scholarly journals Lean-Burn Natural Gas Engines: Challenges and Concepts for an Efficient Exhaust Gas Aftertreatment System

2020 ◽  
Author(s):  
Patrick Lott ◽  
Olaf Deutschmann
Keyword(s):  
Natural Gas ◽  
Carbon Dioxide Emissions ◽  
Rational Design ◽  
Catalytic Converter ◽  
Pollutant Emissions ◽  
Exhaust Gas ◽  
Lean Burn ◽  
Aftertreatment System ◽  
Natural Gas Engines ◽  
Exhaust Gas Aftertreatment

AbstractHigh engine efficiency, comparably low pollutant emissions, and advantageous carbon dioxide emissions make lean-burn natural gas engines an attractive alternative compared to conventional diesel or gasoline engines. However, incomplete combustion in natural gas engines results in emission of small amounts of methane, which has a strong global warming potential and consequently makes an efficient exhaust gas aftertreatment system imperative. Palladium-based catalysts are considered as most effective in low temperature methane conversion, but they suffer from inhibition by the combustion product water and from poisoning by sulfur species that are typically present in the gas stream. Rational design of the catalytic converter combined with recent advances in catalyst operation and process control, particularly short rich periods for catalyst regeneration, allow optimism that these hurdles can be overcome. The availability of a durable and highly efficient exhaust gas aftertreatment system can promote the widespread use of lean-burn natural gas engines, which could be a key step towards reducing mankind’s carbon footprint.

Experimental Evaluation of Volatile Organic Compound Quantification Methods for Reciprocating Natural Gas Engines

2021 ◽  
Vol 143 (7) ◽  
Author(s):  
Brenna King ◽  
Mukund Venkitachalam ◽  
Daniel Olsen
Keyword(s):  
Natural Gas ◽  
Environmental Protection Agency ◽  
Fuel Injection ◽  
Exhaust Gas ◽  
Direct Extraction ◽  
Lean Burn ◽  
Natural Gas Engines ◽  
Flame Ionization ◽  
Volatile Organic ◽  
The Fourier Transform

Abstract Compressor stations utilizing large-bore natural gas engines transport natural gas through pipelines worldwide. One emission class regulated by the Environmental Protection Agency (EPA) is volatile organic compounds (VOCs), which are nonmethane, nonethane, nonaldehyde hydrocarbons. The combination of a gas chromatograph (GC) and a flame ionization detector (FID) can measure VOCs, following EPA Method 18/25A. The Fourier transform infrared spectrometer (FTIR) also measures VOCs, following EPA Method 320. Multiple VOC calculation techniques are utilized, some combining measurements from separate analyzers. Two basic methods of extracting exhaust gas are direct extraction and Tedlar bag sampling. In this study, various VOC quantification methods are evaluated. Exhaust gas was sampled from a Cooper-Bessemer GMV lean-burn engine and a Caterpillar G3304 rich-burn engine. The GMV was tested in three configurations: open chamber spark ignition, precombustion chamber (PCC) ignition, and PCC ignition with high-pressure fuel injection. Ignition timing sweeps were performed on both engines, and a fuel variability test was performed on the GMV. Results showed that the Gasmet and MKS FTIRs’ (Method 320) VOC measurements deviate significantly from the HP GC when measuring low molar concentrations, albeit below regulatory limits. A common VOC quantification approach is subtracting the sum of methane and ethane FTIR measurements from a total hydrocarbon measurement utilizing a FID. This method produces uncertainties of 190% and overestimates VOC concentration by an average of 100%. The Tedlar bag sampling method produced VOC measurements within −2% of the direct extraction method.

A phenomenological model for the description of unburned hydrocarbons emission in ultra-lean engines

2021 ◽  
pp. 146808742110050
Author(s):  
Enrica Malfi ◽  
Vincenzo De Bellis ◽  
Fabio Bozza ◽  
Alberto Cafari ◽  
Gennaro Caputo ◽  
...  
Keyword(s):  
Natural Gas ◽  
Internal Combustion Engines ◽  
Pollutant Emissions ◽  
Average Error ◽  
Combustion Engines ◽  
Nitric Oxides ◽  
Lean Burn ◽  
Fuel Charge ◽  
Unburned Hydrocarbons ◽  
Model Reliability

The adoption of lean-burn concepts for internal combustion engines working with a homogenous air/fuel charge is under development as a path to simultaneously improve thermal efficiency, fuel consumption, nitric oxides, and carbon monoxide emissions. This technology may lead to a relevant emission of unburned hydrocarbons (uHC) compared to a stoichiometric engine. The uHC sources are various and the relative importance varies according to fuel characteristics, engine operating point, and some geometrical details of the combustion chamber. This concern becomes even more relevant in the case of engines supplied with natural gas since the methane has a global warming potential much greater than the other major pollutant emissions. In this work, a simulation model describing the main mechanisms for uHC formation is proposed. The model describes uHC production from crevices and flame wall quenching, also considering the post-oxidation. The uHC model is implemented in commercial software (GT-Power) under the form of “user routine”. It is validated with reference to two large bore engines, whose bores are 31 and 46 cm (engines named accordingly W31 and W46). Both engines are fueled with natural gas and operated with lean mixtures (λ > 2), but with different ignition modalities (pre-chamber device or dual fuel mode). The engines under study are preliminarily schematized in the 1D simulation tool. The consistency of 1D engine schematizations is verified against the experimental data of BMEP, air flow rate, and turbocharger rotational speed over a load sweep. Then, the uHC model is validated against the engine-out measurements. The averaged uHC predictions highlight an average error of 7% and 10 % for W31 and W46 engines, respectively. The uHC model reliability is evidenced by the lack of need for a case-dependent adjustment of its tuning constants, also in presence of relevant variations of both engine load and ring pack design.

