGR showed a much better applicability, and the highest ITE could achieve 45%, which was even higher than that of lean burn with air dilution. Compared with the most efficient points of lean burn with pure air dilution, the lean burn with EGR dilution could reduce 78% THC under IMEP = 1.2 MPa and 12% CO under IMEP = 0.4 MPa. From an overall view of the combustion and emission performances under both low and high loads, the optimum λ would be from 1.4 to 1.6 for the strategy of lean burn with EGR dilution.


Author(s):  
Patrick Lott ◽  
Olaf Deutschmann

AbstractHigh engine efficiency, comparably low pollutant emissions, and advantageous carbon dioxide emissions make lean-burn natural gas engines an attractive alternative compared to conventional diesel or gasoline engines. However, incomplete combustion in natural gas engines results in emission of small amounts of methane, which has a strong global warming potential and consequently makes an efficient exhaust gas aftertreatment system imperative. Palladium-based catalysts are considered as most effective in low temperature methane conversion, but they suffer from inhibition by the combustion product water and from poisoning by sulfur species that are typically present in the gas stream. Rational design of the catalytic converter combined with recent advances in catalyst operation and process control, particularly short rich periods for catalyst regeneration, allow optimism that these hurdles can be overcome. The availability of a durable and highly efficient exhaust gas aftertreatment system can promote the widespread use of lean-burn natural gas engines, which could be a key step towards reducing mankind’s carbon footprint.


Author(s):  
Marc E. Baumgardner ◽  
Daniel B. Olsen

Due to current and future exhaust emissions regulations, oxidation catalysts are increasingly being added to the exhaust streams of large-bore, 2-stroke, natural gas engines. Such catalysts have been found to have a limited operational lifetime, primarily due to chemical (i.e. catalyst poisoning) and mechanical fouling resulting from the carry-over of lubrication oil from the cylinders. It is critical for users and catalyst developers to understand the nature and rate of catalyst deactivation under these circumstances. This study examines the degradation of an exhaust oxidation catalyst on a large-bore, 2-stroke, lean-burn, natural gas field engine over the course of 2 years. Specifically this work examines the process by which the catalyst was aged and tested and presents a timeline of catalyst degradation under commercially relevant circumstances. The catalyst was aged in the field for 2 month intervals in the exhaust slipstream of a GMVH-12 engine and intermittently brought back to the Colorado State Engines and Energy Conversion Laboratory for both engine testing and catalyst surface analysis. Engine testing consisted of measuring catalyst reduction efficiency as a function of temperature as well as the determination of the light-off temperature for several exhaust components. The catalyst surface was analyzed via SEM/EDS and XPS techniques to examine the location and rate of poison deposition. After 2 years on-line the catalyst light-off temperature had increased ∼55°F (31°C) and ∼34 wt% poisons (S, P, Zn) were built up on the catalyst surface, both of which represent significant catalyst deactivation.


Author(s):  
Cory J. Kreutzer ◽  
Daniel B. Olsen ◽  
Robin J. Bremmer

Wellhead gas from which pipeline natural gas originates has significant variability in composition due to natural variations in deposits. Gas quality is influenced by relative concentrations of both inert and hydrocarbon species. Gas compression engines utilizing wellhead gas as a fuel source often require significant installation time and adjustment of stock configuration due to fuel compositions that vary with time and location. Lean burn natural gas engines are chosen as wellhead compression engines for high efficiency and low emissions while minimizing the effect of variable gas composition. Ideal engine conditions are maintained by operating within the knock and misfire limits of the engine. Additional data is needed to find engine operational limitations. In this work, experimental data was collected on a Cummins GTA8.3SLB engine operating on variable methane number fuel under closed-loop equivalence ratio control. A fuel blending system was used to vary methane number to simulate wellhead compositions. NOx and CO emissions were found to increase with decreasing methane number while combustion stability remained constant. In addition, the effects of carbon dioxide and nitrogen diluents in the fuel were investigated. When diluents were present in the fuel, engine performance could be maintained by spark timing advance.


2005 ◽  
Author(s):  
Nigel Clark ◽  
Gregory Thompson ◽  
Richard Atkinson ◽  
Chamila Tissera ◽  
Matt Swartz ◽  
...  

Author(s):  
G. R. Herdin ◽  
F. Gruber ◽  
D. Plohberger ◽  
M. Wagner

The gas engine is a very efficient possibility of a technological approach for the conversion of chemically bound energy into mechanical or electrical power. Degrees of efficiency achieved thus far through the electrification of natural gas amount to up to 45% depending on the engine size and further potentials are already being opened up. Gas engines therefore do not need to fear a comparison with diesel engines in terms of efficiency. The modern gas engines have considerable advantages regarding emissions. The state of the art for the NOx emissions of natural gas engines can presently be given as 0.7 g/kWh (diesel 5 g NOx/kWh) with practically particle-free combustion. As a result of these features the gas engine is especially suitable for the very efficient process of cogeneration of heat and power, through which total degrees of fuel efficiency of about 90% can be attained. As such, the gas engine is even superior to all previously introduced types of fuel cells. The utilization of H2-rich gases as fuel can be seen as a new field of application of gas engines. Jenbacher AG already has many years of experience in the field of “H2-rich fuels” with optimization of combustion control and mixture formation. The H2 content extend from 100% to very low caloric values of gases in the range of 1.67 MJ/Nm3. The gases to be utilized by the gas engines come primarily from thermal pyrolysis processes of biomass or RDF fuels. A very good efficiency behavior with uncommonly low NOx emissions can be determined as the common result of all gas engine sizes. In the case of the high NH3 content of e.g. wood gas, despite the extreme lean-burn operation through the primary formation of NOx from the fuel, no NOx minimum can be attained. For the future, making the step into H2-rich fuel technology particularly regarding emissions means a big step towards the low NOx concepts and thus the further reduction of engine emissions.


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