scholarly journals Applications of Electrokinetic Remediation inEnvironmental Restoration

Author(s):  
Ikrema Hassan
Author(s):  
S.M.P.A Koliyabandara ◽  
Chamika Siriwardhana ◽  
Sakuni M. De Silva ◽  
Janitha Walpita ◽  
Asitha T. Cooray

2021 ◽  
Vol 11 (4) ◽  
pp. 1799
Author(s):  
Claudio Cameselle ◽  
Susana Gouveia ◽  
Adrian Cabo

The electrokinetic remediation of an agricultural soil contaminated with heavy metals was studied using organic acids as facilitating agents. The unenhanced electrokinetic treatment using deionized water as processing fluid did not show any significant mobilization and removal of heavy metals due to the low solubilization of metals and precipitation at high pH conditions close to the cathode. EDTA and citric acid 0.1 M were used as facilitating agents to favor the dissolution and transportation of metals. The organic acids were added to the catholyte and penetrated into the soil specimen by electromigration. EDTA formed negatively charged complexes. Citric acid formed neutral metal complexes in the soil pH conditions (pH = 2–4). Citric acid was much more effective in the dissolution and transportation out of the soil specimen of complexed metals. In order to enhance the removal of metals, the concentration of citric acid was increased up to 0.5 M, resulting in the removal of 78.7% of Cd, 78.6% of Co, 72.5% of Cu, 73.3% of Zn, 11.8% of Cr and 9.8% of Pb.


2021 ◽  
Vol 413 ◽  
pp. 125274
Author(s):  
Jamie M. Purkis ◽  
Phil E. Warwick ◽  
James Graham ◽  
Shaun D. Hemming ◽  
Andrew B. Cundy

Author(s):  
Kristine B. Pedersen ◽  
Ahmed Benamar ◽  
Mohamed T. Ammami ◽  
Florence Portet‐Koltalo ◽  
Gunvor M. Kirkelund

2000 ◽  
Vol 42 (7-8) ◽  
pp. 335-343 ◽  
Author(s):  
S. Shiba ◽  
S. Hino ◽  
Y. Hirata ◽  
T. Seno

The operational variables of electrokinetic remediation have not been cleared yet, because this method is relatively new and is an innovative technique in the aquifer remediation. In order to investigate the operational variables of the electrokinetic remediation, a mathematical model has been constructed based on the physico chemical mass transport process of heavy metals in pore water of contaminated aquifer. The transport of the heavy metals is driven not only by the hydraulic flow due to the injection of the purge water but also by the electromigration due to the application of the electric potential gradient. The electric potential between anode and cathode is the important operational variable for the electrokinetic remediation. From the numerical simulations with use of this model it is confirmed that the remediation starts from the up stream anode and gradually the heavy metal is transported to the down stream cathode and drawn out through the purge water.


Chemosphere ◽  
2014 ◽  
Vol 117 ◽  
pp. 673-678 ◽  
Author(s):  
Sivasankar Annamalai ◽  
Manikandan Santhanam ◽  
Maruthamuthu Sundaram ◽  
Marta Pazos Curras

2012 ◽  
Vol 518-523 ◽  
pp. 361-368 ◽  
Author(s):  
Rong Bing Fu ◽  
Xin Xing Liu ◽  
Fang Liu ◽  
Jin Ma ◽  
Yu Mei Ma ◽  
...  

A new permeable reactive composite electrode (PRCE) attached with a permeable reactive layer (PRL) of Fe0 and zeolite has been developed for soil pH control and the improved removal efficiency of heavy metal ions (Cd, Ni, Pb, Cu) from soil in electrokinetic remediation process. The effects of different composite electrodes on pH control and heavy metal removal efficiency were studied, and changes in the forms of heavy metals moved onto the electrodes were analyzed. The results showed that with acidic/alkaline zeolite added and renewed in time, the composite electrodes could effectively neutralize and capture H+ and OH- produced from electrolysis of the anolyte and catholyte, avoiding or delaying the formation of acidic/alkaline front in tested soil, preventing premature precipitation of heavy metal ions and over-acidification of soil, and thus significantly improved the heavy metal removal efficiency. Fe0 in composite electrodes could deoxidize and stabilize the heavy metal ions. After that capture and immobilization of the pollutants were achieved. The results also showed that, using "Fe0 + zeolite" PRCE in the cathode with timely renewal, after 15-day remediation with a DC voltage of 1.5 V/cm, the total removal rates of Cd, Pb, Cu and Ni were 49.4%, 47.1%, 36.7% and 39.2%, respectively.


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