scholarly journals Emission of Toxic HCN During NO x Removal by Ammonia SCR in the Exhaust of Lean‐Burn Natural Gas Engines

2020 ◽  
Vol 59 (34) ◽  
pp. 14423-14428 ◽  
Author(s):  
Deniz Zengel ◽  
Pirmin Koch ◽  
Bentolhoda Torkashvand ◽  
Jan‐Dierk Grunwaldt ◽  
Maria Casapu ◽  
...  
Keyword(s):  
Natural Gas ◽  
Lean Burn ◽  
Natural Gas Engines

Experimental study of combustion strategy for jet ignition on a natural gas engine

2020 ◽  
pp. 146808742097775
Author(s):  
Ziqing Zhao ◽  
Zhi Wang ◽  
Yunliang Qi ◽  
Kaiyuan Cai ◽  
Fubai Li
Keyword(s):  
Experimental Study ◽  
Natural Gas ◽  
Efficient Points ◽  
Lean Burn ◽  
Gas Engine ◽  
Absolute Value ◽  
Natural Gas Engines ◽  
Natural Gas Engine ◽  
Excess Air ◽  
Lean Limit

To explore a suitable combustion strategy for natural gas engines using jet ignition, lean burn with air dilution, stoichiometric burn with EGR dilution and lean burn with EGR dilution were investigated in a single-cylinder natural gas engine, and the performances of two kinds of jet ignition technology, passive jet ignition (PJI) and active jet ignition (AJI), were compared. In the study of lean burn with air dilution strategy, the results showed that AJI could extend the lean limit of excess air ratio (λ) to 2.1, which was significantly higher than PJI’s 1.6. In addition, the highest indicated thermal efficiency (ITE) of AJI was shown 2% (in absolute value) more than that of PJI. Although a decrease of NOx emission was observed with increasing λ in the air dilution strategy, THC and CO emissions increased. Stoichiometric burn with EGR was proved to be less effective, which can only be applied in a limited operation range and had less flexibility. However, in contrast to the strategy of stoichiometric burn with EGR, the strategy of lean burn with EGR showed a much better applicability, and the highest ITE could achieve 45%, which was even higher than that of lean burn with air dilution. Compared with the most efficient points of lean burn with pure air dilution, the lean burn with EGR dilution could reduce 78% THC under IMEP = 1.2 MPa and 12% CO under IMEP = 0.4 MPa. From an overall view of the combustion and emission performances under both low and high loads, the optimum λ would be from 1.4 to 1.6 for the strategy of lean burn with EGR dilution.

Design of a Flow Reactor for Testing Multi-Brick Catalyst Systems Using Rapid Exhaust Gas Composition Switches

2009 ◽  
Author(s):  
Stefan Klinkert ◽  
John W. Hoard ◽  
Sakthish R. Sathasivam ◽  
Dennis N. Assanis ◽  
Stanislav V. Bohac
Keyword(s):  
Flow Reactor ◽  
Combustion Engine ◽  
Synergistic Effects ◽  
Control Program ◽  
Exhaust Gas ◽  
Gas Composition ◽  
Lean Burn ◽  
Exhaust Gas Aftertreatment ◽  
Scr Catalysts ◽  
Catalyst Systems

In recent years, diesel exhaust gas aftertreatment has become a core combustion engine research subject because of both increasingly stringent emission regulations and incentives toward more fuel-efficient propulsion systems. Lean NOX traps (LNT) and selective catalytic reduction (SCR) catalysts represent two viable pathways for the challenging part of exhaust gas aftertreatment of lean burn engines: NOX abatement. It has been found that the combination of LNT and SCR catalysts can yield synergistic effects. Switches in the operation mode of the engine, temporarily enriching the mixture, are required to regenerate the LNT catalyst and produce ammonia for the SCR. This paper describes the design of a catalyst flow reactor that allows studying multi-brick catalyst systems using rapid exhaust gas composition switches and its initial validation. The flow reactor was designed primarily to study the potential of combining different aftertreatment components. It can accommodate two sample bricks at a time in two tube furnaces, which allows for independent temperature control. Moreover, the flow reactor allows for very flexible control of the composition and flow rate of the synthetic exhaust, which is blended using mass flow controllers. By using a two-branch design, very fast switches between two exhaust gas streams, as seen during the regeneration process of a LNT catalyst, are possible. The flow reactor utilizes a variety of gas analyzers, including a 5-Hz FTIR spectrometer, an emissions bench for oxygen and THC, a hydrogen mass spectrometer, and gas chromatographs for HC speciation. An in-house control program allows for data recording, flow reactor control, and highly flexible automation. Additionally, the hardware and software incorporate features to ensure safe testing. The design also has provisions for engine exhaust sampling.

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