Nanotwins in Copper Nanowires Controlled by Laser Assisted Electrochemical Deposition

Author(s):  
Zhikun Liu ◽  
Yiliang Liao ◽  
Gary J. Cheng ◽  
Yuefeng Wang

Nanotwins in metallic nanowires can improve mechanical strength and maintain high electrical conductivity. We demonstrated a method of pulse laser assisted electrodeposition, which can generate dense nanotwins with different directions in copper nanowires of uniform length. Transmission electron microcopy characterization shows at lower electrochemical potential of −0.2 Volt, nanotwins tend to align along the longitudinal direction of the nanowires whereas at the high potential −0.8 Volt, nanotwins of {111}/<112> type that cross the width of the wire are formed. We investigated the two types of nanotwins by comparing the microstructures under different electrochemistry and laser setting. Two different mechanisms are proposed for two kinds of nanotwin — annealing twins and growth twins.

Metals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 679
Author(s):  
Jinfeng Zou ◽  
Jianyi Cheng ◽  
Guangbo Feng ◽  
Jian Xie ◽  
Fangxin Yu

To obtain high strength and high electrical conductivity at the same time, the microstructure and properties of 0.2 wt.% V-added, 0.1 wt.% V-added and V-free Cu-1.6Ni-1.2Co-0.65Si(-V) alloys were investigated. We examined with electrical conductivity and hardness measurements, tensile test, optical microscope and transmission electron microscope (TEM). The results show that Cu-1.6Ni-1.2Co-0.65Si-0.1V alloy obtains excellent combination properties: electrical conductivity is 46.12% IACS, hardness is 293.88 Hv, and tensile strength is 782 MPa, which are produced by 65% cold rolling + aging at 500 °C for 480 min. The addition of vanadium (V) can accelerate the precipitation of solute atoms from the copper matrix, improve the hardness and electrical conductivity of Cu-1.6Ni-1.2Co-0.65Si alloys, and greatly accelerated the aging response. δ-(Co,Ni)2Si and β-Ni3Si phases are detected in Cu-1.6Ni-1.2Co-0.65Si-0.1V alloy. The Orowan mechanism and grain boundary strengthening play a major role in the yield strength strengthening due to δ-(Co,Ni)2Si phase.


2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Dawei Zhang ◽  
Qing Zhang ◽  
Xin Gao ◽  
Guangzhe Piao

The water-dispersed conductive polypyrrole (PPy) was prepared via thein situoxidative chemical polymerization by using ammonium persulfate (APS) as oxidant and tunicate cellulose nanocrystals (T-CNs) as a dopant and template for tuning the morphologies of PPy nanoparticles. Highly flexible paper-like materials of PPy/T-CNs nanocomposites with high electrical conductivity values and good mechanical properties were prepared. The structure of nanocomposites of PPy/T-CNs was investigated by using Fourier transform infrared spectroscopy. Scanning electron microscopy and transmission electron microscopy analyses of the composites revealed that PPy consisted of nanoparticles about 2.5 nm in mean size to form a continuous coating covered on the T-CNs. The diameters of the PPy nanoparticles increased from 10 to 100 nm with the increasing pyrrole amount. Moreover, electrical properties of the obtained PPy/T-CNs films were studied using standard four-probe technique and the electrical conductivity could be as high as 10−3 S/cm.


2011 ◽  
Vol 695 ◽  
pp. 477-480
Author(s):  
Kyung Hun Park ◽  
Hoon Cho ◽  
Soong Keun Hyun

The development trend for diagnostics is reducing the diameter of coaxial signal cables that comprise the probe cable. The thinner super-fine coaxial cable which is offering superior electronic and mechanical properties, such as 75 %IACS(International Annealed Copper Standard, electrical conductivity) and 700 ~ 800 MPa in tensile strength has to be developed. Cu-Ag based system is one of the most promising systems for high strength and high conductivity Cu alloys. In order to find the optimum conditions to obtain Cu-Ag-Zr-Co alloy with high strength and high electrical conductivity, the aging characteristics including work hardening of micro-Vickers hardness, tensile strength and electrical conductivity of this alloy were systematically measured at room temperature. Also the influence of aging treatment was investigated by transmission electron microscopy(TEM) and scanning electron microscopy(SEM) in this study. The aging treatment for precipitation was divided into two steps and carried out at various time and at different temperature and the multi-step aging treatment coupled with cold rolling was proposed for realizing Cu-Ag-Zr-Co alloys with high strength and high electrical conductivity. The electrical conductivity was improved from 31 %IACS to 91 %IACS remarkably and the tensile strength was increased from 230Mpa to 690Mpa greatly by an optimization of alloy composition and manufacturing process including aging.


2019 ◽  
Vol 11 (49) ◽  
pp. 46026-46033 ◽  
Author(s):  
Hyeon Jun Sim ◽  
Hyunsoo Kim ◽  
Yongwoo Jang ◽  
Geoffrey M. Spinks ◽  
Sanjeev Gambhir ◽  
...  

Author(s):  
John C. Russ ◽  
Nicholas C. Barbi

The rapid growth of interest in attaching energy-dispersive x-ray analysis systems to transmission electron microscopes has centered largely on microanalysis of biological specimens. These are frequently either embedded in plastic or supported by an organic film, which is of great importance as regards stability under the beam since it provides thermal and electrical conductivity from the specimen to the grid.Unfortunately, the supporting medium also produces continuum x-radiation or Bremsstrahlung, which is added to the x-ray spectrum from the sample. It is not difficult to separate the characteristic peaks from the elements in the specimen from the total continuum background, but sometimes it is also necessary to separate the continuum due to the sample from that due to the support. For instance, it is possible to compute relative elemental concentrations in the sample, without standards, based on the relative net characteristic elemental intensities without regard to background; but to calculate absolute concentration, it is necessary to use the background signal itself as a measure of the total excited specimen mass.


Alloy Digest ◽  
1988 ◽  
Vol 37 (1) ◽  

Abstract CDA C18700 is a copper-base alloy containing lead (nominally 1.0%). The lead is added to impart free-cutting properties to the metal. Although the lead lowers the electrical conductivity of CDA C18700 slightly below that of tough-pitch copper, it still has high electrical conductivity well within the limits needed for most current-carrying requirements. Typical uses comprise electrical motor and switch parts, electrical connectors and screw-machine parts requiring high conductivity. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and shear strength. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Cu-533. Producer or source: Copper and copper alloy mills.


Alloy Digest ◽  
1975 ◽  
Vol 24 (12) ◽  

Abstract Copper Alloy NO. 182 is an age-hardening type of alloy that combines relatively high electrical conductivity with good strength and hardness. It was formerly known as Chromium Copper and its applications include such uses as resistance-welding-machine electrodes, switch contacts and cable connectors. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive and shear strength as well as fracture toughness and fatigue. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Cu-305. Producer or source: Copper and copper alloy mills.


Sign in / Sign up

Export Citation Format

Share Document